Fluid inclusions as microchemical systems: evidence and modelling of fluid–host interactions in plagioclase

Dense, CO₂‐rich fluid inclusions hosted by plagioclases, An₄₅ to An₅₄, of the O.‐v.‐Gruber‐ Anorthosite body, central Dronning Maud Land, East Antarctica, contain varying amounts of small calcite, paragonite and pyrophyllite crystals detected by Raman microspectroscopy. These crystals are reaction products that have formed during cooling of the host and the original CO₂‐rich H₂O‐bearing enclosed fluid. Variable amounts of these reaction products illustrates that the reaction did not take place uniformly in all fluid inclusions, possibly due to differences in kinetics as caused by differences in shape and size, or due to compositional variation in the originally trapped fluid. The reaction albite + 2anorthite + 2H₂O + 2CO₂ = pyrophyllite + paragonite + 2calcite was thermodynamically modelled with consideration of different original fluid compositions. Although free H₂O is not detectable in most fluid inclusions, the occurrence of OH‐bearing sheet silicates indicates that the original fluid was not pure CO₂, but contained significant amounts of H₂O. Compared to an actual fluid inclusion it is obvious, that volume estimations of solid phases can be used as a starting point to reverse the retrograde reaction and recalculate the compositional and volumetrical properties of the original fluid. Isochores for an unmodified inclusion can thus be reconstructed, leading to a more realistic estimation of P–T conditions during earlier metamorphic stages or fluid capturing.     

Celebrating 50 years of SWIMs (Salt Water Intrusion Meetings)

The Salt Water Intrusion Meetings, or SWIMs, are a series of meetings that focus on seawater intrusion in coastal aquifers and other salinisation processes. 2018 marks the 50th year of the SWIM and the 25th biennial meeting. The SWIM proceedings record half a century of research progress on site characterisation, geophysical and geochemical techniques, variable-density flow, modelling, and water management. The SWIM is positioning itself to remain a viable platform for discussing the coastal aquifer management challenges of the next 50 years.     

Advancing New Testament interpretation through spatio‐temporal analysis: Demonstrated by case studies

This article explores, via three case studies, how spatio‐temporal analysis can advance New Testament text interpretation. Acts 2, verse 9 to 11 is the text of study. Case study 1 applies network analysis to data representing the Roman road network constrained by parameters valid for ancient times. This analysis provided new information on the background of people attending a festival in Jerusalem. Case study 2 located geographical entities from the text in a cartographic visualization and provided supportive information to compare contemporary textual resources. For the disciplines of textual and conjectural criticism (case study 3), spatio‐temporal analysis opens a new window to study what would be the most probable variant of the original text. The case study puts emendations that have been proposed over centuries in a 3D spatial context and provides in this way a sophisticated tool to relate different alternative variants of a specific text. From the case studies, it can be concluded that spatializing, visualizing, and spatially analyzing geographical concepts from the texts in Acts 2 contributes to the field of New Testament interpretation. Further work will elaborate on the findings.     

Recommended Sampling Intervals for Arsenic in Private Wells

Geogenic arsenic in drinking water is a worldwide problem. For private well owners, testing (e.g., private or government laboratory) is the main method to determine arsenic concentration. However, the temporal variability of arsenic concentrations is not well characterized and it is not clear how often private wells should be tested. To answer this question, three datasets, two new and one publicly available, with temporal arsenic data were utilized: 6370 private wells from New Jersey tested at least twice since 2002, 2174 wells from the USGS NAWQA database, and 391 private wells sampled 14 years apart from Bangladesh. Two arsenic drinking water standards are used for the analysis: 10 µg/L, the WHO guideline and EPA standard or maximum contaminant level (MCL) and 5 µg/L, the New Jersey MCL. A rate of change was determined for each well and these rates were used to predict the temporal change in arsenic for a range of initial arsenic concentrations below an MCL. For each MCL and initial concentration, the probability of exceeding an MCL over time was predicted. Results show that to limit a person to below a 5% chance of drinking water above an MCL, wells that are ½ an MCL and above should be tested every year and wells below ½ an MCL should be tested every 5 years. These results indicate that one test result below an MCL is inadequate to ensure long-term compliance. Future recommendations should account for temporal variability when creating drinking water standards and guidance for private well owners.     

Fluid inclusion modification by H2O and D2O diffusion: the influence of inclusion depth, size, and shape in re-equilibration experiments

The mobility of H₂O and D₂O by diffusion through quartz is illustrated with H₂O-rich fluid inclusions synthesized at 600 °C and 337 MPa, within the α-quartz stability field. Inclusions are re-equilibrated at the same experimental conditions within a pure D₂O fluid environment. Consequently, a gradient in volatile fugacities is the only driving force for diffusion, in the absence of pressure gradients and deformation processes. Up to 100 individual inclusions are analyzed in each experiment before and after re-equilibration by microscopic investigation, microthermometry, and Raman spectroscopy. Changes in fluid inclusion composition are obtained from the ice-melting temperatures, and density changes are obtained from total homogenization temperatures. After 1-day re-equilibration, inclusions already contain up to 11 mol % D₂O. A maximum concentration of 63 mol % D₂O is obtained after 40-day re-equilibration. D₂O concentration profiles in quartz are determined from the concentration in inclusions as a function of their distance to the quartz surface. These profiles illustrate that deep inclusions contain less D₂O than shallow inclusions. At equal depths, a variety of D₂O concentration is observed as a function of fluid inclusion size: Small inclusions are stronger effected compared with large inclusions. A series of 19-day re-equilibration experiments are performed at 300, 400, 500, and 600 °C (at 337 MPa), at the same conditions as the original synthesis. The threshold temperature of diffusion is estimated around 450 °C at 337 MPa, because D₂O is not detected in inclusions from re-equilibration experiments at 300 and 400 °C, whereas maximally 26 mol % D₂O is detected at 500 °C. Our study indicates that the isotopic composition of natural fluid inclusions may be easily modified by re-equilibration processes, according to the experimental conditions at 600 °C and 337 MPa.     

Peridinioid dinoflagellate cysts in a Holocene high-mountain lake deposit in Italy

This paper documents the discovery of peridinioid organic walled dinoflagellate cysts in Holocene sediments of the freshwater, low-alkalinity, high mountain Lake Nero di Cornisello (Adamello mountain range, Trentino, Italy). Among the three main cyst morphotypes found in the samples, the dominant one is acavate, with a smooth and light brown colored wall, with a clear conical shape, elongated with a pointy to rounded end in the antapical-ventral part, with the epicyst broader than the hypocyst and displays a typical peridinioid archeopyle. Comparison with data available in literature, besides pointing out the general scarcity of observations on dinocysts in lakes sediments, suggested a strong morphological similarity with the marine genus Brigantedinium. This finding pinpoints the need for more detailed studies on cysts in freshwater environments offering a new tool for paleoenvironmental interpretations.     

The research agenda of the European Science Foundation's GISDATA scientific programme

Abstract

In January 1993 the European Science Foundation launched a four-year scientific programme on geographical information systems. The programme aims at overcoming the existing fragmentation of GIS research in Europe and addresses three key areas: European-wide data base design, data integration, and social and environmental applications. In each of these areas a number of priorities have been identified which provide the focus of the initiatives and collaborative ventures envisaged by the programme. This article describes the programme's research agenda and sets it in the context of the activities of the European Science Foundation.