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81.
E. J. Berryman B. Wunder A. Ertl M. Koch-Müller D. Rhede K. Scheidl G. Giester W. Heinrich 《Physics and Chemistry of Minerals》2016,43(2):83-102
The crystal structures of synthetic K-dravite [XKYMg 3 Z Al 6 T Si6O18(BO3) 3 V (OH) 3 W (OH)], dravite [XNaYMg 3 Z Al 6 T Si6O18(BO3) 3 V (OH) 3 W (OH)], oxy-uvite [XCaYMg 3 Z Al 6 T Si6O18(BO3) 3 V (OH) 3 W O], and magnesio-foitite [X?Y(Mg2Al)ZAl 6 T Si6O18(BO3) 3 V (OH) 3 W (OH)] are investigated by polarized Raman spectroscopy, single-crystal structure refinement (SREF), and powder X-ray diffraction. The use of compositionally simple tourmalines characterized by electron microprobe analysis facilitates the determination of site occupancy in the SREF and band assignment in the Raman spectra. The synthesized K-dravite, oxy-uvite, and magnesio-foitite have significant Mg–Al disorder between their octahedral sites indicated by their respective average 〈Y–O〉 and 〈Z–O〉 bond lengths. The Y- and Z-site compositions of oxy-uvite (YMg1.52Al1.48(10) and ZAl4.90Mg1.10(15)) and magnesio-foitite (YAl1.62Mg1.38(18) and ZAl4.92Mg1.08(24)) are refined from the electron densities at each site. The Mg–Al ratio of the Y and Z sites is also determined from the relative integrated peak intensities of the Raman bands in the O–H stretching vibrational range (3250–3850 cm?1), producing values in good agreement with the SREF data. The unit cell volume of tourmaline increases from magnesio-foitite (1558.4(3) Å3) to dravite (1569.5(4)–1571.7(3) Å3) to oxy-uvite (1572.4(2) Å3) to K-dravite (1588.1(2) Å3), mainly due to lengthening of the crystallographic c-axis. The increase in the size of the X-site coordination polyhedron from dravite (Na) to K-dravite (K) is accommodated locally in the crystal structure, resulting in the shortening of the neighboring O1–H1 bond. In oxy-uvite, Ca2+ is locally associated with a deprotonated W (O1) site, whereas vacant X sites are neighbored by protonated W (O1) sites. Increasing the size of the X-site-occupying ion does not detectably affect bonding between the other sites; however, the higher charge of Ca and the deprotonated W (O1) site in oxy-uvite are correlated to changes in the lattice vibration Raman spectrum (100–1200 cm?1), particularly for bands assigned to the T 6O18 ring. The Raman spectrum of magnesio-foitite shows significant deviations from those of K-dravite, dravite, and oxy-uvite in both the lattice and O–H stretching vibrational ranges (100–1200 and 3250–3850 cm?1, respectively). The vacant X site is correlated with long- and short-range changes in the crystal structure, i.e., deformation of the T 6O18 ring and lengthening of the O1–H1 and O3–H3 bonds. However, X-site vacancies in K-dravite, dravite, and oxy-uvite result only in the lengthening of the neighboring O1–H1 bond and do not result in identifiable changes in the lattice-bonding environment. 相似文献
82.
Heinrich Faust 《Pure and Applied Geophysics》1963,55(1):209-216
Zusammenfassung Auswertungen von Raketenmessungen aus den Zeiten der Zirkulationsumstellungen oberhalb 20 km in Frühling und Herbst lassen den Mechanismus dieser Umstellungen erkennen. Sie machen es mit Hilfe der Nullschichtkonzeption möglich, Schemata der allgemeinen Zirkulation der aussertropischen Breiten für die Umstellungszeiten zu gewinnen.
Diese Arbeit wurde unterstützt vom US-Department of the Army, European Research Office, unter Kontrakt Nr. DA-91-591-EUC-2174. 相似文献
Summary Evaluations of wind measurements of the North American Meteorological Rocket Network gave a picture of seasonal variation of the mean winds in stratosphere and mesosphere. The upper part of Fig. 1 refers to the northern stations (Fort Churchill and Fort Greely), the lower part to all others rocket bases. The periods in which the general circulation changes from west to east and from east to west were investigated by half-month means (Figs. 2–4). With the help of the null layer conception — a persistent wind extrem layer reverses the large scale vertical motion — it was possible to derive a scheme of the general circulation of the nontropical latitudes for spring and fall (Figs. 5-a and b).
Diese Arbeit wurde unterstützt vom US-Department of the Army, European Research Office, unter Kontrakt Nr. DA-91-591-EUC-2174. 相似文献
83.
Summary Chemical analyses are used by many authors to describe processes of soil development or laterite formation. In this paper some methods of balance calculations are compared by using samples of a laterite profile on granite from India as testing material. It should be proved which of these calculations of transported matter between the different layers are fitting to the mineral analyses of the laterite profile.Only the results of the method proposed byMashall by using an index-mineral as a base for comparison is confirmed by the mineral analyses.The method ofStreng differs from the above described calculation by using a chemical element as an index. FollowingStreng it is supposed that this element remains unchanged during the weathering processes. But certain chemical elements can be constituents of several minerals of a parent rock. During laterite formation all or almost all minerals of the original rock will be altered and the elements will be transported by weathering solutions. Therefore chemical elements do not serve as an index for balance calculations within a laterite complex.UsingGrossers method one cannot decide wether the abundance of a certain element is caused by accumulation of this element or by lost of other constituents and vice-versa.The use of the method developed byMillot u.Bonifas is not advisable except the structure of the original rock is preserved unaltered during laterite formation. This is not indicated in our case. 相似文献
84.
Dr. Heinrich Faust 《Pure and Applied Geophysics》1949,15(1-2):156-167
Zusammenfassung So wie für das Himmelsbild in einer einheitlichen Luftmasse der vertikale Temperaturgradient die wichtigste Rolle spielt, so erweist sich für den Wetterablauf beim Kaltfrontdurchgang die vertikale Temperaturschichtung im Frontbereich von entscheidender Bedeutung. In den Registrierungen der meteorologischen Elemente zeigt sich meist deutlich der Unterschied zwischen «stabilen» und «labilen» Kaltfronten.
Summary As significant the part, played by the vertical lapse rate of temperature in the appearance of the sky in uniform airmasses, as determinant for weather conditions during the passage of a cold front is the vertical lapse rate of temperature in the frontal area. Generally, the recordings of meteorological instruments show a pronounced difference between «stable» and «unstable» coldfronts.相似文献
85.
86.
Heinrich Kölbel 《International Journal of Earth Sciences》1940,31(5-6):448
Ohne Zusammenfassung 相似文献
87.
The Bremen ocean bottom tiltmeter is a new 6000 m-depth deep sea instrument for autonomous observation of sea floor tilt with
signal periods longer than 7.5 s. The instrument also records vertical acceleration in the frequency range from DC to 1 Hz.
The tiltmeter has an Applied Geomechanics Inc. 756 wide angle biaxial bubble tilt sensor with a resolution of 1.0μ rad (0.2
arc second). A Kistler Corp. MEMS accelerometer of type Servo K-Beam 8330A2.5 with about 10−5m/s2 resolution is used for the acceleration measurements. An Oceanographic Embedded Systems AD24 24 bit Sigma-Delta converter,
which is controlled by a low-power Persistor Inc. embedded computer system of type CF 2, samples the data. The duration of
tiltmeter operation is more than one year, which is controlled by the battery life. In our design the tiltmeter does not need
active leveling devices, i.e., servo motors or other moving components to adjust sensors or frame. We designed the instrument
for deployments by means of a remote operated vehicle. Since May 2005 the Bremen ocean bottom tiltmeter has recorded sea floor
deformation and seismicity level in the Logatchev hydrothermal vent field, Mid-Atlantic Ridge. The tiltmeter is a part of
the monitoring system of project ‘Logatchev Long-Term Environmental Monitoring,’ called LOLEM, of the German research program
with the name ‘Schwerpunktprogramm 1144: Vom Mantel zum Ozean.’ 相似文献
88.
We describe an improved nondestructive technique for density measurement based on gamma-ray absorption that permits construction of high-resolution density profiles of marine sediment cores. The system is capable of resolving vertical density variations with a spatial resolution of 4 mm and absolute accuracy of ± 1%. Comparison with conventional density determination on samples confirms the absolute accuracy. In addition to standard vertical profiling, a core rotation option is included to measure density as a function of rotation angle. This allows the quantification of the variability of density within a layer and detection of inhomogenities like icerafted debris or biogenic structures. 相似文献
89.
Heinrich Eichhorn 《Celestial Mechanics and Dynamical Astronomy》1987,43(1-4):237-241
This sketch is based on the following line of thought. If we understand by (physical or dynamical) time the independent variable in the equations of motion, only quantities which are in a strictly linear relationship with this mechanical — physical time should properly be called time. This excludes therefore such concepts as e.g., sidereal time; in general that Earth Rotation Parameter which is one of the angles which define the orientation in space of a coordinate system fixed in a rigid model Earth. The relationships between these Eulerian angles and the ERP which follow from the theory of motion are discussed, also for the case that the reference system is an arbitrary noninertial system whose relationship (as a function of time) with an inertial system is known. 相似文献
90.
Heinrich Eichhorn 《Celestial Mechanics and Dynamical Astronomy》1984,34(1-4):11-18
A frame of reference is defined asinertial if the coordinates of bodies, predicted with respect to it on the basis of some mechanical principles, agree with those actually observed. It is pointed out that within the framework of Newtonian mechanics the concept of an inertial frame of reference is global, but within the framework of general relativity only local. The relativistic local inertial frame of the Solar System moves with respect to the Newtonian global frame by the amount of geodetic precession. In all rigor, the concept of a globally privileged inertial system has been rendered meaningless by general relativity, even though the concept of an inertial reference frame remains useful in contemporary celestial mechanics. It is further pointed out that none of the practically determined approximations to an inertial frame of reference (e.g., the dynamical reference frame of celestial mechanics, the FK5) must be regarded as adefinition of an inertial system itself. 相似文献