Influence of Sungun copper mine on groundwater quality,NW Iran

Sungun mine is the largest open-cast copper mine in northwest of Iran and is in the primary stages of extraction. The influence of mining activity on the quality of regional groundwater has been taken in to consideration in this study. Accordingly, sampling was done from 22 springs in the study area. The concentrations of major anions and cations as well as Al, Cu, Cd, Cr, Fe, Mn, and Zn were determined for all 22 spring samples in mid-August 2005. The results showed that the concentrations of most of these elements were below the USA Environmental Protection Agency (EPA) limits; however, Al and Fe concentrations are considered to be more than limits in a couple of samples. Despite the fact that geological formations are highly weathered and fractured, the dissolution of minerals within the study area is low. This may be justified by the relatively high alkalinity of local underground water which keeps metals in solid phase and does not let them enter dissolved phase. Additionally, this may be attributed to the high velocity of groundwater flows, which do not give enough time for minerals to dissolve. Correlation coefficients among water chemistry components were determined and the weighted-pair group method was chosen for cluster analysis. Accordingly, high correlation among Al, Fe and Cr, Cd ,and Cu, sodium absorption ratio (SAR) and Na as well as total hardness (TH), Ca, and Mg were observed. The chemical characteristics of water compositions on the basis of major ion concentrations were evaluated on a Schoeller and Piper diagram. Accordingly, the dominant type of water in the region is considered to be Ca-HCO₃ (calcium-bicarbonate type). However, this type of water is also rich in Na, K, and especially Mg. Regarding Schoeller diagram, the current status of local underground water is good for drinking purposes. By commencing mining excavation with designed capacity in near future, the minerals will come into contact with air and water resulting in dissolution, especially in ponds, which, in turn, will increase the concentration of toxic metals in groundwater. Considering future uses of this water including for drinking, irrigation, industrial purposes, etc., precautions must be taken in to consideration.     

Coastal landscape evolution tracked from late Holocene wave-cut benches in the Sinan Archipelago,Southwest Korea

Glacio-isostatic adjustment(GIA)and tectonic activity are important factors in the formation of marine terraces.Late Holocene wave-cut benches in the eastern part of the West Sea of Korea,also called the Yellow Sea,can be divided into two steps:531 cm above sea level(ASL)for the upper bench(T2)and 464-481 cm ASL for the lower bench(T1).Sediments on the benches a re classified into four units,and are interpreted to be beach deposits acco rding to gravel shape,textu re,and seaward inclination.The ove rlying sediment indicates that T2 was formed at approximately 530 cm ASL before 2900 yr BP,and T1 at approximately 460-480 cm ASL before 1520 yr BP.Late Holocene(4000-2000 yr BP)relative sea level(RSL)curves based on GIA models are inconsistent with the wave-cut bench elevations.Comparing T1 and T2 benches to the RSL curves of the West Sea,the upper and the lower benches were uplifted by approximately 5-8 m and 4-7 m,respectively.Although the area is several hundred kilometers away from plate boundaries,the high frequency of earthquakes in the West Sea may have induced the uplift of wave-cut benches during the last 2000 years.These indicate that the west coast of the Korean Peninsula(KP)should no longer be considered an area of subsidence,but be assigned to a regime of uplift during the late Holocene.     

Potential increase of flood hazards in Korea due to global warming from a high-resolution regional climate simulation

Because of the importance of the changes in the hydrologic cycle, accurate assessment of precipitation characteristics is essential to understand the impact of climate change due to global warming. This study investigates the changes in extreme precipitation with sub-daily and daily temporal scales. For a fine-scale climate change projection focusing on the Korean peninsula (20 km), we performed the dynamical downscaling of the global climate scenario covering the period 1971?C2100 (130-year) simulated by the Max-Planck-Institute global climate model, ECHAM5, using the latest version of the International Centre for Theoretical Physics (ICTP) regional climate model, RegCM3. While annual mean precipitation exhibits a pronounced interannual and interdecadal variability, with the increasing or decreasing trend repeated during a certain period, extreme precipitation with sub-daily and daily temporal scales estimated from the generalized extreme value distribution shows consistently increasing pattern. The return period of extreme precipitation is significantly reduced despite the decreased annual mean precipitation at the end of 21^st century. The decreased relatively weak precipitation is responsible for the decreased total precipitation, so that the decreased total precipitation does not necessarily mean less heavy precipitation. Climate change projection based on the ECHAM5-RegCM3 model chain clearly shows the effect of global warming in increasing the intensity and frequency of extreme precipitation, even without significantly increased total precipitation, which implies an increased risk for flood hazards.     

Application of hybrid‐simulation to fragility assessment of the telescoping self‐centering energy dissipative bracing system

Substructure hybrid simulation has been the subject of numerous investigations in recent years. The simulation method allows for the assessment of the seismic performance of structures by representing critical components with physical specimens and the rest of the structure with numerical models. In this study the system level performance of a six‐storey structure with telescoping self‐centering energy dissipative (T‐SCED) braces is validated through pseudo‐dynamic (PsD) hybrid simulation. Fragility curves are derived for the T‐SCED system. This paper presents the configuration of the hybrid simulation, the newly developed control software for PsD hybrid simulation, which can integrate generic hydraulic actuators into PsD hybrid simulation, and the seismic performance of a structure equipped with T‐SCED braces. The experimental results show that the six‐storey structure with T‐SCED braces satisfies performance limits specified in ASCE 41. Copyright © 2013 John Wiley & Sons, Ltd.     

Degradation of crude oil in a contaminated tidal flat area and the resilience of bacterial community

Crude oil spills, Hebei Spirit in South Korea, is considered as one of the worst environmental disasters of the region. Our understanding on activation of oil-degrading bacteria and resilience of microbial community in oil contaminated sites are limited due to scarcity of such event. In the present study, tidal flat sediment contaminated by the oil spill were investigated for duration of 13 months to identify temporal change in microbial community and functional genes responsible for PAH-degradation. The results showed predominance of previously known oil-degrading genera, such as Cycloclasticus, Alcanivorax, and Thalassolituus, displaying significant increase within first four months of the accident. The disturbance caused by the oil spill altered the microbial community and its functional structures, but they were almost restored to the original state after 13 months. Present study demonstrated high detoxification capacity of indigenous bacterial populations in the tidal flat sediments and its resilience of microbial community.     

A time‐domain seismic SSI analysis method for inelastic bridge structures through the use of a frequency‐dependent lumped parameter model

It is highlighted in the past that the soil–structure interaction phenomenon can produce a significant alteration on the response of a bridge structure. A variety of approaches has been developed in the past, which is capable of tackling the soil–structure interaction problem from different perspectives. The popular approach of a discretized truncated finite element model of the soil domain is not always a numerically viable solution, especially for computationally demanding simulations such as the probabilistic fragility analysis of a bridge structure or the real time hybrid simulation. This paper aims to develop a complete modeling procedure that is capable of coping with the soil–structure interaction problem of inelastic bridge structures through the use of a frequency dependent lumped parameter assembly. The proposed procedure encounters accuracy and global stability issues observed on past methods while maintaining the broad applicability of the method by any commercial FEM software. A case study of an overpass bridge structure under earthquake excitations is illustrated in order to verify the proposed method. Copyright © 2015 John Wiley & Sons, Ltd.     

Uncertainty analysis for the integration of seismic and controlled source electro‐magnetic data

We study the appraisal problem for the joint inversion of seismic and controlled source electro‐magnetic (CSEM) data and utilize rock‐physics models to integrate these two disparate data sets. The appraisal problem is solved by adopting a Bayesian model and we incorporate four representative sources of uncertainty. These are uncertainties in 1) seismic wave velocity, 2) electric conductivity, 3) seismic data and 4) CSEM data. The uncertainties in porosity and water saturation are quantified by a posterior random sampling in the model space of porosity and water saturation in a marine one‐dimensional structure. We study the relative contributions from the four individual sources of uncertainty by performing several statistical experiments. The uncertainties in the seismic wave velocity and electric conductivity play a more significant role on the variation of posterior uncertainty than do the seismic and CSEM data noise. The numerical simulations also show that the uncertainty in porosity is most affected by the uncertainty in the seismic wave velocity and that the uncertainty in water saturation is most influenced by the uncertainty in electric conductivity. The framework of the uncertainty analysis presented in this study can be utilized to effectively reduce the uncertainty of the porosity and water saturation derived from the integration of seismic and CSEM data.     

Model updating method for substructure pseudo‐dynamic hybrid simulation

Substructure hybrid simulation has been actively investigated and applied to evaluate the seismic performance of structural systems in recent years. The method allows simulation of structures by representing critical components with physically tested specimens and the rest of the structure with numerical models. However, the number of physical specimens is limited by available experimental equipment. Hence, the benefit of the hybrid simulation diminishes when only a few components in a large system can be realistically represented. The objective of the paper is to overcome the limitation through a novel model updating method. The model updating is carried out by applying calibrated weighting factors at each time step to the alternative numerical models, which encompasses the possible variation in the experimental specimen properties. The concept is proposed and implemented in the hybrid simulation framework, UI‐SimCor. Numerical verification is carried out using two‐DOF systems. The method is also applied to an experimental testing, which proves the concept of the proposed model updating method. Copyright © 2013 John Wiley & Sons, Ltd.     

SHRIMP U–Pb zircon ages of pyroclastic rocks in the Bansong Group, Taebaeksan Basin, South Korea and their implication for the Mesozoic tectonics

The Bansong Group (Daedong Supergroup) in the Korean peninsula has long been considered to be an important time marker for two well-known orogenies, in that it was deposited after the Songnim orogeny (Permian–Triassic collision of the North and South China blocks) but was deformed during the Early to Middle Jurassic Daebo tectonic event. Here we present a new interpretation on the origin of the Bansong Group and associated faults on the basis of structural and geochronological data. SHRIMP (Sensitive High-Resolution Ion MicroProbe) U–Pb zircon age determination of two felsic pyroclastic rocks from the Bansong Group formed in the foreland basin of the Gongsuweon thrust in the Taebaeksan Basin yielded ages of 186.3 ± 1.5 and 187.2 ± 1.5 Ma, respectively, indicating the deposition of the Bansong Group during the late Early Jurassic. Inherited zircon component indicates ca. 1.9 Ga source material for the volcanic rocks, agreeing with known basement ages.The Bansong Group represents syntectonic sedimentation during the late Early Jurassic in a compressional regime. During the Daebo tectonic event, the northeast-trending regional folds and thrusts including the Deokpori (Gakdong) and Gongsuweon thrusts with a southeast vergence developed in the Taebaeksan Basin. This is ascribed to deformation in a continental-arc setting due to the northwesterly orthogonal convergence of the Izanagi plate on the Asiatic margin, which occurred immediately after the juxtaposition of the Taebaeksan Basin against the Okcheon Basin in the late stage of the Songnim orogeny. Thus, the Deokpori thrust is not a continental transform fault between the North and South China blocks, but an “intracontinental” thrust that developed after their juxtaposition.     

Surface complexation of Pb(II) by hexagonal birnessite nanoparticles

Natural hexagonal birnessite is a poorly crystalline layer type Mn(IV) oxide precipitated by bacteria and fungi which has a particularly high adsorption affinity for Pb(II). X-ray spectroscopic studies have shown that Pb(II) forms strong inner-sphere surface complexes mainly at two sites on hexagonal birnessite nanoparticles: triple corner-sharing (TCS) complexes on Mn(IV) vacancies in the interlayers and double edge-sharing (DES) complexes on lateral edge surfaces. Although the TCS surface complex has been well characterized by spectroscopy, some important questions remain about the structure and stability of the complexes occurring on the edge surfaces. First-principles simulation techniques such as density functional theory (DFT) offer a useful way to address these questions by providing complementary information that is difficult to obtain by spectroscopy. Following this computational approach, we used spin-polarized DFT to perform total-energy-minimization geometry optimizations of several possible Pb(II) surface complexes on model birnessite nanoparticles similar to those that have been studied experimentally. We first validated our DFT calculations by geometry optimizations of (1) the Pb-Mn oxyhydroxide mineral, quenselite (PbMnO₂OH), and (2) the TCS surface complex, finding good agreement with experimental structural data while uncovering new information about bonding and stability. Our geometry optimizations of several protonated variants of the DES surface complex led us to conclude that the observed edge-surface species is very likely to be this complex if the singly coordinated terminal O that binds to Pb(II) is protonated. Our geometry optimizations also revealed that an unhydrated double corner-sharing (DCS) species that has been proposed as an alternative to the DES complex is intrinsically unstable on nanoparticle edge surfaces, but could become stabilized if the local coordination environment is well-hydrated. A significant similarity exists in the structural parameters for the TCS complex and those for a DCS edge-surface complex that is protonated in the same manner as the optimal DES complex, which could complicate detecting the DCS complex in X-ray absorption spectra.