On the Problem of Differential Payment for the Use of Different-Quality Surface Waters in Ukraine

The evolution of views and practical decisions regarding the problem of collecting payment for the use of surface waters with regard to their quality in the former USSR and present-day Ukraine is discussed. A simple and feasible method is proposed for differentitation of regional (basin) rates of payment for the use of surface water in Ukraine with allowance made for its quality assessed based on a system of environmental classifications.     

冬小麦遥感冠层温度监测土壤含水量的试验研究

在冬小麦主要生育期(2002年4月初到5月底),对不灌溉的冬小麦测定了冠层温度、地温、气温以及土壤含水量,计算了冠气温差且分析了冠层温度和冠气温差与不同土层厚度的土壤含水量相关关系。结果表明:14:00的冠层温度能较好地反映20cm土层的土壤含水量变化,但与其它各土层相关性有较大的波动性;14:00的冠气温差能较好地反映40cm以上土层的土壤含水量变化,二者的相关性很高,在20cm、40cm土层,两者相关系数R2分别为0.98866、0.99389,这为用区域遥感数据反演主要生育期冬小麦的冠气温差进而监测区域40cm土壤含水量提供了实验性的依据;拔节期和灌浆期,用14:00冠气温差来拟合各土壤层的土壤含水量有较高的精度,从而为用区域遥感数据监测区域土壤含水量提供了经验性的模型。     

基于GIS的孔隙水文地质层三维空间离散方法

针对自然界中孔隙水文地质层空间分布的不连续性与厚度分布的不均匀性,研究基于GIS的孔隙水文地质层三维空间离散实现的技术路线,提出基于GIS的孔隙水文地质层不规则六面体元的三维空间离散方法.该法不仅能最大限度地保证不规则六面体元中水文地质层类型的一元性,而且可充分利用GIS的空间分析与数据的自动提取功能,快速提取各个计算结点上空间位置坐标与各类计算参数,大大缩短水文地质模型空间离散与相关数据文件组织所需的时间,提高地下水三维有限差分数值模拟的时效性,具有较高的实用价值.     

碳酸岩Sr、Nd、Pb 同位素地球化学研究评述

碳酸岩是出露相对较少的幔源岩石，其中Sr与Nd是研究地幔物质组成的主要对象之一。本文统计了世界上主要碳酸岩的锶、钕、铅同位素组成特征；研究显示，碳酸岩源区主要是洋岛玄武岩高U／Pb的HIMU端员和富集端员(EM1或EM2)的混合作用；此外大部分碳酸岩的锶、钕同位素落在大洋玄武岩范围内；这些均表明其成因与地慢柱有密切联系。碳酸岩及与之共生的硅酸岩的同源或独立源区模式部很难充分解释两者同位素组成特征，逭反映碳酸岩的演化模式涉及更复杂的过程。可能是俯冲作用使碳酸岩源区经历不同时间和程度的富集、亏损过程导致地幔源区成分不均一。     

Long term atmospheric deposition as the source of nitrate and other salts in the Atacama Desert, Chile: New evidence from mass-independent oxygen isotopic compositions

Isotopic analysis of nitrate and sulfate minerals from the nitrate ore fields of the Atacama Desert in northern Chile has shown anomalous ¹⁷O enrichments in both minerals. Δ¹⁷O values of 14-21 ‰ in nitrate and 0.4 to 4 ‰ in sulfate are the most positive found in terrestrial minerals to date. Modeling of atmospheric processes indicates that the Δ¹⁷O signatures are the result of photochemical reactions in the troposphere and stratosphere. We conclude that the bulk of the nitrate, sulfate and other soluble salts in some parts of the Atacama Desert must be the result of atmospheric deposition of particles produced by gas to particle conversion, with minor but varying amounts from sea spray and local terrestrial sources. Flux calculations indicate that the major salt deposits could have accumulated from atmospheric deposition in a period of 200,000 to 2.0 M years during hyper-arid conditions similar to those currently found in the Atacama Desert. Correlations between Δ¹⁷O and δ¹⁸O in nitrate salts from the Atacama Desert and Mojave Desert, California, indicate varying fractions of microbial and photochemical end-member sources. The photochemical nitrate isotope signature is well preserved in the driest surficial environments that are almost lifeless, whereas the microbial nitrate isotope signature becomes dominant rapidly with increasing moisture, biologic activity, and nitrogen cycling. These isotopic signatures have important implications for paleoclimate, astrobiology, and N cycling studies.