Remote sensing of substances in water

Remote sensing of water colour and its application to the mapping of pigments, suspended matter and other substances by means of airborne and spaceborne sensors is discussed. After an introduction to the physical process involved, the methods for a quantitative interpretation especially of CZCS data are indicated. Applications towards the monitoring of coastal pollution, of algae blooms and of dynamic processes are shown by means of selected examples. Multispectral scanner and imaging spectrometer technologies are discussed with special reference to NASA's Earth Observation System and ESA's Earth Observation Programme.     

Chronostratigraphy and paleoclimatic meaning of cryogenic deformations in the Central European loess

Cryoturbations in loess reflect cold and wet environments but not necessarily permafrost. Only flat bottomed cryoturbations are indicative of it. Outside the permafrost zone they occur during the wet period of the last glaciation: during the early Weichselian, the lower pleniglacial, the end of the middle pleniglacial and the late glacial. Their morphology ist related to the frost susceptibility of the superimposed layers, expressed in form of differential frost heaving, ruled by the drainage quality and the frost susceptibility gradient. Their diagenesis is discussed.     

Marble mylonites in the Bancroft shear zone, Ontario, Canada: microstructures and deformation mechanisms

Mylonitization of medium-grade marbles in the Bancroft shear zone, Ontario, Canada, is characterized by decreasing grain-size of both calcite and graphite, and a variety of textures. Calcite grain-sizes vary from several millimeters in the protolith, to 50–200 μm in mylonite, to <30 μm in ultramylonite. Corresponding calcite grain shapes are equant in the protolith, elongate in protomylonite (first-developed dimensional preferred orientation), equant in coarse mylonite, elongate in fine mylonite (second-developed dimensional preferred orientation) and generally equant in ultramylonite, which suggests that external energy (applied stress) that tends to elongate grains competed with internal energy sources (e.g. distortional strain) that favor equant shapes. Graphite grain-size changes from several millimeters to centimeters in the protolith to submicroscopic in ultramylonite. In the mylonitic stages, graphite is present as dark bands, while in the ultramylonitic stage it is preserved as a fine coating on calcite grains.Based on textural evidence, twinning (exponential creep; regime I), dynamic recrystallization (power law creep; regime II) and possibly grain boundary sliding superplasticity (regime III) are considered the dominant deformation mechanisms with increasing intensity of mylonitization; their activity is largely controlled by calcite grain-size. Calcite grain-size reduction occurred predominantly by the process of rotation recrystallization during the early stages of mylonitization, as indicated by the occurrence of core and mantle or mortar structures, and by the grain-size of subgrains and recrystallized grains. Grain elongation in S-C structures indicates the activity of migration recrystallization; these structures are not the result of flattening of originally equant grains. Differential stress estimates in coarse mylonites and ultramylonites, based on recrystallized grain-size, are 2–5 and 14–38 MPa, respectively. Initial grain-size reduction of graphite occurred by progressive separation along basal planes, analogous to mica fish formation in quartzo-feldspathic mylonites.Calcite-graphite thermometry on mylonitic and ultramylonitic samples shows that the metamorphic conditions during mylonitization were 475 ± 50°C, which, combined with a differential stress value of 26 MPa, gives a strain rate of 1.2 x 10⁻¹⁰s⁻¹ based on constitutive equations; corresponding displacement rates are <38 mmyr⁻¹.     

The first and the second e of the extreme value distribution,EV1

In the peak over threshold model resulting in the Extreme-value distribution, type I, (EV1) the firste of the distribution function is based on the Poisson number of exceedances, and the seconde arises from the Exponentially distributed magnitudes.This paper, on the one hand, generalises the Poisson model to the (positive and negative) Binomial distribution, and, on the other hand, the Exponential distribution is generalised to the Generalised Pareto distribution. Lack of fit with respect to the Poisson and Exponential distribution is measured by statistics derived from those which would be locally most powerful if the estimates of the location and scale parameter were equal to the true parameter values. Ways of combining both statistics are discussed.     

Long-range weather forecasts through numerical and empirical methods

There has been much improvement in numerical weather prediction since L.F. Richardson (1922, Weather Prediction by Numerical Process, Cambridge University Press, Cambridge, p. 236) wrote his famous book. NWP has primarily been successful in improving day-by-day forecasts starting from an observed detailed Initial Condition (IC) out to about a week. The purpose of this paper is to discuss first the state of the art in long-range NWP by presenting results of a new large numerical experiment (named DERF90; from Dynamical Extended Range Forecasting in 1990 out to 90 days) conducted at the National Meteorological Center (NMC) during the summer and autumn of 1990 (Section 2). One hundred and twenty eight 90-day global forecasts were made from successive daily initial conditions (IC), thus giving us ample opportunity to assess skill of forecasts at lead times beyond 1 week.We then move on to define the notion of a limit of predictability (LOP), and following a procedure by Lorenz (1982), give a numerical estimate of the LOP using the DERF90 data set. We then produce a list of reasons, as to why this estimate (LOP = 18 days) should not be taken too literally. In particular, we argue that the LOP varies as a function of the flow itself, and it would be (much) larger if we had, as we will ultimately, a coupled ocean-atmosphere model for making long-lead forecasts. Last, but not least, we present results of empirical forecasts that point to modest but significant skill well beyond the traditional LOP (a few weeks).A specific recent example of empirical forecasting is discussed. Through Canonical Correlation Analysis (CCA), experimental forecasts are being made for the United States surface temperatures at lead times of several seasons. While modest, the skill is significant in that it defies the existence or a 3-week LOP, and so demonstrates the potential for model improvements.     

A combined pyrolysis mass spectrometric and light microscopic study of peatified Calluna wood isolated from raised bog peat deposits

Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids.     

Fluid inclusion and cathodoluminescence studies on fluorite from the Kerio valley, Kenya

The Kerio valley lies between the Elgeyo escarpment and the Tugen hills which mark the western margin of the Kenya rift valley. The main fluorite deposits are located in the southern part of the valley at Kimwarer, Choff and Kamnaon.Three types of inclusion fillings were identified: Liquid+Vapour, Liquid+Daughter Minerals and Liquid. The L+V type is dominant. Inclusions occur as clusters, trails along the crystal growth zones and as isolated ones. Low salinities, apparently lower than the 5% wt. NaCl equivalent, were established. Homogenization temperatures suggest that fluorite mineralization took place at different stages and at temperatures between 120 and 180 °C. Isolated readings above 180°C may be referring to the original inclusions in limestone. These measurements and the absence of CO₂ in the inclusions, as well as the occurrence of vugs and crustifications with fluorite, suggest that mineralization took place at relatively shallow depths.Emission spectrum lines representing Eu²⁺, Dy³⁺, Tb³⁺ and Sm³⁺ in fluorite were identified. Sm³⁺ was detected only in the pinkish luminescence of veined fluorite, whereas the pinkish zone in banded fluorite contains Tb³⁺. Eu²⁺ which gives the strongest emission lines in the blue part of the visible spectrum, apparently is responsible for the strong blue cathodoluminescence (CL) in fluorite. The dominance of Eu²⁺ peaks further points to the fact that fluorite mineralization in the Kerio valley took place in an environment that was enriched in Lanthanide Rare Earth Elements (LREE). The presence of rare earths and radioactive elements in fluorite points towards their enrichment in the environment of fluorite mineralization. A juvenile origin of mineral forming solutions is proposed.Two generations of fluorite were established: allotriomorphic fluorite, forming the matrix, and the idiomorphic variety, occurring either in barite or in druzes in early fluorite. Barite in turn forms idiomorphic crystals in allotriomorphic fluorite. Relics of calcite occur in both K-feldspars and in early fluorite. Oxides and hydroxides of Fe, Mn, Ti and Al commonly occur in open spaces in fluorite. Of significance is the presence of gold in fluorite. Fluorite mineralization is of hydrothermal origin in the post-Miocene era and was formed as a result of metasomatic replacement of marble and open space fillings.     

Response of a marine ice sheet to changes at the grounding line

A numerical model was designed to study the stability of a marine ice sheet, and used to do some basic experiments. The ice-shelf/ice-sheet interaction enters through the flow law in which the longitudinal stress is also taken into account. Instead of applying the model to some (measured) profile and showing that this is unstable (as is common practice in other studies), an attempt is made to simulate a whole cycle of growth and retreat of a marine ice sheet, although none of the model sheets is particularly sensitive to changes in environmental conditions. The question as to what might happen to the West Antarctic Ice Sheet in the near future when a climatic warming can be expecied as a result of the CO₂ effect, seems to be open for discussion again. From the results presented in this paper one can infer that a collapse, caused by increased melting on the ice shelves, is not very likely.     

Paleomagnetism of the Cambro-Ordovician McClure Mountain alkalic complex,Colorado

The Middle to Late Cambrian loop in the North American apparent polar wander path (APWP) has been variously attributed to tectonic rotations, remagnetizations and primary magnetizations. Although no primary thermal remanent magnetizations or primary detrital remanent magnetizations have as yet been demonstrated, the temporally self-consistent nature of the loop has been used as an argument for primary magnetizations. We have studied535 ± 5Ma nepheline syenites and syenites of the McClure Mountain alkalic complex, as well as495 ± 10Ma red trachyte dikes which intruded the complex, in an effort to find a primary TRM. Because Zijderveld analysis yielded consistent results for only one trachyte dike, remagnetization great-circle analysis was employed, giving a pole for the trachyte dikes at the tip of the loop (43°N, 114°E), while the syenites and nepheline synenites gave a pole at the base of the loop (18°N, 142°E). The magnetic carrier in the trachytes is hematite which apparently formed during a pervasive hydrothermal alteration. KAr whole rock dating of the trachytes suggests a Pennsylvanian age for the alteration, and thus a late Paleozoic remagnetization of the trachytes. Thus, the low-latitude Cambrian pole is confirmed, but we find no evidence in this study to support the primary nature of the Cambrian APWP.