西湖凹陷平北地区烃源岩特征及生排烃史

为了综合确定平北地区的主力烃源岩,深化其油气成藏动力学过程研究,在烃源岩分布特征及有机质丰度、类型和成熟度分析的基础上,应用舍油气盆地数值模拟技术,定量恢复了研究区主要烃源岩层系的生排烃历史。研究表明,平北地区主要发育始新统平湖组、渐新统花港组两套烃源岩系,其中平湖组暗色泥岩为主力烃源岩,具较高的有机质丰度、成熟度、生排烃强度与排烃效率;以平湖组为源岩的油气系统应是本区油气勘探的主要目标。     

Dynamics of arrays of floating point-absorber wave energy converters with inter-body and bottom slack-mooring connections

If point absorbers are employed in the extensive exploitation of the offshore wave energy resource, they should be deployed in arrays, the distance between the elements in the array being possibly tens of meters. In such cases, it may be more convenient that the array is spread moored to the sea bottom through only some of its elements, located in the periphery, while the other array elements are prevented from drifting and colliding with each other by connections to adjacent elements. An array of identical floating point absorbers located at the grid points of an equilateral triangular grid is considered in the paper. A spread set of slack-mooring lines connect the peripheric floaters to the bottom. A weight is located at the centre of each triangle whose function is to pull the three floaters towards each other and keep the inter-body mooring lines under tension. The power take-off system (PTO) is a linear damper activated by the buoy heaving motion. The whole system–buoys, moorings and power take-off systems–is assumed linear, so that a frequency domain analysis may be employed. Hydrodynamic interference between the oscillating buoys in array is accounted for. Equations are presented for a set of three identical point absorbers. This is then extended to more complex equilateral triangular grid arrays. Results from numerical simulations, with regular and irregular waves, are presented for the motions and power absorption of hemispherical converters in arrays of three and seven elements and for different mooring parameters and wave incidence angles. Comparisons are given with the unmoored and independently-moored buoy situations.     

海州湾潮间带大型底栖动物的分布特征

于2002年6月对海州湾3种底质的潮间带底栖动物进行了采样分析.结果显示,该区被鉴定出的大型底栖动物共有98种,其中多毛类为13种、软体动物为53种、甲壳类为25种、棘皮动物为2种、其它类动物为5种,软体动物和甲壳类的种类可占80%;该区潮间带大型底栖动物的平均生物量和平均栖息密度分别为257.30 g/m2和953个/m2,软体动物生物量(201.19 g/m2)和栖息密度(727 个/m2)分别占总数的78%和76%.经底栖动物种类相似性聚类分析和多维尺度排序,可将该区潮间带大型底栖动物划分为岩礁、沙滩和泥沙滩3个群落.通过对3个底栖动物群落的生态特征及相关环境因子分析得出:对于种类,泥沙滩群落 > 岩礁群落 > 沙滩群落;对于生物量、息栖密度、多样性指数和均匀度指数,岩礁群落 > 泥沙滩群落 > 沙滩群落;泥沙滩群落中的TE断面优势种分布显著而使多样性指数和均匀度指数明显低于其它两条泥沙滩断面.沙滩群落和岩礁群落的底栖动物分布分别与海水浴场和货运码头较多的人为活动影响有关,而泥沙滩群落的分布差异主要与海岸开敞度、海流潮汐作用、滩涂贝类养殖及优势种分布影响有关.泥沙滩是该区经济贝类的重要养殖场所,为使养殖种类健康生长,建议对沿岸排污口水质及养殖区沉积物环境质量进行定期监测.     

激发态质子转移分子2-(2'-羟基苯基)苯并噻唑溶液的全光开关效应

研究了激发态质子转移(ESPT)分子2-(2'-羟基苯基)苯并噻唑(HBT)在不同极性溶剂中的光开关行为,探讨了溶剂极性对HBT分子光开光效应的影响.揭示了光开关脉冲信号的形成原因,建立了基于光诱导HBT分子激发态非线性折射效应的皮秒全光开关的理论模型.根据对时间响应函数的理论计算和实验结果分析,确定了光开关脉冲信号下降前沿和上升后沿的形成机理以及影响因素,并提出了增强光开关信号下降前沿的关断深度,提升上升后沿的恢复速度的有效途径和方法.本文工作为制成皮秒量级关断,微秒甚至纳秒量级重新打开的快速全光开关器     

银纳米杆高温熔化断裂弛豫性能的原子级模拟研究

采用分子动力学模拟方法,研究了不同长度银纳米杆在不同温度弛豫过程中的结构演变过程.结果表明:银纳米杆存在一与杆长相关的临界熔断温度,该临界熔断温度随杆长增加而显著降低.当温度大于熔点而小于临界熔断温度时,体系形成一个高度无序的球形团簇,而温度大于临界熔断温度时,体系则熔断成两个球形团簇.并给出了银纳米杆的产生该熔断现象的机理.     

Pristine or altered: low-Mg calcite shells survived from massive dolomitization? A case study from Miocene carbonates

Low-Mg calcite shells have been widely used to reconstruct the chemistry of ancient seawater. There is always a question: are the shells chemically pristine? This paper presents the isotope and elemental geochemistry of low-Mg calcite bivalve shells in late Miocene platform carbonates, SE Spain. The platform carbonates were extensively dolomitized, and limestone is restricted to older stratal units, and to units mainly in topographically higher and more landward strata. Low-Mg calcite oyster shells were completely dissolved out in the basinward dolomite, but are well preserved in the limestone. These shells appear to retain the original growth microstructures, based on hand samples. Under the microscope, however, dissolution and recrystallization, as well as pristine growth lines are all present. Sr isotopes in these shells range from that of normal Miocene seawater to radiogenic values. δ¹⁸O and δ¹³C values, and Mg, Sr, and Na concentrations in these shells are rather variable. The high end members are consistent with the typical values of modern/late Miocene normal-seawater low-Mg calcite shells, whereas the low end members are close to those of diagenetic calcite cements, which have low δ¹⁸O, δ¹³C, Sr and Na values, and radiogenic Sr. The Nijar shells were altered physically and chemically to different degrees by diagenesis, although these shells are consistent with some “criteria” of unalteration. The isotopic and trace-element data collected in altered and pristine (or less altered) portions coexisting in the same shells are clearly differentiable. Quantitative simulation of covariations of geochemical pairs indicates that solid mixing of unaltered and altered portions by sampling is consistent with the variations in isotopic and elemental data recorded in the Nijar shells. The geological significance of this study is that ancient fabric-retentive calcite shells may have been altered geochemically although they may appear pristine. Calcite shells that underwent intensive diagenesis should be examined rigorously under the microscope, coupled with investigations of multiple geochemical proxies to assess chemical alteration. Only the data of unaltered shells can be used to reconstruct the chemistry of ancient seawater.     

无结构网格二维河口海岸水动力数值模式的建立及其应用

为完全拟合河口近海复杂岸线和工程结构以及有效局部加密,设计并建立了一个无结构三角形网格二维河口海岸水动力数值模式。空间离散主要基于有限体积法以保证守恒性,时间积分采用预估修正法以提高精度。水位在三角形网格中心通过连续方程求解;水平x方向和y方向的流速U和V均在网格边中点上通过动量方程求解。流速平流项的求解中采用了TVD格式。TVD流速平流通量为一个一阶迎风格式通量和一个二阶格式通量的组合,一阶格式通量和二阶格式通量根据流速的局部分布情况得出配比,最终组合得到TVD通量。TVD格式具有低耗散和无频散的优点,提高了模式的稳定性。应用实测资料验证建立的模式,结果显示水位、流速和流向的计算值与实测值均符合良好。     

退火对B掺杂纳米金刚石薄膜微结构和电化学性能的影响

采用热丝化学气相沉积法制备B掺杂纳米金刚石薄膜,并对薄膜进行真空退火处理,系统研究了不同退火温度对B掺杂纳米金刚石薄膜的微结构和电化学性能的影响.结果表明,当退火温度升高到800 ℃后,薄膜的Raman谱图中由未退火时在1157,1346,1470,1555 cm^-1处的4个峰转变为只有D峰和G峰,说明晶界上的氢大量解吸附量减少;并且D峰和G峰的积分强度比I_D/I_G值变为最小,即sp²相团簇     

Influence of core property on multi-electron process in slow collisions of isocharged sequence ions with neon

Influence of core property on multi-electron process in the collisions of q=6-9 and 11 isocharged sequence ions with Ne is investigated in the keV/u region. The cross-section ratios of double-, triple-, quadruple- and total multi-electron processes to the single electron capture process as well as the partial ratios of different reaction channels to the relevant multi-electron process are measured by using position-sensitive and time-of-flight techniques. The experimental data are compared with the theoretical predictions including the extended classical over-barrier model, the molecular Columbic barrier model and the semi-empirical scaling law. Results show a core effect on multi-electron process of isocharge ions colliding with Neon, which is consistent with the results of Helium we obtained previously.     

澳大利亚西北陆架中生界生储盖组合特征

澳大利亚西北陆架是一个贫油富气的地区,在近年的勘探开发中显示出广阔的前景。区域上包含4个盆地和1个造山带:北卡那封盆地、柔布克盆地、布劳斯盆地、波拿巴盆地和帝汶—班达褶皱带。西北陆架油气绝大多数集中在中生界。中生界发育4套主要烃源岩:三叠系湖相泥页岩、下—中侏罗统海相和海陆交互相碳质泥岩和煤系、上侏罗统海相页岩及下白垩统海相泥页岩;主要储集岩为中—上三叠统三角洲—边缘海相砂岩、下—中侏罗统砂岩、上侏罗统砂岩和白垩系砂岩;主要区域性盖层是下白垩统海相泥页岩。根据生储盖组合的沉积环境,主要发育海生海储海盖型和陆生陆储陆盖型两大生储盖组合类型。海生海储海盖型生储盖组合广泛分布于西北大陆架,是区域最重要的成藏组合。