Adsorption characteristics of perchloroethylene in natural sandy materials with low organic carbon content

Laboratory batch tests were conducted to investigate the sorption isotherms and sorption kinetics of the chlorinated hydrocarbon perchloroethylene (PCE) in five natural sandy materials with an organic carbon content (f _oc) in the range 0.080–0.540%. The amended non-linear dual-mode model can describe the sorption isotherms in materials with f _oc in the range 0.080–0.090%. For a sample with a much higher f _oc of 0.54%, the absorption isotherm was found to fit a linear model. These results may indicate that organic carbon is not the main factor influencing the sorption isotherm. The sorption kinetics of PCE in samples with f _oc in the range 0.080–0.090% are not first-order and are different from those observed in the samples with higher f _oc. The sorption process in the materials with lower f _oc involves fast sorption, fast desorption and an equilibrium stage. The results may imply that the factors affecting sorption kinetics of PCE in low f _oc media are pore filling and capillary condensation rather than organic carbon content.     

Allocating local groundwater monitoring stations for South Korea using an analytic hierarchy process

A national groundwater-monitoring network consisting of 320 stations has been operated by the Ministry of Construction and Transportation and the Korea Water Resources Corporation since 1995. The network was established as a result of the Groundwater Act of Korea, and a supplementary local groundwater monitoring network containing 10,000 stations will be established throughout the country by the year 2011. A method of allocating stations and organizing the local monitoring network has been developed, based on the analytic hierarchy process (AHP), using pairwise comparison. Several evaluation criteria were selected for determining the required number of the monitoring stations at specific local districts. Weights of the selected criteria were assigned by the pairwise comparison, reflecting hydrogeological conditions and supported by pertinent questions to 93 groundwater experts. To evaluate appropriateness of this method, an example city, Jeonju, was selected where groundwater levels were monitored; seven stations were determined as to be required for the supplementary groundwater-monitoring network. The study demonstrated the usefulness of the AHP. The concepts of the development and the structure of the AHP model can be applied to site or well selections within a particular district.     

Electric charge and magnetic flux on rotating black holes in a force-free magnetosphere

The electric charge on rotating black holes is calculated to be ∼ BJ in the force-free configuration of Ghosh, with a horizon flux of ∼ BM ². This charge is gravitationally weak for B ∼10¹⁵ G , so that the Kerr metric applies. Being similar to the electric charge of a magnetar, both electric charge and magnetic flux should be, in sign and order of magnitude, continuous during stellar collapse into a black hole. Extraction of the rotational energy from newly formed black holes may proceed by interaction with the magnetic field.     

Scattered ground‐roll attenuation using model‐driven interferometry

Scattered ground roll is a type of noise observed in land seismic data that can be particularly difficult to suppress. Typically, this type of noise cannot be removed using conventional velocity‐based filters. In this paper, we discuss a model‐driven form of seismic interferometry that allows suppression of scattered ground‐roll noise in land seismic data. The conventional cross‐correlate and stack interferometry approach results in scattered noise estimates between two receiver locations (i.e. as if one of the receivers had been replaced by a source). For noise suppression, this requires that each source we wish to attenuate the noise from is co‐located with a receiver. The model‐driven form differs, as the use of a simple model in place of one of the inputs for interferometry allows the scattered noise estimate to be made between a source and a receiver. This allows the method to be more flexible, as co‐location of sources and receivers is not required, and the method can be applied to data sets with a variety of different acquisition geometries. A simple plane‐wave model is used, allowing the method to remain relatively data driven, with weighting factors for the plane waves determined using a least‐squares solution. Using a number of both synthetic and real two‐dimensional (2D) and three‐dimensional (3D) land seismic data sets, we show that this model‐driven approach provides effective results, allowing suppression of scattered ground‐roll noise without having an adverse effect on the underlying signal.     

Climate change signal analysis for Northeast Asian surface temperature

Climate change detection, attribution, and prediction were studied for the surface temperature in the Northeast Asian region using NCEP/NCAR reanalysis data and three coupled-model simulations from ECHAM4/OPYC3, HadCM3, and CCCma GCMs (Canadian Centre for Climate Modeling and Analysis general circulation model). The Bayesian fingerprint approach was used to perform the detection and attribution test for the anthropogenic climate change signal associated with changes in anthropogenic carbon dioxide (CO2) and sulfate aerosol (SO42-) concentrations for the Northeast Asian temperature. It was shown that there was a weak anthropogenic climate change signal in the Northeast Asian temperature change. The relative contribution of CO2 and SO42- effects to total temperature change in Northeast Asia was quantified from ECHAM4/OPYC3 and CCCma GCM simulations using analysis of variance. For the observed temperature change for the period of 1959-1998, the CO2 effect contributed 10%-21% of the total variance and the di     

The composition and crystallinity of the near-surface regions of weathered alkali feldspars

Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction.     

Estimating hydraulic conductivity using grain-size analyses, aquifer tests, and numerical modeling in a riverside alluvial system in South Korea

Hydraulic conductivity (K) for an alluvial system in a riverbank filtration area in Changwon City, South Korea, has been studied using grain-size distribution, pumping and slug tests, and numerical modeling. The alluvial system is composed of layers: upper fine sand, medium sand, lower fine sand, and a highly conductive sand/gravel layer at the base. The geometric mean of K for the sand/gravel layer (9.89?×?10^?4 m s^?1), as determined by grain-size analyses, was 3.33 times greater than the geometric mean obtained from pumping tests (2.97?×?10^?4 m s^?1). The geometric mean of K estimates obtained from slug tests (3.08?×?10^?6 m s^?1) was one to two orders of magnitude lower than that from pumping tests and grain-size analyses. K estimates derived from a numerical model were compared to those derived from the grain-size methods, slug tests and pumping tests in order to determine the degree of deviation from the numerical model. It is considered that the K estimates determined by the slug tests resemble the uppermost part of the alluvial deposit, whereas the K estimates obtained by grain-size analyses and pumping tests are similar to those from the numerical model for the sand/gravel layer of the riverside alluvial system.