CAT-scan analysis of sedimentary sequences: An ultrahigh-resolution paleoclimatic tool

Paleoclimate research is essential to determine the natural variability of climate and to place the current climate change into its natural context. The current need is to generate the highest temporal resolution paleoclimatic reconstructions possible in order to assess the natural variability of the climate system, but also to test the ability of numerical models to simulate conditions different from the ones observed with the relatively short instrumental records. In this paper, we show that CAT-scan analysis of sedimentary sequences, with its 1 mm downcore resolution, can be used to identify millennial to seasonal cycles in sedimentary sequences. In examples from the St. Lawrence Estuary, Eastern Canada, spectral analysis of the CAT-scan data from Holocene postglacial sediments revealed millennial- to centennial-scale oscillations possibly associated with either solar variability, changes in relative sea-level or tidal amplitude. Similarly, spectral analysis of Holocene and Sangamonian glaciomarine sequences revealed decadal- to annual-scale oscillations with periods close to the one previously associated with the North Atlantic Oscillation (NAO), whereas spectral analysis of the CAT-scan data from the Sangamonian rhythmites possibly revealed seasonal cycles.     

Regional modeling of carbonaceous aerosols over Europe—focus on secondary organic aerosols

In this study, an improved and complete secondary organic aerosols (SOA) chemistry scheme was implemented in the CHIMERE model. The implementation of isoprene chemistry for SOA significantly improves agreement between long series of simulated and observed particulate matter concentrations. While simulated organic carbon concentrations are clearly improved at elevated sites by adding the SOA scheme, time correlation are impaired at low level sites in Portugal, Italy and Slovakia. At several sites a clear underestimation by the CHIMERE model is noticed in wintertime possibly due to missing wood burning emissions as shown in previous modeling studies. In Europe, the CHIMERE model gives yearly average SOA concentrations ranging from 0.5 μg m ^− 3 in the Northern Europe to 4 μg m ^− 3 over forested regions in Spain, France, Germany and Italy. In addition, our work suggests that during the highest fire emission periods, fires can be the dominant source of primary organic carbon over the Mediterranean Basin, but the SOA contribution from fire emissions is low. Isoprene chemistry has a strong impact on SOA formation when using current available kinetic schemes.     

Influence of the Laurentide Ice Sheet and relative sea‐level changes on sediment dynamics in the Estuary and Gulf of St. Lawrence since the last deglaciation

Physical properties, grain size, bulk mineralogy, elemental geochemistry and magnetic parameters of three sediment piston cores recovered in the Laurentian Channel from its head to its mouth were investigated to reconstruct changes in detrital sediment provenance and transport related to climate variability since the last deglaciation. The comparison of the detrital proxies indicates the succession of two sedimentary regimes in the Estuary and Gulf of St. Lawrence (EGSL) during the Holocene, which are associated with the melting history of the Laurentide Ice Sheet (LIS) and relative sea‐level changes. During the early Holocene (10–8.5 cal. ka BP), high sedimentation rates together with mineralogical, geochemical and magnetic signatures indicate that sedimentation in the EGSL was mainly controlled by meltwater discharges from the local retreat of the southeastern margin of the LIS on the Canadian Shield. At this time, sediment‐laden meltwater plumes caused the accumulation of fine‐grained sediments in the ice‐distal zones. Since the mid‐Holocene, postglacial movements of the continental crust, related to the withdrawal of the LIS (c. 6 cal. ka BP), have triggered significant variations in relative sea level (RSL) in the EGSL. The significant correlation between the RSL curves and the mineralogical, geochemical, magnetic and grain‐size data suggest that the RSL was the dominant force acting on the sedimentary dynamics of the EGSL during the mid‐to‐late Holocene. Beyond 6 cal. ka BP, characteristic mineralogical, geochemical, magnetic signatures and diffuse spectral reflectance data suggest that the Canadian Maritime Provinces and western Newfoundland coast are the primary sources for detrital sediments in the Gulf of St. Lawrence, with the Canadian Shield acting as a secondary source. Conversely, in the lower St. Lawrence Estuary, detrital sediments are mainly supplied by the Canadian Shield province. Finally, our results suggest that the modern sedimentation regime in the EGSL was established during the mid‐Holocene.     

Developing carbon budgets for UK agriculture, land-use, land-use change and forestry out to 2022

This paper derives a notional future carbon budget for UK agriculture, land use, land use change and forestry sectors (ALULUCF). The budget is based on a bottom-up marginal abatement cost curve (MACC) derived for a range of mitigation measures for specified adoption scenarios for the years 2012, 2017 and 2022. The results indicate that in 2022 around 6.36 MtCO₂e could be abated at negative or zero cost. Furthermore, in the same year, over 17% of agricultural GHG emissions (7.85 MtCO₂e) could be abated at a cost of less than the 2022 Shadow Price of Carbon (£34 (tCO₂e)^???1). The development of robust MACCs faces a range of methodological hurdles that complicate cost-effectiveness appraisal in ALULUCF relative to other sectors. Nevertheless, the current analysis provides an initial route map of efficient measures for mitigation in UK agriculture.     

Soil charcoal stability over the Holocene across boreal northeastern North America

The analysis of macroscopic wood charcoal fragments extracted from soils is frequently used as a palaeoecological tool for reconstructing stand-scale forest composition and fire history. Here we explored the putative loss of palaeoecological information due to charcoal degradation through time and in different biogeographical settings. We compared the relationship between charcoal mass and abundance for soil samples from five biogeographical regions of boreal northeastern North America spanning most of the Holocene period. We verified whether charcoal (Ø ≥ 2 mm) conservation differed as a consequence of different taphonomical processes between organic and mineral soil types. We also assessed the mass/abundance relationship as a function of charcoal residence time in soil. Overall, the slope of the regression between charcoal particles mass (g) and abundance (number of particles) was 0.0042. The slope was not significantly different in samples from organic and mineral soil, and all biogeographical regions had similar slope values except one (higher charcoal fragmentation, probably due to high colluvial activity). Charcoal conservation also did not vary according to residence time in soil. This study shows that macroscopic soil charcoal particles resist fragmentation over millennia in different biogeographical settings and under the influence of various taphonomical processes.     

The dynamo basis of solar cycle precursor schemes

We investigate the dynamo underpinning of solar cycle precursor schemes based on direct or indirect measures of the solar surface magnetic field. We do so for various types of mean-field-like kinematic axisymmetric dynamo models, where amplitude fluctuations are driven by zero-mean stochastic forcing of the dynamo number controlling the strength of the poloidal source term. In all stochastically forced models considered, the surface poloidal magnetic field is found to have precursor value only if it feeds back into the dynamo loop, which suggests that accurate determination of the magnetic flux budget of the solar polar fields may hold the key to dynamo model-based cycle forecasting.     

Understanding the evolution of syn-depositional folds: Coupling decompaction and 3D sequential restoration

The analysis of basin dynamics and burial evolution requires a good understanding of sediment compaction. Classically, decompaction of sediments is performed in one dimension at a well location, using either a simple compaction/depth relationship or more complex elasto-plastic models. This paper presents a new approach combining sequential decompaction with 3D restoration to allow for a true 3D basin analysis. Decompaction is performed in 3D after each restoration step, thus taking into account possible tectonic events and lateral thickness variations. Care is taken to apply decompaction to ensure volume continuity especially around faults. This approach is particularly suitable for syn-depositional folds whose growth strata constrain tectonic evolution through time.The proposed approach is applied to the sand-rich turbiditic reservoir analogue of Annot (SE France) where two fictitious wells are used to compare the new 3D technique to a well decompaction analysis. Coupling restoration and decompaction leads to an improved assessment of the basin history: an uplift of the underlying units is identified, which was not detected using decompaction on wells only. Such differences may have a significant impact on possible hydrocarbon maturation models of the basin. Moreover, the geometry of the restored and decompacted models can better constrains the basin history, and influence our understanding of potential hydrocarbon migration pathways.     

Spectroscopic investigation and theoretical modeling of kaolinite-group minerals and other low-temperature phases

This article summarizes some recent results obtained on the physical properties of environmental minerals, mostly kaolinite-group minerals and Fe- and Al-(hydr)oxides occurring in lateritic soils. The defective structure of these minerals, including impurities, stacking faults and radiation-induced defects, is probed using infrared spectroscopy and electron paramagnetic resonance. Resulting information bears on models of soil formation and transformation mechanisms of minerals in low-temperature environments. We underline the increasing impact of quantum chemical modeling in this field, providing straightforward interpretations of spectroscopic signals and overcoming the limits of fingerprint approaches. Importantly, the first-principles modeling of isotopic fractionation factors provides new links between mineralogical and geochemical investigations of secondary minerals.     

MC‐ICP‐MS Isotope Measurements with Direct Injection Nebulisation (d‐DIHEN): Optimisation and Application to Boron in Seawater and Carbonate Samples

We report here an optimisation of the demountable direct injection high efficiency nebuliser (d‐DIHEN) for isotopic measurements with a Neptune (ThermoFisher Scientific, Bremen, Germany) multi‐collector inductively coupled plasma‐mass spectrometer (MC‐ICP‐MS) and describe a method for boron isotopic ratio determination. With direct injection nebulisation 100% of the analyte was introduced into the ICP‐MS plasma and wash times were drastically reduced for elements such as boron and thorium. Compared to the classical stable introduction system (SIS: double Scott/cyclonic spray chamber), sensitivity for boron was 2–5 times higher with d‐DIHEN and wash times up to ten times shorter. Repeatability of ¹¹B/¹⁰B sample‐calibrator bracketing measurements reached 0.25‰ (2s) for seawater and coral samples. Method accuracy and reproducibility were tested on mixed reference solutions having δ¹¹B values in the ranges ?90 to +40‰ and ?2 to +2.5‰, demonstrating our ability to distinguish δ¹¹B values with differences of only 0.25‰. The international seawater reference material NRCC NASS‐5 (National Research Council, Ottawa, Canada), analysed in different sessions over a 10‐month period, yielded an average δ¹¹B value of +39.89 ± 0.25‰, in the upper range of previously published seawater values. A comparison between δ¹¹B determined by d‐DIHEN MC‐ICP‐MS and positive‐TIMS (P‐TIMS) for four modern corals showed an excellent agreement (with bias of less than 0.4‰).     

Magnetostratigraphy of the Northern Tian Shan foreland,Taxi He section,China

The Tian Shan range formed in the late Cenozoic in response to the northward propagation of deformation related to the India–Eurasia continental collision. Precise timing of the Tian Shan uplift is required to understand possible mechanisms of continental lithosphere deformation and interactions between climate, tectonism and erosion. Here, we provide magnetostratigraphic age control on the northern Chinese Tian Shan foreland successions. A thorough rock magnetic analysis identifies haematite‐ and magnetite‐bearing alluvial fan deposits in the upper portion of the sampled strata as more reliable palaeomagnetic recorders than magnetite‐bearing fluvial and lacustrine deposits that are often maghaemitized in the lower part of the record. As a result, a robust correlation to the geomagnetic polarity time scale is obtained from 6 to 2 Ma while a tentative correlation is proposed from 6 to 16 Ma. Sediment accumulation rates increase from 155 to 260 m Myr^?1 at 3.9±0.3 Ma. This change coincides with a gradual lithologic transition from fluvial (sandstone‐dominated) to alluvial fan (conglomerate‐dominated) deposits that likely records an approaching erosional source related to tectonically increased subsidence rather than differential compaction. Clear evidence for growth strata starting at an estimated age of ～2 Ma provides a minimum age for folding. These results are compared with previous magneotstratigraphic studies from the same and other sections of the northern Tian Shan foreland basin fill, thus enabling a critical assessment of the reliability of magnetostratigraphic dating and the significance of sediment accumulation rate variations with respect to facies variations and growth strata. Our results in the Taxi He section provide a sequence of events that is consistent with enhanced tectonic forcing starting at ～4 Ma, although a climatic contribution must be considered given the close relationship of these ages with the Pliocene climate deterioration.