量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

区域环境地球化学空间信息系统

本文阐述了地理信息系统在环境地球化学中的应用,提出建立区域环境地球化学空间信息系统的方法、功能及组成,并以红枫湖区域环境地球化学空间信息系统为例,作了分析。     

第一代恒星的观测和研究进展

第一代恒星（星族Ⅲ恒星）标志着宇宙从暗物质时代到现在已知的宇宙的转折点。目前对第一代恒星（星族Ⅲ恒星）的观测结果表明，在银河系中还没有发现零金属丰度的恒星，金属丰度[Fe/H]≤-2.5的恒星极少。由于近几年的BPS巡天，银河系中已知的极端贫金属丰度的恒星数目大大增多。目前，可探测到的极端贫金属星的金属丰度[Fe/H]最低约为－4．1。金属丰度在－4到－3之间的恒星大约有100多颗，这些恒星的运动学特性非常类似于其它晕星。然而还没有发现第一代恒星，或金属丰度[Fe/H]≤-5的恒星。关于第一代恒星的形成过程、初始质量函数以及存在于银河系的什么地方，都还没有任何直接的证据。但第一代恒星确实存在。第一代恒星这个谜一般的实体，向观测和理论天文学家提出了巨大挑战。为探测和预言银河系中的第一代恒星，天文学家提出了许多观测方案和理论模型。对有关第一代恒星在观测和理论研究上的进展进行了综述。     

EFFECT OF LIGHT INTENSITY ON THE TOTAL LIPID AND FATTY ACID COMPOSITION OF SIX STRAINS OF MARINE DIATOMS

The effect of light intensity ( 1500 Ix and 5000 Ix) on the total lipid and fatty acid composition of six strains of marine diatoms Cylindrotheca fusiformis (B211 ), Phaeodactylum tricornutum (Bl14, Bl18 and B221) Nitzschia closterium (B222) and Chaetoceros gracilis (B13) was investigated.The total lipids of B13, Bl14, and B211 grown at 5000 Ix were lower than those grown at 1500 Ix. No evident changes were observed in Bl18, B221 and B222. Fatty acid composition changed considerably at different light intensity although no consistent correlation between the relative proportion of a single FA and light intensity. The major fatty acids of the 6 strains were 14:0, 16:0, 16:l(n- 7) and 20:5(n-3) . Cylindrothecafusiformis had high percentage of 20:4n - 6 (9.2 - 10.9% ) . The total polyunsaturated fatty acid /rl all 6 strains decreased with increasing light intensity. The percentage of the highly unsaturated fatty acid eicosapentaenoic acid (EPA) decreased with increasing light intensity in all strains except Chaetoceros gracilis.     

Determination of physical parameters of NGC 2023 using the hyperfine NH3 spectrum

An improved approach is given for deriving the physical parameters of a molecular cloud by its NH₃ rotation-inversion hyperfine spectra. The optical depth τ₀(1, 1) of NH₃ (1,1) is obtained by considering the blending effect of the magnetic hyperfine spectral lines, the (1-1) excitation temperature T_ex (1, 1) is calculated by a two level model, the effect of different collision rate and the thermalization of the (1, 1) inversion lines are discussed, the rotation temperature T_R ( 2, 1) between the NH₃ levels (2, 2) and (1, 1) and the column density N( 1, 1) of the NH₃ (1, 1) inversion level are derived, the results of the total column density from different assumptions for the abundance ratio of ortho-NH₃ and para-NH₃ are also discussed.

This approach is used for the molecular cloud NGC 2023 by using the relevant observed data and its optical depth and other physical parameters are obtained.     

Force-free magnetic fields on curvilinear coordinate surfaces

To seek nonlinear solutions of force-free magnetic fields, some symmetries or approximations are usually invoked. We consider magnetic fields lying on coordinate surfaces of an orthogonal curvilinear coordinate system. We conclude that only fields on parallel planes or spherical shells can be expressed in the form provided by Low in 1980s. These force-free fields are stable against small perturbations with rigid boundaries. Fields on cylindrical shells are also considered.     

Energy flow in Branchiura sowerbyi (Oligochaeta: tubificidae) in a shallow macrophyte-dominated lake, Biandantang Lake

The energy flow ofBranchiura sowerbyi was studied for the first time in China in a shallow macrophytic lake, Biandantang Lake, Hubei Province. The energy flow was calculated from the measurement of flesh production (12.5241kJ/m²a), egestion (517.7302kJ/m²a), metabolism (38.3273 kJ/m²a), and excretion (4.3798kJ/m²a). The net growth efficiency of the species is about 22.7%, which accords well with the generally reported value for oligochaetes. In addition, the relationship between starvation respiration (R, mgO₂/ind·d), wet weight (Ww, mg) and temperature (T, °C) were also measured, with the regression function beingR=0.008Ww^0.736 e^0.050T. Project supported by NSFC (30270278, 3960019), the foundation of the government of Hubei Province (No. 2000J109), and the foundation of Ecological Station, CAS in the Institute of Hydrobiology.     

ENERGY FLOW OF BELIAMYA AERUGINOSA IN A SHALLOW ALGAL LAKE, HOUHU LAKE （WUHAN, CHINA）

The energy budget ofBellamya earuginosa in a shallow algal lake, Houhu Lake (Wuhan, China) was investigated by the measurement of flesh production (32.8 kJ/(m²·a)), egestion (337.7 kJ/(m²·a)), metabolism (246.7 kJ/(m²·a)), and estimation of excretion (21.4kJ/(m²·a)). The net growth efficiency of the species is about 10.9%, which accords with the generally reported value for gastropods. In addition, the relationships between starvation respiration (R, mgO₂/(Ind·d)), body weight (Wd, mg in dry wt) and temperature (T, °C) were also determined. The regression equationR=0.044Wd ^0.537 e ^0.061T was obtained by the least square method, The measured SDA of the species is 26.51% of its gross metabolism. Project No. 3960019 and 39430101 supported by NSFC and also a granted for the East Lake Ecological Experimental Station, CAS, Wuhan.     

On the microwave millisecond spike emission and its associated phenomena during the impulsive phase of large solar flare

We propose a model of two acceleration regions, which can explain, on the basis of microwave maser caused by a “hollow-beam” distribution of electrons, the presence of millisecond spikes in the event of 1981 May 16 and their absence in the event of 1981 October 12, and the enhanced continuous emission in the latter. We have also uncovered relations among the features, e.g. the Type III_G, Type IV_DCIM and hard x-ray bursts, that accompany the microwave millisecond spikes during the impulsive phase of a large flare.     

CLIMATIC TREND INDICATED BY VARIATIONS OF GLACIERS AND LAKES IN THE TIANSHAN MOUNTAINS

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