Predictions of exceptionally strong ‘4430’ in the backscattered light from reflection nebulae

The strength of the 4430 interstellar spectrum feature in the backscattered light from certain reflection nebulae is shown to be a sensitive indicator of the feature's origin.Backscattering 4430 profiles have been computed for several, models of silicate, graphite, dirtyice-coated graphite, and silicon carbide grains with impurities. The effect on these profiles of both non-sphericity of the grains and finite optical thickness of the reflection nebula have been considered. For silicate grains, the 4430 central depth is predicted to be up to ten times its value in the corresponding extinction profile, whereas for graphite only a rather weak feature is expected. Some comments are made concerning the future comparison of observations with these theretical results.     

Soil feedback drives the mid-Holocene North African monsoon northward in fully coupled CCSM2 simulations with a dynamic vegetation model

We explore climate-vegetation interactions in mid-Holocene North Africa with a suite of community climate system model (CCSM2) simulations. The CCSM includes synchronously coupled atmosphere, ocean, sea ice, land, and vegetation models. The CCSMs present-day precipitation for North Africa compares well with simulations of other models and observations. Mid-Holocene data reveal a wetter and greener Sahara compared to the present. The CCSM exhibits a greater, closer to the expected, precipitation increase than other models, and in response, grasses advance from 18.75° to 22.5°N in much of North Africa. Precipitation is enhanced locally by the northward advance of grasses, but suppressed regionally mainly due to an insufficient albedo decrease with the expansion of vegetation. Prior studies have always lowered the surface albedo with the expansion of vegetation in North Africa. In the CCSMs mid-Holocene simulations, the albedo decreases more because wetter soils are simulated darker than drier soils than due to expanding vegetation. These results isolate albedo as the key ingredient in obtaining a positive precipitation-vegetation feedback in North Africa. Two additional simulations support this conclusion. In the first simulation, the deserts sandy soil textures are changed to loam to represent increased organic matter. Soil water retention and grass cover increase; albedo decreases somewhat. Precipitation responds with a small, yet widespread, increase. In the second simulation, a darker soil color is prescribed for this region. Now the monsoon advances north about 4°. These results illustrate a North African monsoon highly sensitive to changes in surface albedo and less sensitive to changes in evapotranspiration.     

Bioaccumulation of gold by sulfate-reducing bacteria cultured in the presence of gold(I)-thiosulfate complex

A sulfate-reducing bacterial (SRB) enrichment, from the Driefontein Consolidated Gold Mine, Witwatersrand Basin, Republic of South Africa, was able to destabilize gold(I)-thiosulfate complex and precipitate elemental gold. The precipitation of gold was observed in the presence of active (live) SRB due to the formation and release of hydrogen sulfide as an end-product of metabolism, and occurred by three possible mechanisms involving iron sulfide, localized reducing conditions, and metabolism. The presence of biogenic iron sulfide caused significant removal of gold from solutions by adsorption and reduction processes on the iron sulfide surfaces. The presence of gold nanoparticles within and immediately surrounding the bacterial cell envelope highlights the presence of localized reducing conditions produced by the bacterial electron transport chain via energy generating reactions within the cell. Specifically, the decrease in redox conditions caused by the release of hydrogen sulfide from the bacterial cells destabilized the solutions. The presence of gold as nanoparticles (<10 nm) inside a sub-population of SRB suggests that the reduction of gold was a part of metabolic process. In late stationary phase or death phase, gold nanoparticles that were initially precipitated inside the bacterial cells, were released from the cells and deposited in the bulk solution as addition of gold nanoparticles that already precipitated in the solution. Ultimately, the formation of micrometer-scale sub-octahedral and octahedral gold and spherical aggregates containing octahedral gold was observed.     

Dealing with drought: The challenge of using water system technologies to break dryland poverty traps

We explore strategies among farmers in semi-arid Tanzania to cope with drought, and investigate if access to a local supplemental irrigation system (the Ndiva system) can improve coping capacity. Results show high dependency on local ecosystem services when harvests fail, and indicate that farmers commonly exhaust asset holdings during droughts. Ndiva access did not have any direct effects on coping capacity, but seemed to have some indirect effects. Drawing on our findings we discuss the complexity of escaping persistent dryland poverty, and outline the circumstances under which small-scale water system technologies, such as Ndiva irrigation, may help.     

Diurnal thermal tides in a non-synchronized hot Jupiter

We perform a linear analysis to investigate the dynamical response of a non-synchronized hot Jupiter to stellar irradiation. In this work, we consider the diurnal Fourier harmonic of the stellar irradiation acting at the top of a radiative layer of a hot Jupiter with no clouds and winds. In the absence of the Coriolis force, the diurnal thermal forcing can excite internal waves propagating into the planet's interior when the thermal forcing period is longer than the sound crossing time of the planet's surface. When the Coriolis effect is taken into consideration, the latitude-dependent stellar heating can excite weak internal waves (g modes) and/or strong baroclinic Rossby waves (buoyant r modes) depending on the asynchrony of the planet. When the planet spins faster than its orbital motion (i.e. retrograde thermal forcing), these waves carry negative angular momentum and are damped by radiative loss as they propagate downwards from the upper layer of the radiative zone. As a result, angular momentum is transferred from the lower layer of the radiative zone to the upper layer and generates a vertical shear. We estimate the resulting internal torques for different rotation periods based on the parameters of HD 209458b.     

Arsenite sequestration at the surface of nano-Fe(OH)2, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefaciens

X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [Fe^II₄Fe^III₂(OH)₁₂CO₃: GR1(CO₃)], which completely converted into ferrous-carbonate hydroxide (Fe^II₂(OH)₂CO₃: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO₃) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO₃) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO₃) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)₂ phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)₂ nanoparticles as oligomers binding to the edges of Fe(OH)₆ octahedra at the edges of the octahedral layers of Fe(OH)₂. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.