Synthetic ANaB(Na x Li1 − x Mg1)CMg5Si8O22(OH)2 (with x = 0.6, 0.2 and 0) P21/m amphiboles at high pressure: a synchrotron infrared study

The high-pressure behavior of three synthetic amphiboles crystallized with space group P2₁/m at room conditions in the system Li₂O–Na₂O–MgO–SiO₂–H₂O has been studied by in situ synchrotron infrared absorption spectroscopy. The amphiboles have compositions ^ANa ^B(Na _x Li_1 − x Mg₁) ^CMg₅ Si₈ O₂₂(OH)₂ with x = 0.6, 0.2 and 0.0, respectively. The high-P experiments up to 32 GPa were carried out on the U2A beamline at Brookhaven National Laboratory (NY, USA) using a diamond anvil cell under non-hydrostatic or quasi-hydrostatic conditions. The two most intense absorption bands in the OH-stretching infrared spectra can be assigned to two non-equivalent O–H dipoles in the P2₁/m structure, bonded to the same local environment ^M1M3Mg₃–OH–^ANa, and pointing toward two differently kinked tetrahedral rings. In all samples these bands progressively merge to give a unique symmetrical absorption with increasing pressure, suggesting a change in symmetry from P2₁/m to C2/m. The pressure at which the transition occurs appears to be linearly correlated to the aggregate B-site dimension. The infrared spectra collected for amphibole ^B(Na_0.2Li_0.8Mg₁) in the frequency range 50 to 1,400 cm⁻¹ also show a series of changes with increasing pressure. The data reported here support the inference of Iezzi et al. (Am Miner 91:479–482, 2006a) regarding a new high-pressure amphibole polymorph.     

A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.     

On the use of infinite elements in the analysis of two-dimensional layered elastic systems via discretized integral equations

A boundary integral equation approach is presented for the two-dimensional plane strain analysis of horizontally layered elastic systems resting on a rough and rigid base. The validity of Somigliana identity for unbounded layers is discussed and an Infinite Boundary Element is proposed in order to take into account the lateral unboundedness of the physical problem in the discretized equations. This element is implemented in a computer code based on a successive stiffness solution procedure. A series of numerical tests concerning single- and multi-layered problems is illustrated, and the performance of the proposed solution method is compared with that of more traditional boundary element and finite element techniques.     

Young runoff fractions control streamwater age and solute concentration dynamics

We introduce a new representation of coupled solute and water age dynamics at the catchment scale, which shows how the contributions of young runoff waters can be directly referenced to observed water quality patterns. The methodology stems from recent trends in hydrologic transport that acknowledge the dynamic nature of streamflow age and explores the use of water age fractions as an alternative to the mean age. The approach uses a travel time‐based transport model to compute the fractions of streamflow that are younger than some thresholds (e.g., younger than a few weeks) and compares them to observed solute concentration patterns. The method is here validated with data from the Hubbard Brook Experimental Forest during spring 2008, where we show that the presence of water younger than roughly 2 weeks, tracked using a hydrologic transport model and deuterium measurements, mimics the variation in dissolved silicon concentrations. Our approach suggests that an age–discharge relationship can be coupled to classic concentration–discharge relationship, to identify the links between transport timescales and solute concentration. Our results highlight that the younger streamflow components can be crucial for determining water quality variations and for characterizing the dominant hydrologic transport dynamics.     

A parallel computing thin‐sheet inversion algorithm for airborne time‐domain data utilising a variable overburden

Accurate modelling of the conductivity structure of mineralisations can often be difficult. In order to remedy this, a parametric approach is often used. We have developed a parametric thin‐sheet code, with a variable overburden. The code is capable of performing inversions of time‐domain airborne electromagnetic data, and it has been tested successfully on both synthetic data and field data. The code implements an integral solution containing one or more conductive sheets, buried in a half‐space with a laterally varying conductive overburden. This implementation increases the area of applicability compared to, for example, codes operating in free space, but it comes with a significant increase in computational cost. To minimise the cost, the code is parallelised using OpenMP and heavily optimised, which means that inversions of field data can be performed in hours on multiprocessor desktop computers. The code models the full system transfer function of the electromagnetic system, including variable flight height. The code is demonstrated with a synthetic example imitating a mineralisation buried underneath a conductive meadow. As a field example, the Valen mineral deposit, which is a graphite mineral deposit located in a variable overburden, is successfully inverted. Our results match well with previous models of the deposit; however, our predicted sheet remains inconclusive. These examples collectively demonstrate the effectiveness of our thin‐sheet code.     

Chandra smells a RRAT

“Rotating RAdio Transients” (RRATs) are a newly discovered astronomical phenomenon, characterised by occasional brief radio bursts, with average intervals between bursts ranging from minutes to hours. The burst spacings allow identification of periodicities, which fall in the range 0.4 to 7 seconds. The RRATs thus seem to be rotating neutron stars, albeit with properties very different from the rest of the population. We here present the serendipitous detection with the Chandra X-ray Observatory of a bright point-like X-ray source coincident with one of the RRATs. We discuss the temporal and spectral properties of this X-ray emission, consider counterparts in other wavebands, and interpret these results in the context of possible explanations for the RRAT population. B.M.G. acknowledges the support of NASA through LTSA grant NAG5-13023 and of an Alfred P. Sloan Fellowship.     

Searching for inner-Earth objects: a possible ground-based approach

The likely existence of bodies orbiting the Sun with aphelia Q < 0.983 AU has been suggested by numerical simulations of the dynamical evolution of the near-Earth objects (NEOs) population. For obvious reasons, these hypothetical minor bodies are called inner-Earth objects (IEOs). While much progresses has been made in learning more about the Amor, Apollo, and Aten population from surveys optimized for their discovery, no large, systematic, and similar observation projects devoted to the search of IEOs have been started. For their own orbital nature, IEOs can be observed only at small solar elongations (<90°), corresponding to regions of the sky currently neglected by the modern, ongoing surveys. This paper discusses a possible ground-based approach to look for IEOs, providing some useful tricks and the results of simulated surveys devoted to their discovery. It will be shown that such a search promises interesting results, the setup of a dedicated project being highly recommended.     

Framing the use of geo-information in government: a tale of two perspectives

While commercial virtual globes (e.g. Google Earth) and global scientific cyber-infrastructures (e.g. Digital Earth) are revolutionizing the way we use and produce geo-information, we still lack a rich conceptual understanding of how genuine human actors use geo-information and associated technologies in real work settings. In this paper, we conceptualize the use of geo-information as encompassing people’s actual use practices, the values to which people aspire through geo-information use, and the rules that either legally prescribe or just encourage optimal use. Values, practices and rules can be illuminated from two perspectives (or lenses), the market and the polis, resulting in radically different insights on the use of geo-information as a social phenomenon. We argue that with a polis lens we stand a chance to explain how authentic human actors, groups and communities with different values, interests and motivations use geo-information, and how societal benefits materialize or not as a result. Seen from a polis lens, values are not easily measurable standards of goodness, dominant public management ideas can be the source of technical-organizational change in government while policies can be fruitfully examined as persuasive arguments to target audiences. With a polis lens, we are more likely to understand the emergence of new practices, value contests and global rules underpinning commercial virtual globes and scientific cyber-infrastructures.