Discussion of the Möller radiation chart

Summary M?ller's assumptions for the carbon dioxide-water vapor overlap region, which lead to the construction of his radiation chart, are reinvestigated in the light of modern theory. A new radiation chart, taking into account the carbon dioxide-water vapor overlap, is constructed using water vapor and carbon dioxide absorption data as furnished byM?ller andElsasser respectively. The results of the radiative fluxes computed from the new chart are compared with equivalent results using the original M?ller and the revised Elsasser radiation diagrams, as well as with measurements.

---

Zusammenfassung Die Berechtigung derM?llerschen Annahme zur getrennten Behandlung von Kohlens?ure- und Wasserdampfabsorption zwecks Konstruktion eines atmosph?rischen Strahlungsdiagrammes wird im Lichte der modernen Theorie diskutiert. Ein neues Strahlungspapier wird vorgelegt, das die gleichzeitige Anwesenheit von Kohlens?ure und Wasserdampf im gleichen Spektralbereich berücksichtigt. Dieses beruht auf Wasserdampf- und Kohlens?uredaten, die vonM?ller undElsasser vorgegeben wurden. Nach dem neuen Strahlungsdiagramm berechnete Werte werden mit Me?werten und theoretischen Werten verglichen, die mit dem ursprünglichen M?llerschen und mit dem verbesserten Elsasserschen Strahlungspapier ermittelt wurden.

---

Résumé Au vu des théories modernes, on discute l'hypothèse formulée parM?ller et sa justification, hypothèse selon laquelle il est nécessaire de traiter séparément l'absorption du dioxyde de carbone et celle de la vapeur d'eau lors de l'établissement d'un diagramme du rayonnement atmosphérique. On propose alors un nouvel abaque qui tient compte de la présence simultanée du dioxyde de carbone et de la vapeur d'eau dans la même région spectrale. Cet abaque s'appuie sur les valeurs données parM?ller et parElsasser, valeurs valables pour ces deux gaz. On compare le résultat de calculs effectués avec ce nouvel abaque à des mesures et à des valeurs théoriques ces dernières étant basées tant sur les travaux originaux deM?ller que sur l'abaque amélioré deElsasser.

---

---

With 4 Figures     

Identification of chlorite and chlorite-related minerals in sediments

A scheme is presented for the identification and classification of chlorite and related minerals in sediments which is mainly based on X-ray characteristics of the orginal sample and the sample heated at 350°C and treated with K⁺ and with glycerol. Examples are given. It is emphasized that additional data about clay mineral genesis, electron microscopy, infrared spectroscopy and chemical analyses are needed for the ordening of a certain mineral in the proposed scheme. Many names of minerals so far found to occur in the clay separate of sediments proved to be synonymous (52 of a total of 88) and thus should be abandoned. They only give confusion and needlessly increase the many difficulties which already exist in the identification, classification and quantitative determination of this complicated group of minerals of about 36 well defined specimens which may be found in sediments.     

The volcano-magnetic effect

Summary A geometrically simple volcano is considered, havig a spherical magma chamber of 2.5 km radius centred at 10 km depth. The Curie point isotherm is assumed to be a plane at 20 km depth, except for the spherical volume which is also non-magnetic. The stress pattern in the vicinity of the spherical chamber, due to regional stress of sufficient intensity to cause an eruptions, is used to calculate the change in magnetization which results from the piezomagnetic effect through the volume of solid rock. The consequent magnetic field anomaly at the surface is then obtaied by numerical integration of the dipole law of force over the stressed volume. For rocks of the type found on the volcanic island of St. Vincent (West Indies), this model gives a maximum local volcano-magnet c effect of about 7 gammas.     

An optimized method for automated analysis of algal pigments by HPLC

A recent development in algal pigment analysis by high-performance liquid chromatography (HPLC) is the application of automation. An optimization of a complete sampling and analysis protocol applied specifically in automation has not yet been performed. In this paper we show that automation can only be successful if the various methodological aspects of the sampling and analysis protocol are considered in coherence. We introduce an optimized protocol that involves freeze-drying of the sample, subsequent extraction in 90% acetone and the application of water-packing during analysis. The method was evaluated on both natural plankton populations and a broad spectrum of microalgal cultures: Thalassiosira weisflogii (Bacillariophyceae), Emiliania huxleyi (Prymnesiophyceae), Phaeocystis globosa and Phaeocystis antarctica (Prymnesiophyceae) and Pyramimonas sp. (Prasinophyceae). Whereas pigment extracts were unstable in methanol, with recorded chlorophyll a losses from 10% to 60% per day, pigment degradation rates in acetone were generally less than 1% over 18 h storage in the autosampler (4 °C). In addition, it was found that the extraction efficiency of acetone significantly increased upon freeze-drying prior to extraction. Increases as high as 50–60% were measured in P. antarctica. The application of water-packing of the sample during injection resulted in improved peak shape and peak separation, without diluting the pigment concentrations. Automation is especially beneficial for application in the field, when mixed algal assemblages and low biomass put a high demand on the sensitivity as well as reproducibility of the method.     

A new method for the generation of second-order random waves

In order to prevent the generation of spurious free sub- and superharmonics of random waves in a laboratory channel, the control signal for the wave board has to be derived according to a higher-order wave theory. An expression for this control signal has been derived with the perturbation method of multiple scales. It is much less complex and requires less computation time than the expressions obtained from the full second-order theory. The new method for second-order subharmonics was verified experimentally for waves with bichromatic and continuous first-order spectra. The data were analysed with the complex-harmonic principal-component analysis to reduce the influence of noise.     

Measurement of the redox speciation of iron in seawater by catalytic cathodic stripping voltammetry

Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (Fe_R) in the absence and presence of 2 μM Dp, Fe_R being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H₂O₂ and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for Fe_R. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for Fe_R, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of Fe_R ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column.     

Risk of dike failure due to flow slides

Flow slides may affect the stability of dikes. A flow slide is an instability of a submerged slope caused by liquefaction of loose, (medium) fine sand. Whether a flow slide will occur depends on the properties of the sand, which are a function of its density, and the geometry of the slope, as determined by wave and current induced scour and sedimentation. The influence of sand properties and the geometry parameters on the risk of flow slides are discussed. The application of a flow slide prediction method to an example and a risk analysis is briefly discussed.     

Transient biouptake flux and accumulation by microorganisms: The case of two types of sites with Langmuir adsorption

The uptake of a chemical species by an aquatic microorganism is modelled considering two kinds of sites where Langmuirian adsorption is followed by first order internalisation kinetics. Simpler models, such as only one internalisation route (while most of the adsorption takes place on non-internalising sites) or a linear isotherm for adsorption on one or both sites, become limiting cases of this double-Langmuirian model. The model considers the sites located on the spherical (or semi-spherical) surface of the organism, and takes diffusion from the medium into explicit account. The numerical solution for the internalisation flux shows a maximum. We provide an estimate for the time needed to reach a certain proximity to steady state. The transient solution confirms that the analytical expressions for the steady-state flux are usually valid and that the accumulated amounts reflect the impact of the short-time uptake. The Instantaneous Steady-State Approximation (ISSA), where an intercept of the linear regression of accumulated amount as a function of time is interpreted as an adsorbed amount, can be critically assessed with the transient numerical code for two cases: (i) when the total burden of metal on the cell is the input data and (ii) when an extraction procedure provides further information on the adsorbed and internalised amount.