全文获取类型
收费全文 | 170篇 |
免费 | 8篇 |
国内免费 | 4篇 |
专业分类
测绘学 | 2篇 |
大气科学 | 9篇 |
地球物理 | 54篇 |
地质学 | 58篇 |
海洋学 | 14篇 |
天文学 | 40篇 |
自然地理 | 5篇 |
出版年
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 4篇 |
2018年 | 3篇 |
2017年 | 6篇 |
2016年 | 4篇 |
2015年 | 3篇 |
2014年 | 7篇 |
2013年 | 14篇 |
2012年 | 11篇 |
2011年 | 17篇 |
2010年 | 13篇 |
2009年 | 13篇 |
2008年 | 9篇 |
2007年 | 9篇 |
2006年 | 8篇 |
2005年 | 8篇 |
2004年 | 4篇 |
2003年 | 4篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有182条查询结果,搜索用时 225 毫秒
61.
Anja Bretzler Lucien Stolze Julien Nikiema Franck Lalanne Elaheh Ghadiri Matthias S.Brennwald Massimo Rolle Mario Schirmer 《地学前缘(英文版)》2019,10(5):1685-1699
The semi-arid Sahel regions of West Africa rely heavily on groundwater from shallow to moderately deep(100 m b.g.l.)crystalline bedrock aquifers for drinking water production.Groundwater quality may be affected by high geogenic arsenic(As)concentrations(10μg/L)stemming from the oxidation of sulphide minerals(pyrite,arsenopyrite)in mineralised zones.These aquifers are still little investigated,especially concerning groundwater residence times and the influence of the annual monsoon season on groundwater chemistry.To gain insights on the temporal aspects of As contamination,we have used isotope tracers(noble gases,~3H,stable water isotopes(~2 H,~(18)O))and performed hydrochemical analyses on groundwater abstracted from tube wells and dug wells in a small study area in southwestern Burkina Faso.Results revealed a great variability in groundwater properties(e.g.redox conditions,As concentrations,water level,residence time)over spatial scales of only a few hundred metres,characteristic of the highly heterogeneous fractured underground.Elevated As levels are found in oxic groundwater of circum-neutral pH and show little relation with any of the measured parameters.Arsenic concentrations are relatively stable over the course of the year,with little effect seen by the monsoon.Groundwater residence time does not seem to have an influence on As concentrations,as elevated As can be found both in groundwater with short(50 a)and long(10~3 a)residence times as indicated by ~3He/~4He ratios spanning three orders of magnitude.These results support the hypothesis that the proximity to mineralised zones is the most crucial factor controlling As concentrations in the observed redox/pH conditions.The existence of very old water portions with residence times10~3 years already at depths of50 m b.g.l.is a new finding for the shallow fractured bedrock aquifers of Burkina Faso,suggesting that overexploitation of these relatively low-yielding aquifers may be an issue in the future. 相似文献
62.
Site U1446 (19°50’N, 85°44’E, at water depth 1 430 m) was drilled during Expedition 353 (Indian monsoon rainfall) of the International Ocean Discovery Program (IODP). It is located in the Mahanadi offshore basin, on the northern Bay of Bengal. Sedimentation rates and contents of biocarbonates are high at this relatively shallow site. Using a micropaleontological approach, we examined planktonic and benthic foraminifera in the upper around 40 m of this site, spanning the last around 190 ka. A striking feature of the foraminiferal record is the occurrence of strong but varying dissolution although the site is located well above the modern lysocline. Such strong dissolution has never been reported in this area. We estimated the flux of foraminifera and quantified the ratio of benthic foraminifera over total foraminifera (benthic/total foraminifera) along with the foraminifer fragmentation index in order to characterize past changes in this above-lysocline dissolution. This study reveals a clear glacial-interglacial contrast, with a stronger dissolution during marine isotope stages (MISs) 1 and 5 than during MISs 2–4 and 6. Such a difference in preservation is likely to have a strong impact on geochemical proxies measured on foraminifera. Our new observations call for an in-depth study of the causes of such above-lysocline dissolution in the region, and an evaluation of its impact on the foraminifera-based proxies used for paleoenvironmental reconstruction. 相似文献
63.
Marc Blanchard Franck Poitrasson Michele Lazzeri Etienne Balan 《Geochimica et cosmochimica acta》2009,73(21):6565-776
In addition to equilibrium isotopic fractionation factors experimentally derived, theoretical predictions are needed for interpreting isotopic compositions measured on natural samples because they allow exploring more easily a broader range of temperature and composition. For iron isotopes, only aqueous species were studied by first-principles methods and the combination of these data with those obtained by different methods for minerals leads to discrepancies between theoretical and experimental isotopic fractionation factors. In this paper, equilibrium iron isotope fractionation factors for the common minerals pyrite, hematite, and siderite were determined as a function of temperature, using first-principles methods based on the density functional theory (DFT). In these minerals belonging to the sulfide, oxide and carbonate class, iron is present under two different oxidation states and is involved in contrasted types of interatomic bonds. Equilibrium fractionation factors calculated between hematite and siderite compare well with the one estimated from experimental data (ln α57Fe/54Fe = 4.59 ± 0.30‰ and 5.46 ± 0.63‰ at 20 °C for theoretical and experimental data, respectively) while those for Fe(III)aq-hematite and Fe(II)aq-siderite are significantly higher that experimental values. This suggests that the absolute values of the reduced partition functions (β-factors) of aqueous species are not accurate enough to be combined with those calculated for minerals. When compared to previous predictions derived from Mössbauer or INRXS data [Polyakov V. B., Clayton R. N., Horita J. and Mineev S. D. (2007) Equilibrium iron isotope fractionation factors of minerals: reevaluation from the data of nuclear inelastic resonant X-ray scattering and Mössbauer spectroscopy. Geochim. Cosmochim. Acta71, 3833-3846], our iron β-factors are in good agreement for siderite and hematite while a discrepancy is observed for pyrite. However, the detailed investigation of the structural, electronic and vibrational properties of pyrite as well as the study of sulfur isotope fractionation between pyrite and two other sulfides (sphalerite and galena) indicate that DFT-derived β-factors of pyrite are as accurate as for hematite and siderite. We thus suggest that experimental vibrational density of states of pyrite should be re-examined. 相似文献
64.
Marie-Françoise André Bruno Phalip Olivier Voldoire Franck Vautier Yves Géraud Mhammed Benbakkar Christophe Constantin Fabienne Huber Gilles Morvan 《Environmental Earth Sciences》2011,63(7-8):1723-1739
This article is based on field investigations carried out at Ta Keo and Banteay Srei temples (Angkor, Cambodia), which have similar environmental histories and display the same recurrent decorative pattern (lotus petal) in three different sandstone lithotypes. Based on two original scales of mechanical and chemical weathering, the degree of deterioration of c.2000 sandstone petals was visually assessed, resulting in the proposal of a durability scale. An explanatory scheme was provided, based on laboratory analyses of stone materials (ICP-AES, XRD, SEM-EDS, polarizing microscopy and mercury injection). The key drivers of sandstone durability are both mineralogical and petrophysical. The remarkable preservation of the pink sandstone is due to the quartzose nature of its clasts, the non-swelling clay content of its abundant matrix (kaolinite) and its porosity structure (large connected pores and probable non-connected porosity). The overall good preservation of the green sandstone is due to its extremely low porosity and specific surface area, associated with its strong cementation. The severe deterioration of the grey sandstone is due to its laminated structure (oriented biotites), the susceptibility to hygric swelling and solution of its binding agents (chlorite/smectite and calcite) and its porosity structure, which evolves during a two-stage weathering sequence. The first stage is characterized by a bimodal porosity due to the partial clogging of macropores by swelling clays, and the second stage by a substantial increase in porosity and the penetration of salts (barite and anhydrite). Conversely, oxidation phenomena associated with weathering can lead to a drastic reduction of porosity. 相似文献
65.
Morphological controls on the dynamics of carbonate landscapes under a mediterranean climate 下载免费PDF全文
Franck Thomas Vincent Godard Olivier Bellier Esmaeil Shabanian Vincent Ollivier Lucilla Benedetti Magali Rizza Nicolas Espurt Valéry Guillou Fabrice Hollender Stéphane Molliex ASTER Team 《地学学报》2017,29(3):173-182
The influence of the morphological setting on the denudation of carbonate landscapes and the respective contributions of mechanical and chemical weathering processes are still debated. We have addressed these questions by measuring 36Cl concentrations in 40 samples from the Luberon mountain, SE France, to constrain the denudation of various landscape elements. We observe a clear contrast between the local denudation rates from the flat summit surface, clustered around 30 mm/ka, and the basin‐average denudation rates across the flanks, ranging from 100 to 200 mm/ka. This difference highlights the transient evolution of the range, whose topography is still adjusting to previous uplift events. Such a pattern also suggests that carbonate dissolution is not the only driver of denudation in this setting, which appears to be significantly controlled by slope‐dependent processes. 相似文献
66.
This paper is the continuation of an earlier one on planetary evolution of Earth and Mars (Franck and Orgzall, 1987). Here models for the history of the Martian magnetic field are presented. It is concluded, that Mars once had a substantial magnetic field that was switched off approximately 1 billion years ago on the one hand due to missing gravitational energy supply— the core reached its eutectic composition earlier— and on the other hand due to dynamic inhibitions. 相似文献
67.
Conventional evolutionary models for Mars adopt a dry mantle solidus. Taking into account the condensation conditions in the preplanetary nebula in the accretion zone of Mars, it can be concluded that large amounts of water or hydrated silicates have condensed in those regions. Therefore, water influences significantly the melting behaviour and the viscosity of the silicatic material. A model for the calculation of the thermal history of a planet is constructed. On this basis, and use of water — saturated solidus — it is possible to derive that the core is not liquid, as given in models employing a dry mantle solidus, but solid to a large extent, which prevents the operation of a large-scale dynamo and explains in that way the lack of a magnetic field. With these assumptions one can construct a possible evolutionary scheme that covers early crust differentiation, a hot thermal past and the missing magnetic field at present. 相似文献
68.
Franck Poitrasson Eric Oelkers Jean-Marc Montel 《Geochimica et cosmochimica acta》2004,68(10):2207-2221
The solubility of synthetic NdPO4 monazite end-member has been determined experimentally from 21 to 300°C in aqueous solutions at pH = 2, and at 21°C and pH = 2 for GdPO4. Measurements were performed in batch reactors, with regular solution sampling for pH measurement, rare earths and phosphorous analysis by inductively coupled plasma mass spectrometry (ICP-MS) coupled with a desolvation system. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were employed to check that no reprecipitation of secondary phases occurred and that the mineral surfaces remained those of a monazite. Coupled with speciation calculations, measured solution compositions permitted the determination of NdPO4 and GdPO4 solubility products which are in general agreement with previous experimental determination on rhabdophane at 25°C, but showing that monazite is more than two orders of magnitude less soluble than inferred on the basis of previous thermodynamic estimates. The temperature evolution from 21 to 300°C of the equilibrium constant (K) of the NdPO4 monazite end-member dissolution reaction given by:
69.
A vertically resolved ecosystem model is developed to simulate the dynamics of the pelagic food web in St Helena Bay during a representative period of relaxation after an upwelling event. The proposed model aims at coupling three biogeochemical cycles (carbon, nitrogen and silicon), using several recently developed concepts of the stoichiometric approach. A consequence of this approach is that important qualitative aspects are introduced, such as indicators of phytoplankton physiological state or variable food C:N ratios. For instance, the sedimentation and exudation rates for phytoplankton vary according to physiological state. An attempt is made to parameterize and simulate the diel cycles for vertical migration and feeding rhythms of large zooplankton, two important mesoscale processes that are thought to influence the overall dynamics of the huge phytoplankton blooms in the region.Observations of the Anchor Station Experiment 1987 (ASE’87) are used to assess the quality of the model. There is overall agreement between observations and the corresponding simulated results. The timing, the magnitude, and the vertical structure of the phytoplankton bloom are well reproduced. The balances for carbon and nitrogen flows and stocks compare well to the numerous estimates found from the literature for the southern Benguela region.On the basis of the model results, the origin of the new nutrients, the fate of the carbon fixed by phytoplankton, and the importance of the microheterotrophic pathways are discussed. It is concluded that sediments of the St Helena Bay and surrounding areas may play a crucial role in increasing the level of phytoplankton production. The results also suggest that exudation is the main process by which the carbon fixed by phytoplankton would have been lost, and that microheterotrophic pathways would have been intense during the experiment. 相似文献
70.
Wen Chen Christian La Borderie Olivier Maurel Gilles Pijaudier‐Cabot Franck Rey‐Bethbeder 《国际地质力学数值与分析法杂志》2014,38(5):457-474
The results reported in this paper deal with the simulation of damage in cohesive geomaterials such as rocks or concrete subjected to dynamic loads. The practical objective is to stimulate the production of tight gas reservoirs with a technique that is an alternative to hydraulic fracturing. The principle is that when subjected to dynamic loads, cohesive materials such as concrete, rocks or ceramics exhibit distributed micro‐cracking as opposed to localised cracking observed under static loads. Hence, a low permeability rock containing gas trapped into occluded pores can be fragmented with the help of dynamic loads, and gas can be extracted in a much more efficient way compared with hydraulic fracturing, where only large macro cracks are formed with very few connections between occluded pores. At the stage of laboratory development of this technique, compressive underwater shock waves have been used to increase the intrinsic permeability of concrete specimens. In a previous study, pressure waves generated by pulsed arc electrohydraulic discharges in water were used in order to induce micro‐cracking and an increase of average permeability of concrete hollow cylinders subjected to confinement stresses (equivalent to geostatic stresses). We discuss here a 3‐D anisotropic constitutive model aimed at describing the dynamic response of these specimens. It is based on rate‐dependent continuum damage constitutive relations. Crack closure effects and damage‐induced anisotropy are included in the model. The directional growth of damage is related to the directional growth of material intrinsic permeability. Numerical simulations of damage induced by shock waves show good agreement with the experiments for various confinement levels of the specimens. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献