Evaluation of redox-sensitive metals in marine surface sediments influenced by the oxygen minimum zone of the Humboldt Current System,Northern Chile

Upwelling coastal systems can be used to understand how dissolved oxygen and biological productivity control the accumulation of redox-sensitive metals in marine sediments. The aluminium (Al), cadmium (Cd), iron (Fe), nickel (Ni), molybdenum (Mo), vanadium (V), total organic carbon (TOC), total nitrogen (TN) and total sulfur (TS) contents in surficial sediment collected from different water depths (30, 70, and 120?m) in three northern Chilean bays influenced by coastal upwelling and oxygen minimum zones (OMZs) were measured. Principal component analysis (PCA), cluster analysis, and Spearman?s rank correlation were used to identify the mechanisms responsible for the redox-sensitive metal accumulation. The content of redox-sensitive metals and organic components in sediment increased with increasing water column depth, whereas lithogenic metals decreased. In the Mejillones del Sur and Caldera bays, the enrichment factors of the redox-sensitive metals showed enrichment for all metals with depth. The Cd and V enrichments are mainly the product of biogenic flow to the seabed, and the Mo and Ni enrichments are due to preservation under low subsurface oxygen conditions. Sulfate reduction is not an important mechanism in the accumulation of redox-sensitive metals in the sediment of the three bays. The PCA showed that the behaviors of the redox-sensitive metals and organic components reflect differences in the effects of the OMZ in sediment along the coast of northern Chile, with a more intense OMZ in Mejillones del Sur bay and weaker OMZs in Caldera and Inglesa bays. However, the high degree of enrichment in redox-sensitive metals in Caldera Bay can be attributed to the intense activity of the mining industry near the bay, a situation that produces geochemical behavior similar to that observed in Mejillones del Sur Bay.     

Inferring sediment transfers and functional connectivity of rivers from repeat topographic surveys

High-resolution topographic models have revolutionized monitoring of river changes by comparing sequential river topographic surveys (i.e. change detection). Nevertheless, much more may be obtained from this innovative quantification of changes. In this paper, we enhance the interpretation of geomorphic processes by presenting a new method for understanding of sources and sinks of sediment, river sediment transfers and functional sediment connectivity. Repeat digital elevation models (DEMs) obtained by photogrammetry were used to quantify topographic change after two floods by creating a DEM of difference (DoD) of a 6.5 km-long reach of Rambla de la Viuda stream, an ephemeral gravel-bed river in eastern Spain. The proposed method involved dividing the channel into 10 m-long longitudinal strips that were used to systematically draw boundaries between the erosional and depositional areas of the DoD. The analysis objectively: (i) drew a series of erosional and depositional segments, from 120 to 1360 m in length; (ii) estimated ranges of source-to-storage sediment transport distances, 320–670 m in the upstream and middle reaches and up to 2030 m in the lower reach; and (iii) obtained values of functional connectivity (i.e. the ratio between the sediment exported (erosion) and retained (deposition), ranging from 10³ to 10⁻³). The variability in these three parameters along the river was found to be related to the level of channel disturbance by in-stream mining during the 1990s and 2000s. Additionally, this method indicates that the main process responsible for self-adjustment of the present morphosedimentary conditions is intra-reach erosion of banks and channel beds. Thus, this study proposes a new methodology to characterize morphological change, sediment transfer and connectivity that may serve as environmental indicators of the hydromorphological integrity of rivers with potential application to the European Water Framework Directive. © 2019 John Wiley & Sons, Ltd.     

Site effects in 3D basins using 1D and 2D models: an evaluation of the differences based on simulations of the seismic response of Euroseistest

Site effects are one of the most predictable factors of destructive earthquake ground motion but results depend on the type of model chosen. We compare simulations of ground motion for a 3D model of the Mygdonian basin in northern Greece (Euroseistest) using different approximation for this basin. Site effects predicted using simple 1D models at many points inside the basin are compared to site effects predicted using four different 2D cross sections across the basin and with results for a full 3D simulation. Surface topography was neglected but anelastic attenuation was included in the simulations. We show that lateral heterogeneity may increase ground motion amplification by 100 %. Larger amplification is distributed in a wide frequency range, and amplification may occur at frequencies different from the expected resonant frequencies for the soil column. In contrast, on a different cross section, smaller conversion of incident energy into surface waves and larger dispersion leads to similar amplitudes of ground motion for 2D and 1D models. In general, results from 2D simulations are similar to those from a complete 3D model. 2D models may overestimate local surface wave amplitudes, especially when the boundaries of the basin are oblique to the selected cross section. However, the differences between 2D and 3D site effects are small, especially in regard of the difficulties and uncertainties associated to building a reliable 3D model for a large basin.     

Short‐term dynamics in fish assemblage structure on a sheltered sandy beach in Guanabara Bay,Southeastern Brazil

Short‐term dynamics in juvenile fish assemblage structure were studied to test whether the most abundant species show temporal segregation, in order to assess whether selected environmental variables could predict species groupings, and to examine the stability of sunset–day–sunrise–night differences. Samplings were collected at 3‐h intervals over 48 h on a seasonal basis between spring 2005 and winter 2006. Fish species richness and abundance were higher in spring, and the lowest values occurred in winter. Harengula clupeola occurred mainly in spring, whereas Atherinella brasiliensis peaked in summer and autumn. On the other hand, Trachinotus carolinus, Umbrina coroides and Mugil liza were abundant in winter. Although temperature, salinity and dissolved oxygen were not found to have a strong effect on the abundance patterns of most species, they did appear to have a significant influence on assemblage groupings, according to canonical correspondence analysis and Spearman rank correlation. There is no consistency of diel usage patterns by a given species across seasons. The relative abundance differed between the time of day, which differed among the seasons; this further complicates an understanding of the dynamics of an assemblage. Studies of diel changes that pooled the sampling period as day or night can miss important changes that occur in a short time scale, such as a 3‐h period.