Removal of arsenic and iron from mine-tailing leachate using chitosan hydrogels synthesized by gamma radiation

Mine residue and leachate were sampled from an acid mine drainage site near Arroyo San Pedro, which is one of the oldest abandoned mine districts in San Luis Potosi, Mexico, and characterized by X-ray diffraction and inductively coupled plasma-optical emission spectroscopy, confirming the presence of Fe, As, and SO₄ ^2?. To address this problem, chitosan network (net-CS) and chitosan network-N-vinylcaprolactam/N–N-dimethylacrylamide (net-CS)-g-NVCL/DMAAm hydrogels were synthesized and used as adsorbents of the different ions present in the aforementioned leachate by batch equilibrium procedure. Kinetics, isotherms, and ions dissolved in leachate were evaluated. The gels showed the highest adsorption capacity for As and Fe ions. The adsorption capacity of the net-CS hydrogels for As (V) and Fe(III) was 0.786 and 76.85 mg/g, respectively, attained after 50 h. The surface of the hydrogels was investigated by scanning electron microscopy and Fourier transform infrared spectroscopy, before and after the adsorption process, where the presence of a bond between the hydrogels and heavy metals ions, which is commonly observed in organic groups, was observed. In addition, Freundlich and Langmuir adsorption isotherms constants were determined for the As and Fe ions, and it was found that the Freundlich isotherm, with a first-order pseudo model, better fitted the adsorption process, indicating heterogeneous sorption, and the retention process occurred by chemisorption. The results from the Geochemist´s Workbench (GWB) software program revealed that arsenates, such as H₃AsO₄, H₂AsO₄ ^?, as well as Fe⁺⁺, FeSO₄(aq) and FeOH⁺ were the common aqueous species found in the leachate at pH = 2.9.     

Characterization and low-cost treatment of an industrial arid soil polluted with lead sulfide in northern Chile

Lead (Pb) dust exposure can have detrimental environmental and human health effects. Improperly enclosed stockpiles of Pb concentrates can cause dust emissions, subsequent pollution of the soil and environmental risk. The aim of this work was to study Pb form, distribution and immobilization (by using eggshell and seashell) in an industrial arid soil near a storage area of Pb mineral concentrates in northern Chile. High amounts of sulfur (S; 9900 mg kg^?1) and Pb (6530 mg kg^?1) were found in the polluted soil. The energy-dispersive X-ray spectroscopy analysis revealed a lead sulfide (PbS: galena). Metallic Pb particles, which were between 41 and 46 µm, were identified in the soil. After eggshell and seashell (20%) were applied, the soil pH increased from 6.0 to 7.84 and 8.07, respectively. In the studied soil, the leaching test showed a 59 mg L^?1 average Pb extractable concentration. After 240 days, extractable Pb by toxicity characteristics leaching procedure decreased to 4.79 mg L^?1 (93.3%) with the application of seashell at 20% compared with a decrease of 33.33 mg L^?1 (53.6%) using eggshell. Pb in the polluted soil was mainly found in the exchangeable fraction (66%), followed by the reducible (24%), residual (7%) and oxidizable (6%) fractions. According to the risk assessment code, the contaminated soil before treatment was classified as very high risk. Adding eggshell (20%) and seashell (20%) decreased the exchangeable fractions to 39 and 35%, respectively. Applying these liming materials achieved Pb immobilization in the soil, but the soil remained in the high environmental risk category. We conclude that the application of seashell waste, resulting from high aquaculture activity, opens an interesting window to the treatment of contaminated arid soils.     

Distribution and characterization of Chilean populations of the brine shrimp Artemia (Crustacea, Branchiopoda, Anostraca)

Hypersaline habitats in Chile, from marine solar salt pans to saline lagoons and pools in Andean salars, were prospected in search of Artemia populations. These saline ecosystems were characterized through physico-chemical parameters and ionic composition of their brines. Biometrics of cysts and nauplii, as well as morphometrics by using multivariate discriminant analysis for adult specimens evidenced that the Chilean populations of brine shrimp belong to A. franciscana. Cross-breeding results supported the former hypothesis of conspecific Chilean populations, and their differences with A. persimilis, also endemic to the New World, but restricted to Argentinean sites.     

Two new conceptual models for the formation and degradation of baymouth spits by longshore drift and fluvial discharge (Iguape,SE Brazil)

This study describes the formation of two successive baymouth spits systems on the south‐eastern Brazilian coast and the degradation of the first system. The study area includes the Jureia Beach spit, the deflected Ribeira de Iguape River mouth, the central Iguape sandy headland, the Icapara Inlet of the Mar Pequeno Lagoon and the northern end of the Comprida Island barrier spit. The wave and river flow patterns were combined with the coastline evolution and the alongshore migration rates deduced from satellite images. Initially, both spits showed convergent alongshore migration rates equal to or less than 83 m/yr. However, the extreme river flow due to high rainfall during a very strong El Niño event in 1983 eroded the inland side of the Jureia Beach spit, which finally retreated due to wave erosion. In 1989, a sand bank emerged in the river mouth, which attached to the central headland forming a recurved northeastward spit. In 1994, the high fluvial discharge associated with another very strong El Niño event caused the landward migration of the new spit and emersion of a second sand bank. This second sand bank merged with the Jureia Beach spit in 1997 at an alongshore migration rate of 1795.6 m/yr. Wave erosion of the central headland continued and the attached spit disappeared in 2000. In 2009, the headland erosion merged the river mouth and the Icapara Inlet, which resulted in flanking baymouth spits in a configuration that remains today. Therefore, two models for the formation of baymouth spits have been documented for wave‐dominated microtidal coasts in humid tropical regions with intense fluvial discharge. The convergent longshore migration of the spits is controlled by both the bidirectional longshore drift and the fluvial discharge, the latter eroding the fronting spit, supplying sediments and acting as a hydraulic blockage for longshore drift. Copyright © 2017 John Wiley & Sons, Ltd.     

Angola seismicity

This work describes the development of the Angolan earthquake catalog and seismicity distribution in the Southwestern African Plate, in Angola. This region is one of the least seismically active, even for stable continental regions (SCRs) in the world. The maximum known earthquake had a magnitude of 6.0 M_s, while events with magnitudes of 4.5 have return period of about 10 years. Events with magnitude 5 and above occur with return period of about 20 years. Five seismic zones can be confirmed in Angola, within and along craton edges and in the sedimentary basins including offshore. Overall, the exposed cratonic regions tend to have more earthquakes compared to other regions such as sedimentary basins. Earthquakes tend to occur in Archaic rocks, especially inside preexisting weakness zones and in tectonic-magmatic reactivation zones of Mesozoic and Meso-Cenozoic, associated with the installation of a wide variety of intrusive rocks, strongly marked by intense tectonism. This fact can be explained by the models of preexisting weakness zones and stress concentration near intersecting structures. The Angolan passive margin is also a new region where seismic activity occurs. Although clear differences are found between different areas along the passive margin, in the middle near Porto Amboim city, seismic activity is more frequent compared with northwestern and southwestern regions.     

Non-stationary future return levels for extreme rainfall over Extremadura (southwestern Iberian Peninsula)

Based on a previous study for temperature, a new method for the calculation of non-stationary return levels for extreme rainfall is described and applied to Extremadura, a region of southwestern Spain, using the peaks-over-threshold approach. Both all-days and rainy-days-only datasets were considered and the 20-year return levels expected in 2020 were estimated taking different trends into account: first, for all days, considering a time-dependent threshold and the trend in the scale parameter of the generalized Pareto distribution; and second, for rainy days only, considering how the mean, variance, and number of rainy days evolve. Generally, the changes in mean, variance and number of rainy days can explain the observed trends in extremes, and their extrapolation gives more robust estimations. The results point to a decrease of future return levels in 2020 for spring and winter, but an increase for autumn.     

Evaluation of redox-sensitive metals in marine surface sediments influenced by the oxygen minimum zone of the Humboldt Current System,Northern Chile

Upwelling coastal systems can be used to understand how dissolved oxygen and biological productivity control the accumulation of redox-sensitive metals in marine sediments. The aluminium (Al), cadmium (Cd), iron (Fe), nickel (Ni), molybdenum (Mo), vanadium (V), total organic carbon (TOC), total nitrogen (TN) and total sulfur (TS) contents in surficial sediment collected from different water depths (30, 70, and 120?m) in three northern Chilean bays influenced by coastal upwelling and oxygen minimum zones (OMZs) were measured. Principal component analysis (PCA), cluster analysis, and Spearman?s rank correlation were used to identify the mechanisms responsible for the redox-sensitive metal accumulation. The content of redox-sensitive metals and organic components in sediment increased with increasing water column depth, whereas lithogenic metals decreased. In the Mejillones del Sur and Caldera bays, the enrichment factors of the redox-sensitive metals showed enrichment for all metals with depth. The Cd and V enrichments are mainly the product of biogenic flow to the seabed, and the Mo and Ni enrichments are due to preservation under low subsurface oxygen conditions. Sulfate reduction is not an important mechanism in the accumulation of redox-sensitive metals in the sediment of the three bays. The PCA showed that the behaviors of the redox-sensitive metals and organic components reflect differences in the effects of the OMZ in sediment along the coast of northern Chile, with a more intense OMZ in Mejillones del Sur bay and weaker OMZs in Caldera and Inglesa bays. However, the high degree of enrichment in redox-sensitive metals in Caldera Bay can be attributed to the intense activity of the mining industry near the bay, a situation that produces geochemical behavior similar to that observed in Mejillones del Sur Bay.     

Inferring sediment transfers and functional connectivity of rivers from repeat topographic surveys

High-resolution topographic models have revolutionized monitoring of river changes by comparing sequential river topographic surveys (i.e. change detection). Nevertheless, much more may be obtained from this innovative quantification of changes. In this paper, we enhance the interpretation of geomorphic processes by presenting a new method for understanding of sources and sinks of sediment, river sediment transfers and functional sediment connectivity. Repeat digital elevation models (DEMs) obtained by photogrammetry were used to quantify topographic change after two floods by creating a DEM of difference (DoD) of a 6.5 km-long reach of Rambla de la Viuda stream, an ephemeral gravel-bed river in eastern Spain. The proposed method involved dividing the channel into 10 m-long longitudinal strips that were used to systematically draw boundaries between the erosional and depositional areas of the DoD. The analysis objectively: (i) drew a series of erosional and depositional segments, from 120 to 1360 m in length; (ii) estimated ranges of source-to-storage sediment transport distances, 320–670 m in the upstream and middle reaches and up to 2030 m in the lower reach; and (iii) obtained values of functional connectivity (i.e. the ratio between the sediment exported (erosion) and retained (deposition), ranging from 10³ to 10⁻³). The variability in these three parameters along the river was found to be related to the level of channel disturbance by in-stream mining during the 1990s and 2000s. Additionally, this method indicates that the main process responsible for self-adjustment of the present morphosedimentary conditions is intra-reach erosion of banks and channel beds. Thus, this study proposes a new methodology to characterize morphological change, sediment transfer and connectivity that may serve as environmental indicators of the hydromorphological integrity of rivers with potential application to the European Water Framework Directive. © 2019 John Wiley & Sons, Ltd.