From outwash to coastal systems in the Portneuf–Forestville deltaic complex (Québec North Shore): Anatomy of a forced regressive deglacial sequence

Deglacial sequences typically include backstepping grounding zone wedges and prevailing glaciomarine depositional facies. However, in coastal domains, deglacial sequences are dominated by depositional systems ranging from turbiditic to fluvial facies. Such deglacial sequences are strongly impacted by glacio‐isostatic rebound, the rate and amplitude of which commonly outpaces those of post‐glacial eustatic sea‐level rise. This results in a sustained relative sea‐level fall covering the entire depositional time interval. This paper examines a Late Quaternary, forced regressive, deglacial sequence located on the North Shore of the St. Lawrence Estuary (Portneuf Peninsula, Québec, Canada) and aims to decipher the main controls that governed its stratigraphic architecture. The forced regressive deglacial sequence forms a thick (>100 m) and extensive (>100 km²) multiphased deltaic complex emplaced after the retreat of the Laurentide Ice Sheet margin from the study area ca 12 500 years ago. The sedimentary succession is composed of ice‐contact, glaciomarine, turbiditic, deltaic, fluvial and coastal depositional units. A four‐stage development is recognized: (i) an early ice‐contact stage (esker, glaciomarine mud and outwash fan); (ii) an in‐valley progradational stage (fjord head or moraine‐dammed lacustrine deltas) fed by glacigenics; (iii) an open‐coast deltaic progradation, when proglacial depositional systems expanded beyond the valley outlets and merged together; and (iv) a final stage of river entrenchment and shallow marine reworking that affected the previously emplaced deltaic complex. Most of the sedimentary volume (10 to 15 km³) was emplaced during the three‐first stages over a ca 2 kyr interval. In spite of sustained high rates of relative sea‐level fall (50 to 30 mm·year^?1), delta plain accretion occurred up to the end of the proglacial open‐coast progradational stage. River entrenchment only occurred later, after a significant decrease in the relative sea‐level fall rates (<30 mm·year^?1), and was concurrent with the formation and preservation of extensive coastal deposits (raised beaches, spit platform and barrier sands). The turnaround from delta plain accretion to river entrenchment and coastal erosion is interpreted to be a consequence of the retreat of the ice margin from the river drainage basins that led to the drastic drop of sediment supply and the abrupt decrease in progradation rates. The main internal stratigraphic discontinuity within the forced regressive deglacial sequence does not reflect changes in relative sea‐level variations.     

Formation of Zn–Ca phyllomanganate nanoparticles in grass roots

It is now well established that a number of terrestrial and aquatic microorganisms have the capacity to oxidize and precipitate Mn as phyllomanganate. However, this biomineralization has never been shown to occur in plant tissues, nor has the structure of a natural Mn(IV) biooxide been characterized in detail. We show that the graminaceous plant Festuca rubra (red fescue) produces a Zn-rich phyllomanganate with constant Zn:Mn and Ca:Mn atomic ratios (0.46 and 0.38, respectively) when grown on a contaminated sediment. This new phase is so far the Zn-richest manganate known to form in nature (chalcophanite has a Zn:Mn ratio of 0.33) and has no synthetic equivalent. Visual examination of root fragments under a microscope shows black precipitates about ten to several tens of microns in size, and their imaging with backscattered and secondary electrons demonstrates that they are located in the root epidermis. In situ measurements by Mn and Zn K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray diffraction (XRD) with a micro-focused beam can be quantitatively described by a single-phase model consisting of Mn(IV) octahedral layers with 22% vacant sites capped with tetrahedral and octahedral Zn in proportions of 3:1. The layer charge deficit is also partly balanced by interlayer Mn and Ca. Diffracting crystallites have a domain radius of 33 Å in the ab plane and contain only 1.2 layers (8.6 Å) on average. Since this biogenic Mn oxide consists mostly of isolated layers, basal 00l reflections are essentially absent despite its lamellar structure. Individual Mn layers are probably held together in the Mn–Zn precipitates by stabilizing organic molecules. Zinc biomineralization by plants likely is a defense mechanism against toxicity induced by excess concentrations of this metal in the rhizosphere.     

Geological,geophysical and geochemical structure of a fault zone developed in granitic rocks: Implications for fault zone modeling in 3-D

The structure of a fault zone developed in granitic rocks can be established on the basis of the spatial variability of geological, geophysical and geochemical parameters. In the North Fault of the Mina Ratones area (SW Iberian Massif, Spain), fault rocks along two studied traverses (SR-2 and SR-3 boreholes) exhibit systematic changes in mineralogy, geochemistry, fabrics and microstructures that are related to brittle deformation and alteration of granite to form cataclasite and subsequent gouge. The spatial distribution and intensity of these changes suggest a North Fault morphology that is consistent with the fault-core/damage-zone model proposed by Chester et al. (1993) to describe a fault zone architecture. North Fault damage zone thickness can be defined by the development of mechanically related mesoscopic faults and joints, that produce a Fracture Index (FI)>10. High FI values are spatially correlated with relative low seismic velocity zones (V_P<5 km/s and V_S<2.5 km/s in the well-logs), more probably related to a high concentration of fractures and geochemical alteration produced by meteoric water-granite interaction along fault surfaces. This correlation is the base of a geostatistical model proposed in the final part of this study to image the fault zone architecture of a granitic massif.     

Sites occupancy of Fe3+ in Garfield Nontronite: A spectroscopic study

New data on the structure of Garfield nontronite have been produced by the use of different spectroscopic techniques: Mössbauer spectroscopy, optical spectroscopy, X-ray absorption edges and EXAFS and NMR. The tetrahedral iron content is found to be no higher than 1 percent. All iron atoms belong to the octahedral sheet excluding the possibility of the presence of non crystallized phases. Some ambiguities remain about the coherence of the octahedral sheet because of the presence of two doublets in the Mössbauer spectrum and at least two lineshapes in NMR spectra of OH which correspond to different environments.     

Isotropic and anisotropic pointing models

This paper describes an alternative approach for generating pointing models for telescopes equipped with serial kinematics, esp. equatorial or alt-az mounts. Our model construction does not exploit any assumption for the underlying physical constraints of the mount, however, one can assign various effects to the respective components of the equations. In order to recover the pointing model parameters, classical linear least squares fitting procedures can be applied. This parameterization also lacks any kind of parametric singularity. We demonstrate the efficiency of this type of model on real measurements with meter-class telescopes where the results provide a root mean square accuracy of 1.5?2 arcseconds.     

Evaluation of recent hydro-climatic changes in four tributaries of the Niger River Basin (West Africa)

West Africa experienced severe drought during the 1970s and 1980s, posing a threat to water resources. A wetter climate more recently suggests recovery from the drought. The Mann-Kendall trend and Theil-Sen’s slope estimator were applied to detect probable trends in weather elements in four sub-basins of the Niger River Basin between 1970 and 2010. The cross-entropy method was used to detect breakpoints in rainfall and runoff, Spearman’s rank test for correlation between the two, and cross-correlation analysis for possible lags. Results showed an overall increase in rainfall and runoff and a decrease in sunshine duration. Spearman’s coefficients suggest significant (5%) moderate to strong rainfall–runoff correlation for three sub-basins. A significant lower runoff was observed around 1979, with a rainfall break around 1992, indicating possible cessation of the drought. Temperatures increased significantly, at 0.02–0.05°C year^-1, with a negative wind speed trend for most stations. Half of the stations exhibited an increase in potential evapotranspiration.

EDITOR M.C. Acreman

ASSOCIATE EDITOR Not assigned     

Digital photographic photometry of NGC 5253 and NGC 2915

The surface digital photometry for NGC 5253 and NGC 2915 is given. The luminosity profiles and colour gradients are discussed and compared. It is concluded that NGC 2915 differs from NGC 5253, both in the extension and intensity of the star burst event because of the kinematical behaviour of the captured gas.CONICET, Buenos Aires, Visiting Astronomer, Cerro Tololo Inter-American Observatory, La Serena, Chile, operated by NSF     

Contractivity-preserving explicit multistep Hermite–Obrechkoff series differential equation solvers

New optimal, contractivity-preserving (CP), explicit, d-derivative, k-step Hermite–Obrechkoff series methods of order p up to \(p=20\), denoted by CP HO(d, k, p), with nonnegative coefficients are constructed. These methods are used to solve nonstiff first-order initial value problems \(y'=f(t,y)\), \(y(t_0)=y_0\). The upper bound \(p_u\) of order p of HO(d, k, p) can reach, approximately, as high as 2.4 times the number of derivatives d. The stability regions of HO(d, k, p) have generally a good shape and grow with decreasing \(p-d\). We, first, note that three selected CP HO methods: 4-derivative 7-step HO of order 13, denoted by HO(4, 7, 13), 5-derivative 6-step HO of order 13, denoted by HO(5, 6, 13), and 9-derivative 2-step HO of order 13, denoted by CMDAHO(13) compare favorably with Adams–Cowell of order 13, denoted by AC(13), in solving standard N-body problems over an interval of 1000 periods on the basis of the relative error of energy as a function of the CPU time. Next, the three HO methods compare positively with AC(13) in solving standard N-body problems on the basis of the growth of relative positional error and relative energy error over 10, 000 periods of integration. Finally, these three methods compare also well with P-stable methods of Cash and Franco et al. on some quasi periodic, second-order linear and nonlinear problems. The coefficients of selected HO methods are listed in the appendix.     

Failure Mode and Spatial Distribution of Damage in Rothbach Sandstone in the Brittle-ductile Transition

— To elucidate the spatial complexity of damage and evolution of localized failure in the transitional regime from brittle faulting to cataclastic ductile flow in a porous sandstone, we performed a series of triaxial compression experiments on Rothbach sandstone (20% porosity). Quantitative microstructural analysis and X-ray computed tomography (CT) imaging were conducted on deformed samples. Localized failure was observed in samples at effective pressures ranging from 5 MPa to 130 MPa. In the brittle faulting regime, dilating shear bands were observed. The CT images and stereological measurements reveal the geometric complexity and spatial heterogeneity of damage in the failed samples. In the transitional regime (at effective pressures between 45 MPa and 130 MPa), compacting shear bands at high angles and compaction bands perpendicular to the maximum compression direction were observed. The laboratory results suggest that these complex localized features can be pervasive in sandstone formations, not just limited to the very porous aeolian sandstone in which they were first documented. The microstructural observations are in qualitative agreement with theoretical predictions of bifurcation analyses, except for the occurrence of compaction bands in the sample deformed at effective pressure of 130 MPa. The bifurcation analysis with the constitutive model used in this paper is nonadequate to predict compaction band formation, may be due to the neglect of bedding anisotropy of the rock and multiple yield mechanisms in the constitutive model.