Patterns of rare earth and other trace elements in different size fractions of clays of Campanian–Maastrichtian deposits from the Portuguese western margin (Aveiro and Taveiro Formations)

The Upper Cretaceous (Campanian–Maastrichtian) Taveiro and Aveiro Formations belong to the northern sector of the Lusitanian basin (Portuguese western margin). The Taveiro Formation was deposited in alluvial fans, including mud flow beds, lakes and sinuous rivers. The Aveiro Formation was deposited in a flat region with low hydrodynamics channels, with the formation of a barrier island-tidal system. The reconstruction of this sedimentary basin may be difficult due to its complex architecture. This work aims a methodology to be used in the reconstruction of Cretaceous sedimentary environments of the Lusitanian basin, through the establishment of geochemical patterns of different size fractions of those deposits. Chemical analysis was performed by instrumental neutron activation analysis (INAA), and the mineralogical composition obtained by X-ray diffractometry (XRD). The whole rock and different size fractions (? ≥ 125 μm, 63–125 μm, 20–63 μm, 2–20 μm and ? < 2 μm) of selected samples were studied aiming the rare earth elements (REE) and other trace elements distribution and its correlation with the grain size and mineralogy.The results obtained for the studied Cretaceous sediments showed that REE patterns and other trace elements distribution in the different size fractions may be used as a tool to differentiate deposits within and between sedimentary formations. Within the Taveiro Formation, REE are concentrated in the silt fractions (20–63 μm and 2–20 μm) of the Reveles deposit, and in the clay size fraction of S. Pedro deposit, which is richer in kaolinite. The 1st transition elements, particularly Zn, are correlated with the presence of smectite in the clay fraction of Reveles deposit. In the sand and silt size fractions (>2 μm) of samples from Taveiro Formation correlations were found between: Ga and 1st transition elements, and phyllosilicates; Cs and mica; and Rb and Ba, and K–feldspars.The Bustos deposit (Aveiro Formation) samples are very fine-grained and with a high proportion of the fine silt fraction where REE are concentrated, especially the heavy ones. Incorporation of MREE, Co and U in carbonates of the coarser fraction appears to occur. The abundances of the 1st transition elements, Ga and As, are correlated with phyllosilicates.Significant differences were found in the trace elements patterns of the various analysed size fractions of the Lusitanian basin of Cretaceous sediments, between and even within formations, which can be used as a methodological approach for a fine paleogeographic reconstruction.     

Combining TEM/resistivity joint inversion and magnetic data for groundwater exploration: application to the northeastern part of Greater Cairo,Egypt

This paper presents the combination of two complementary methods, magnetic and joint inversion of resistivity/TEM data, as an effective approach to characterize groundwater reservoirs. Twenty stations of transient electromagnetic (TEM) and vertical electrical soundings (VES) were measured and interpreted using a joint inversion technique to evaluate the subsurface low resistivity zones connected to the groundwater reservoir. A complementary survey including 871 land magnetic stations was carried out at the same area to detect the upper surface of the basaltic sheet, which represents the bottom of the Miocene aquifer in the study area. The geological log from one borehole drilled in the zone was used to partially calibrate the calculated models. The results revealed that the study area consists of five different geological units with ages ranging from Paleogene (Oligocene) to Quaternary. The methodology provides good results at a very low cost when compared with drilling boreholes.     

HP–LT Variscan metamorphism in the Cubito-Moura schists (Ossa-Morena Zone, southern Iberia)

Multi-equilibrium thermobarometry shows that low-grade metapelites (Cubito-Moura schists) from the Ossa–Morena Zone underwent HP–LT metamorphism from 340–370 °C at 1.0–0.9 GPa to 400–450 °C at 0.8–0.7 GPa. These HP–LT equilibriums were reached by parageneses including white K mica, chlorite and chloritoid, which define the earliest schistosity (S₁) in these rocks. The main foliation in the schists is a crenulation cleavage (S₂), which developed during decompression from 0.8–0.7 to 0.4–0.3 GPa at increasing temperatures from 400–450 °C to 440–465 °C. Fe³⁺ in chlorite decreased greatly during prograde metamorphism from molar fractions of 0.4 determined in syn-S₁ chlorites down to 0.1 in syn-S₂ chlorites. These new data add to previous findings of eclogites in the Moura schists indicating that a pile of allochtonous rocks situated next to the Beja-Acebuches oceanic amphibolites underwent HP–LT metamorphism during the Variscan orogeny. To cite this article: G. Booth-Rea et al., C. R. Geoscience 338 (2006).     

Zinc and sulfur isotope variation in sphalerite from carbonate-hosted zinc deposits,Cantabria, Spain

We studied zinc and sulfur isotopes and the chemical composition of sphalerite samples from Picos de Europa (Aliva mine) and sphalerite and hydrozincite samples from La Florida mine, two carbonate-hosted Mississippi Valley-type (MVT) deposits located in northern Spain; despite being close, they are hosted in carbonatic rocks of different ages, Lower Carboniferous and Lower Cretaceous, respectively. The two generations of sphalerite at Picos de Europa show different δ⁶⁶Zn values (stage 1 sphalerite +0.24 per mil and stage 2 sphalerite from ?0.75 to +0.08 per mil). Both generations also differ in the sulfur isotope composition (stage 1 has δ³⁴S?=?+6.6 and stage 2 has δ³⁴S?=??0.9 to +2.9 per mil) and the chemical composition (stage 1 sphalerite, compared to stage 2 sphalerite, is significantly enriched in Pb, As, Mn, Sb, slightly enriched in Ag, Ni, and Cu and depleted in Co, Ga, Tl, Te, Ge, and Sn). We suggest that Zn isotope fractionation was controlled predominantly by pH and T changes. High Zn isotope values reflect rapid precipitation of sphalerite from higher-temperature acidic fluids that carried Zn mostly as chloride species after interaction with carbonate rocks while lower Zn isotope values most likely resulted from a longer precipitation process from fluid at higher pH and decreasing T that carried dominantly Zn sulfide species. At La Florida, sphalerite samples show light ⁶⁶Zn-depleted signatures with δ⁶⁶Zn values from ?0.80 to ?0.01 per mil (mostly between ?0.80 and ?0.24 per mil) and δ³⁴S values from +10.7 to +15.7 per mil without any relationship between the δ⁶⁶Zn and δ³⁴S values. Here, the variation in Zn isotope values is interpreted as related to mixing of fluids from two reservoirs. The Zn was carried by a single deep-seated and higher T (~250–320 °C) fluid, and precipitation took place after mixing with a connate S-rich fluid in a system with mH₂S?>?mZn²⁺ as a result of change in pH, T, and Zn predominant species. The light δ⁶⁶Zn accompanied by heavy δ³⁴S values resulted from fractionation of Zn aqueous sulfides at near-neutral pH and decreasing T. Hydrozincite samples show much heavier δ⁶⁶Zn values (+0.21 to +0.33 per mil), consistent with fractionation during supergene processes.     

A New Appraisal of Sri Lankan BB Zircon as a Reference Material for LA‐ICP‐MS U‐Pb Geochronology and Lu‐Hf Isotope Tracing

A potential zircon reference material (BB zircon) for laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U‐Pb geochronology and Hf isotope geochemistry is described. A batch of twenty zircon megacrysts (0.5–1.5 cm³) from Sri Lanka was studied. Within‐grain rare earth element (REE) compositions are largely homogeneous, albeit with some variation seen between fractured and homogeneous domains. Excluding fractured cathodoluminescence bright domains, the variation in U content for all analysed crystals ranged from 227 to 368 μg g^?1 and the average Th/U ratios were between 0.20 and 0.47. The Hf isotope composition (0.56–0.84 g/100 g Hf) is homogeneous within and between the grains – mean ¹⁷⁶Hf/¹⁷⁷Hf of 0.281674 ± 0.000018 (2s). The calculated alpha dose of 0.59 × 10¹⁸ g^?1 for a number of BB grains falls within the trend of previously studied, untreated zircon samples from Sri Lanka. Aliquots of the same crystal (analysed by ID‐TIMS in four different laboratories) gave consistent U‐Pb ages with excellent measurement reproducibility (0.1–0.4% RSD). Interlaboratory assessment (by LA‐ICP‐MS) from individual crystals returned results that are within uncertainty equivalent to the TIMS ages. Finally, we report on within‐ and between‐grain homogeneity of the oxygen isotope systematic of four BB crystals (13.16‰ VSMOW).     

A New Genus and Species of Damsel-Dragonfly (Odonata: Isophlebioidea: Campterophlebiidae) in the Middle Jurassic of Inner Mongolia, China

The campterophlebiid new genus and species Ctenogampsophlebia reni is described from the Middle Jurassic of Inner Mongolia, China. It shows close similarities with the Lower to Middle Jurassic genera Gampsophlebia, and Petrophlebia, with closed and short subdiscoidal cells, confirming the attribution of these two other genera to the Campterophlebiidae.     

Long‐term temporal and spatial patterns in bioeroding sponge distribution at the Abrolhos Bank,Brazil, Southwestern Atlantic

Bioeroding sponges belong to the most dominant bioeroders, significantly contributing to the erosion of coral reefs. Some species are tolerant or even benefit from environmental conditions such as ocean warming, acidification, and eutrophication. In consequence, increases in sponge bioerosion have been observed on some coral reefs over the last decades. The Abrolhos Bank is the largest coral reef system in the South Atlantic. It has been affected by sedimentation, eutrophication, overfishing, and climate change, mainly affecting coastal reefs, and at lesser intensity outer ones as well. This study aimed to describe spatial and temporal patterns in bioeroding sponge distribution in carbonate substrates in the Abrolhos Bank. Photo‐quadrats were used to compare bioeroding sponge abundance between two shallow reefs: a coastal, Pedra de Leste (PL), and an outer reef, Parcel dos Abrolhos (PAB). Each individual was delimitated over the substrate by determining the sponge surface through a line connecting the outermost papillae. The study was conducted over 6 years in 2008–2009 and 2013–2016. Four species of bioeroding sponges were identified: Cliona carteri Ridley, 1881, C. delitrix Pang, 1973, C. cf. schmidtii Ridley, 1881, and Siphonodictyon coralliphagum Rützler, 1971. The distribution and abundance of species varied between the inner and outer reefs and across the years, and displayed certain selectivity for the calcareous substrates recorded. Crustose coralline algae (CCA) were the main substrate excavated by the most abundant bioeroding species, C. carteri, and represented 70% of the substrate types occupied by this sponge (CCA, coral overgrown by CCA and plain coral). The highest abundance of bioeroding sponges observed in photo‐quadrats was 21.3 individuals/m² at the outer reefs (PAB) in 2014. The abundances or areal extents of bioeroding sponges were up to 10 times greater on the outer reefs than on the coastal ones, where sedimentation is higher and more strongly influenced by siliciclastic material. Moreover, a higher herbivorous fish biomass has been reported on outer reefs which could also influence the higher abundance of bioeroding sponges in outer reefs. During the study period of 6 years, an increase in bioeroding sponge abundance was observed at the outer reefs (PAB), with the sea surface temperature increase. As CCA have an important role in reefal cementation and carbonate production in the Abrolhos reefs, a bioerosion impact might be expected, in particular, on the outer reefs.     

High-frequency monitoring of hydrological and biogeochemical fluxes in forested catchments of southern Chile

The variability of rainfall-dependent streamflow at catchment scale modulates many ecosystem processes in wet temperate forests. Runoff in small mountain catchments is characterized by a quick response to rainfall pulses which affects biogeochemical fluxes to all downstream systems. In wet-temperate climates, water erosion is the most important natural factor driving downstream soil and nutrient losses from upland ecosystems. Most hydrochemical studies have focused on water flux measurements at hourly scales, along with weekly or monthly samples for water chemistry. Here, we assessed how water and element flows from broad-leaved, evergreen forested catchments in southwestern South America, are influenced by different successional stages, quantifying runoff, sediment transport and nutrient fluxes during hourly rainfall events of different intensities. Hydrograph comparisons among different successional stages indicated that forested catchments differed in their responses to high intensity rainfall, with greater runoff in areas covered by secondary forests (SF), compared to old-growth forest cover (OG) and dense scrub vegetation (CH). Further, throughfall water was greatly nutrient enriched for all forest types. Suspended sediment loads varied between successional stages. SF catchments exported 455 kg of sediments per ha, followed by OG with 91 kg/ha and CH with 14 kg/ha, corresponding to 11 rainfall events measured from December 2013 to April 2014. Total nitrogen (TN) and phosphorus (TP) concentrations in stream water also varied with rainfall intensity. In seven rainfall events sampled during the study period, CH catchments exported less nutrients (46 kg/ha TN and 7 kg/ha TP) than SF catchments (718 kg/ha TN and 107 kg/ha TP), while OG catchments exported intermediate sediment loads (201 kg/ha TN and 23 kg/ha TP). Further, we found significant effects of successional stage attributes (vegetation structure and soil physical properties) and catchment morphometry on runoff and sediment concentrations, and greater nutrients retention in OG and CH catchments. We conclude that in these southern hemisphere, broad-leaved evergreen temperate forests, hydrological processes are driven by multiple interacting phenomena, including climate, vegetation, soils, topography, and disturbance history.