Combining TEM/resistivity joint inversion and magnetic data for groundwater exploration: application to the northeastern part of Greater Cairo,Egypt

This paper presents the combination of two complementary methods, magnetic and joint inversion of resistivity/TEM data, as an effective approach to characterize groundwater reservoirs. Twenty stations of transient electromagnetic (TEM) and vertical electrical soundings (VES) were measured and interpreted using a joint inversion technique to evaluate the subsurface low resistivity zones connected to the groundwater reservoir. A complementary survey including 871 land magnetic stations was carried out at the same area to detect the upper surface of the basaltic sheet, which represents the bottom of the Miocene aquifer in the study area. The geological log from one borehole drilled in the zone was used to partially calibrate the calculated models. The results revealed that the study area consists of five different geological units with ages ranging from Paleogene (Oligocene) to Quaternary. The methodology provides good results at a very low cost when compared with drilling boreholes.     

Volumetric strains in neutral surface folding

Neutral surface folding is a significant contributor to fold development. This mechanism produces contrasting strains in the inner and outer arcs of the folded layer that arise from principal stress orientations that are approximately parallel and perpendicular to the layer. We demonstrate that such stress patterns imply significant gradients of mean stress across the folding layer, being more tensional on the outer arc and more compressive in the inner arc. This could pump fluids towards the outer arc during folding and result in heterogeneous volume changes. We conclude that the neutral surface folding model should be adapted to accommodate volumetric strains, in order to explain dilatational structures (e.g. open fractures, veining) on the extrados and volume-loss structures (e.g. pressure solution seams, stylolitic cleavages) on the intrados. This dilatation has economic implications as it allows prediction of sites of mineralization and zones of secondary permeability in fold-related hydrocarbon traps.     

Landform instability and land-use dynamics in tropical high mountains, Central Mexico

This investigation is an analysis of the influence of landform instability on the distribution of land-use dynamics in a hydrographical basin, located in the Mexican Volcanic Belt mountain range (central Mexico), currently affected by substantial changes in land use and deforestation. A landform map was produced, in addition to seven attribute maps - altimetry, drainage density, slope, relief energy, potential erosion, geology and tectonics - which were considered as factors for determining landform instability through Multi-criteria Evaluation Analysis. Likewise, the direction and rhythm of land-use dynamics were analyzed in four dates - between 1976 and 2000 - and cross tabulations were made between them, in order to analyze the trends and processes of land-use dynamics. Afterwards, the databases obtained were cross tabulated with the landform variables to derive areas, percentages and correlation indices. In the study area, high-instability landforms are associated with most ancient volcanic and sedimentary landforms, where high altitude, drainage density, slope and potential to develop gravitational and fluvial processes are the major factors favouring a land-use pattern, dominated by the conservation of extensive forest land, abandonment of human land use and regeneration of disturbed areas. In contrast, low-instability landforms correspond to alluvial plains and lava hills covered by pyroclasts, where low potential erosion to develop fluvial processes, added to water and soil availability and accessibility, have favoured a land-use pattern dominated by the expansion of agroforestry plantations and human settlements, showing a marked trend towards either intensification or permanence of the current land use and with little abandonment and regeneration.     

The toxicological interaction between ocean acidity and metals in coastal meiobenthic copepods

Increased atmospheric CO₂ concentrations are causing greater dissolution of CO₂ into seawater, and are ultimately responsible for today’s ongoing ocean acidification. We manipulated seawater acidity by addition of HCl and by increasing CO₂ concentration and observed that two coastal harpacticoid copepods, Amphiascoides atopus and Schizopera knabeni were both more sensitive to increased acidity when generated by CO₂. The present study indicates that copepods living in environments more prone to hypercapnia, such as mudflats where S. knabeni lives, may be less sensitive to future acidification. Ocean acidification is also expected to alter the toxicity of waterborne metals by influencing their speciation in seawater. CO₂ enrichment did not affect the free-ion concentration of Cd but did increase the free-ion concentration of Cu. Antagonistic toxicities were observed between CO₂ with Cd, Cu and Cu free-ion in A. atopus. This interaction could be due to a competition for H⁺ and metals for binding sites.     

Flow time estimation with spatially variable hillslope velocity in ungauged basins

The automated spatial estimation of the hillslope runoff dynamics is used as a valuable tool for the estimation of the travel time distribution (flow time), a major factor for the hydrologic prediction in ungauged basins. In fact, while the flow time function is usually obtained by rescaling the flow paths with constant channel and hillslope velocities, in this work a spatially distributed kinematic component, as a function of terrain features and in particular slope and land use, is implemented and its influence on the hydrologic response is tested by means of the Width Function Instantaneous Unit Hydrograph (WFIUH) framework. Hillslope surface flow velocities are evaluated by applying different uniform flow formulas within an automated DEM-based (terrain analysis) algorithm. A comparison test of the performances of the Manning, Darcy, Maidment and Soil Conservation Service uniform flow equations is performed for several case studies in Italy pertaining to different climatic and geomorphic conditions. Results provide new insights for a better understanding of the flow time function also introducing a more parsimonious and physically-based calibration scheme of the WFIUH.     

The validity of the monocentric city model in a polycentric age: US metropolitan areas in 1990, 2000 and 2010

In this article, we use local indicators of spatial association (LISA) and other spatial analysis techniques to analyze the distribution of centers with high employment density within metropolitan areas. We examine the 359 metropolitan areas across the United States at three points in time (1990, 2000, and 2010) to provide a spatio-temporal panoramic of urban spatial structure. Our analysis highlights three key findings. (1) The monocentric structure persists in a majority of metropolitan areas: 56.5% in 1990, 64.1% in 2000, and 57.7% in 2010. (2) The pattern of employment centers remains stable for most metropolitan areas: the number of centers remained the same for 74.9% of metropolitan areas between 1990 and 2000 and for 85.2% between 2000 and 2010. (3) Compared with monocentric metropolitan areas, polycentric metros are larger and more dense, with higher per-capita incomes and lower poverty rates.     

The SHARE European Earthquake Catalogue (SHEEC) 1000–1899

In the frame of the European Commission project “Seismic Hazard Harmonization in Europe” (SHARE), aiming at harmonizing seismic hazard at a European scale, the compilation of a homogeneous, European parametric earthquake catalogue was planned. The goal was to be achieved by considering the most updated historical dataset and assessing homogenous magnitudes, with support from several institutions. This paper describes the SHARE European Earthquake Catalogue (SHEEC), which covers the time window 1000–1899. It strongly relies on the experience of the European Commission project “Network of Research Infrastructures for European Seismology” (NERIES), a module of which was dedicated to create the European “Archive of Historical Earthquake Data” (AHEAD) and to establish methodologies to homogenously derive earthquake parameters from macroseismic data. AHEAD has supplied the final earthquake list, obtained after sorting duplications out and eliminating many fake events; in addition, it supplied the most updated historical dataset. Macroseismic data points (MDPs) provided by AHEAD have been processed with updated, repeatable procedures, regionally calibrated against a set of recent, instrumental earthquakes, to obtain earthquake parameters. From the same data, a set of epicentral intensity-to-magnitude relations has been derived, with the aim of providing another set of homogeneous Mw estimates. Then, a strategy focussed on maximizing the homogeneity of the final epicentral location and Mw, has been adopted. Special care has been devoted also to supply location and Mw uncertainty. The paper focuses on the procedure adopted for the compilation of SHEEC and briefly comments on the achieved results.     

Geodynamic evolution of a forearc rift in the southernmost Mariana Arc

The southernmost Mariana forearc stretched to accommodate opening of the Mariana Trough backarc basin in late Neogene time, erupting basalts at 3.7–2.7 Ma that are now exposed in the Southeast Mariana Forearc Rift (SEMFR). Today, SEMFR is a broad zone of extension that formed on hydrated, forearc lithosphere and overlies the shallow subducting slab (slab depth ≤ 30–50 km). It comprises NW–SE trending subparallel deeps, 3–16 km wide, that can be traced ≥ ∼30 km from the trench almost to the backarc spreading center, the Malaguana‐Gadao Ridge (MGR). While forearcs are usually underlain by serpentinized harzburgites too cold to melt, SEMFR crust is mostly composed of Pliocene, low‐K basaltic to basaltic andesite lavas that are compositionally similar to arc lavas and backarc basin (BAB) lavas, and thus defines a forearc region that recently witnessed abundant igneous activity in the form of seafloor spreading. SEMFR igneous rocks have low Na₈, Ti₈, and Fe₈, consistent with extensive melting, at ∼23 ± 6.6 km depth and 1239 ± 40°C, by adiabatic decompression of depleted asthenospheric mantle metasomatized by slab‐derived fluids. Stretching of pre‐existing forearc lithosphere allowed BAB‐like mantle to flow along the SEMFR and melt, forming new oceanic crust. Melts interacted with pre‐existing forearc lithosphere during ascent. The SEMFR is no longer magmatically active and post‐magmatic tectonic activity dominates the rift.     

Modeling the Permeability Loss of Metallic Iron Water Filtration Systems

Over the past 30 years the literature has burgeoned with in situ approaches for groundwater remediation. Of the methods currently available, the use of metallic iron (Fe⁰) in permeable reactive barrier (PRB) systems is one of the most commonly applied. Despite such interest, an increasing amount of experimental and field observations have reported inconsistent Fe⁰ barrier operation compared to contemporary theory. In the current work, a critical review of the physical chemistry of aqueous Fe⁰ corrosion in porous media is presented. Subsequent implications for the design of Fe⁰ filtration systems are modeled. The results suggest that: (i) for the pH range of natural waters (>4.5), the high volumetric expansion of Fe⁰ during oxidation and precipitation dictates that Fe⁰ should be mixed with a non‐expansive material; (ii) naturally occurring solute precipitates have a negligible impact on permeability loss compared to Fe⁰ expansive corrosion; and (iii) the proliferation of H₂ metabolizing bacteria may contribute to alleviate permeability loss. As a consequence, it is suggested that more emphasis must be placed on future work with regard to considering the Fe⁰ PRB system as a physical (size‐exclusion) water filter device.