研究“源兆”的若干问题及途径分析

从位场理论的观点讨论了场和源的概念,建议将“场兆”改称为构造前兆,将“源兆”称为震源前兆。文中还分析了震源体与各种前兆观测方法探测的深度,并根据地磁与重力观测方法不同的物理基础和地质基础,指出震磁效应对于研究震源前兆的特殊意义,文中还介绍了１９７６唐山地震观测到震源前兆的部分实际地磁资料。     

Gold Solubility in SiO2—HCl—H2O System at 200℃：a Preliminary Assessment of the Implications of Silicification with Regard to Gold Mineralization

The complexation between gold and silica was experimentally, confirmed and calibrated at 200 °C: $$\begin{gathered} Au^ + + H_3 SiO_4^ - \rightleftharpoons AuH_3 SiO_4^0 \hfill \\ \log K_{(200^\circ C)} = 19.26 \pm 0.4 \hfill \\ \end{gathered} $$ Thermodynamic calculations show that AuH₃SiO ₄ ⁰ would be far more abundant than AuCl ₂ ^? under physicochemical conditions of geological interest, suggesting that silica is much more important than chloride as ligands for gold transport. In systems containing both sulfur and silica, AuH₃SiO ₄ ⁰ would be increasingly more important than Au (HS) ₂ ^? as the proportion of SiO₂ in the system increases. The dissolution of gold in aqueous SiO₂ solutions can be described by the reaction: $$\begin{gathered} Au + 1/4O_2 + H_4 SiO_4^0 \rightleftharpoons AuH_3 SiO_4^0 + 1/2H_2 O \hfill \\ log K_{(200^\circ C)} = 6.23 \hfill \\ \end{gathered} $$ which indicates that SiO₂ precipitation is an effective mechanism governing gold deposition, and thus explains the close association of silicification and gold mineralization.     

地铁施工对济南白泉泉群流量的影响

为研究地铁建设对济南白泉泉群的影响，在综合分析白泉泉域地质、水文地质条件的基础上，假定研究区岩溶强径流带位置及水力性质，利用FEFLOW软件建立地下水流数值模型。以规划地铁M1号线为研究对象，分析了济南东站、梁王站、梁王东站分别施工及3个站同时施工4种情景下，采用施工降水或施工降水+人工回灌两种施工方式对白泉泉群流量的影响。结果表明：单独采用施工降水的施工方式使得白泉泉群流量衰减，其中3个站同时施工对泉流量的影响最大，泉流量最大衰减达5.48%；各站分别施工时，济南东站对泉流量影响最大，泉流量较未施工时减少了0.043×10⁴ m³/d。采用施工降水+人工回灌的施工方式，能够有效缓解泉流量的衰减，各车站施工时的泉流量衰减由仅施工降水时的2.26%~5.48%降低至0.08%~1.21%。岩溶强径流带有利于地下水形成优势径流，促进白泉泉群补给，一定程度上缓解因地铁施工引起的泉流量衰减。     

Two-dimensional pH distributions and dynamics in bioturbated marine sediments

The seafloor is the site of intense biogeochemical and mineral dissolution-precipitation reactions which generate strong gradients in pH near the sediment-overlying water interface. These gradients are usually measured in one-dimension vertically with depth. Two-dimensional pH distributions in marine sediments were examined at high resolution (65 × 65 μm pixel) and analytical precision over areas of ∼150 to 225 cm² using a newly developed pH planar fluorosensor. Dramatic three-dimensional gradients, complex heterogeneity, and dynamic changes of pH occur in the surficial zone of deposits inhabited by macrofauna. pH can vary by ±2 units horizontally as well as vertically over millimeter scales. pH minima zones often form in association with redoxclines within a few millimeters of inner burrow walls, and become more pronounced with time if burrows remain stable and irrigated for extended periods. Microenvironmental pH minima also form locally around decaying biomass and relict burrow tracks, and dissipate with time (∼5 d). H⁺ concentrations and fluxes in sandy mud show complex acid-base reaction distributions with net H⁺ fluxes around burrows up to ∼12 nmol cm⁻² d⁻¹ and maximum net reaction rates varying between −90 (consumption) to 120 (production) μM d⁻¹ (∼90 nmol cm⁻¹ d⁻¹ burrow length). Acid producing zones that surround irrigated burrows are largely balanced by acid titration zones along inner burrow walls and outer radial boundaries. The geometry and scaling of pH microenvironments are functions of diagenetic reaction rates and three-dimensional transport patterns determined by sediment properties, such as diffusive tortuosity, and by benthic community characteristics such as the abundance, mobility, and size of infauna. Previously, undocumented biogeochemical phenomena such as low pH regions associated with in-filled relict biogenic structures and burrowing tracks are readily demonstrated by two-dimensional and time-dependent images of pH and sedimentary structure.     

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

高三学生地理自主学习能力的培养

本文以高三地理教学为例,着重阐释了用新课程的视角重新审视地理双基的基本观点,阐述了分析筛选地理主干知识的具体方法,以及地理学科读图的规范和技巧,并从完善认知层次、分析主导因素、注重知识内化、形成迁移能力、培养辩证思维、讲究科学表述等方面论述了高三地理的复习教学策略。     

大气CO2浓度升高对土壤中不同粒级碳的影响

不同粒级土壤中的碳有着不同的周转规律，在高CO2浓度条件下，它们含量的变化将在一定程度上反映土壤碳是累积还是减少，对明确土壤碳的变化趋势有重要意义．采用田间培养试验初步模拟研究在高CO2浓度条件下土壤不同粒级碳的分布．结果表明，加入秸秆培养1年，由于CO2浓度升高的原因导致在低氮（LN）、常规氮（NN）和高氮（HN）水平下土壤中碳分别增加0．01、1．10、1．22g／kg，表现为粒级〈53μm土壤颗粒中碳分别增加1．53、2．19、2．70g／kg．粒级〈53μmm土壤颗粒碳量的增加，主要是由于其重量分配百分数显著增加36．2％，碳浓度增加5．4％；粒级〉250μm和250～53μm土壤颗粒部分虽然其碳浓度分别增加20．8％和17．3％（P〈0．05），怛由于重量分配百分数分别显著降低22．8％和36．1％，结果碳量降低．试验表明高CO2浓度导致不同粒级土壤的分配及碳浓度的变化；高氮施肥水平下有增加土壤碳量特别是小粒级土壤碳量的趋势．     

福建平潭虎潮山滑坡成因机理分析与评价

虎潮山滑坡位于平宏公路12k 704~12k 884段北侧山坡体上,是平潭海岛通往陆地的唯一公路通道。论文通过定性的工程地质分析和定量计算评价了虎潮山坡体稳定性的变化趋势,提出改建公路超挖深切坡脚和持续长时间强降雨导致的孔隙水压力作用是边坡发生滑动破坏的主要因素。     

邢台矿区山字型构造的发现及其地质意义

邢台山字型构造位于河北省邯邢煤田内，其前弧向ES突出，脊柱呈ES-WN走向。分别分析了山字型构造脊柱及其东、西翼反射弧构造形迹特征，对研究区找矿具有重要意义。     

淮北煤田孙庄勘探区煤层气赋存规律及影响因素分析

通过对淮北煤田孙庄勘探区地质构造、沉积特征、煤层煤质及煤层气赋存特征的分析，研究认为有利于本区煤层气赋存的主要因素是较大的埋藏深度、较高的壳质组＋镜质组、较高的变质程度、较大的煤层厚度、低透气性的盖层、较缓的地层倾角和封闭性较好的构造条件，推测煤田深部可能具有一定工业价值的煤层气资源。