Characteristics and genesis of maghemite in Chinese loess and paleosols: Mechanism for magnetic susceptibility enhancement in paleosols

Morphological characteristics and microstructures of magnetic minerals extracted from Chinese loess and paleosols were investigated using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Our results indicate that maghemite in loess–paleosol sequences was transformed from magnetite through oxidation of magnetite. Maghemite transformed from eolian magnetite during chemical weathering has low-angle grain boundaries among maghemite nano-crystals. Some nano-crystalline maghemites with nanoporous texture resulted from microbe-induced precipitation of magnetite or transformation of poorly crystalline ferric Fe (oxy)hydroxides in presence of Fe-reducing bacteria. Aggregates of euhedral maghemite nano-crystals were transformed from magnetite magnetosomes. Both microbe-induced nanoporous magnetite and microbe-produced magnetite magnetosomes are directly related to microbial activities and pedogenesis of the paleosols. It is proposed that the formation of nano-crystalline maghemite with superparamagnetic property in paleosol results in the enhancement of magnetic susceptibility, although the total amount (weight percent) of magnetic minerals in both paleosol and loess units is similar. Our results also show that nano-crystalline and nanoporous magnetite grains prefer to transform into maghemite in semi-arid soil environments instead of hematite, although hematite is a thermodynamically stable phase. This result also indicates that a decrease in crystal size will increase stability of maghemite. It is also inferred that surface energy of maghemite is lower than that of hematite.     

Non-minimum-phase wavelet estimation using second- and third-order moments

This paper presents a new algorithm for estimating non‐minimum‐phase seismic wavelets by using the second‐ and higher‐order statistics (HOS) of the wavelets. In contrast to many, if not most, of the HOS‐based methods, the proposed method does not need to assume that subsurface seismic reflectivity is a non‐Gaussian, statistically independent and identically distributed random process. The amplitude and phase spectra of the wavelets are estimated, respectively, using the second‐order statistics (SOS) and third‐order moment (TOM) of the wavelets, which will, in turn, be derived from the HOS of the seismic traces. In our approach, the wavelets can be ‘calculated’ from seismic traces efficiently; no optimization or inversion is necessarily required. Very good results have been obtained by applying this method to both synthetic and real‐field data sets.     

南半球对流层气候年代际变化及其与太阳活动的联系

通过南半球对流层温度场谱分析和逐次滤波分析发现，南半球对流层大气温度场半个多世纪以来呈现明显的持续升温趋势，升温幅度由低层到高层逐步增加，其中地面层1 000 hPa年升温率为0.013℃/a，对流层中部500 hPa年升温率为0.019℃/ a，对流层上部300 hPa年升温率为0.036℃/ a；滤除南半球大气温度场的趋势变化，发现南半球大气温度场从地面层直至对流层顶广泛盛行着十分显著的与太阳磁场磁性22年周期变化相一致的变化周期。太阳磁场磁性周期变化趋势略有超前，分析认为，这是南半球对流层大气气候系统对太阳磁场周期性变化的响应。进一步分析还发现，南半球从地面层1 000 hPa到对流层顶，再到平流层中部10 hPa各层次大气温度变化22年周期分量振荡位相基本一致，周期振幅由低层到高层迅速增大，说明太阳磁场变化对对流层高层比低层影响大，对平流层影响更大。其中地面层1 000 hPa温度场的22年变化周期是在滤除趋势变化和11年周期之后才显现出来的，所以太阳磁场磁性周期变化对地面层气候的影响较小并且经常处于被掩盖状态；南半球地面层1 000 hPa温度场滤除趋势变化之后显示出十分显著的与太阳活动11年周期相一致的变化周期，分析认为，这是南半球对流层大气气候系统对太阳活动11周期性变化的响应。对流层上层300 hPa温度场滤除趋势变化和22年周期之后也显示出11年变化周期，而对流层中部500 hPa则无此周期反应，说明太阳活动11年周期对地面层1 000 hPa大气气候影响最明显，对流层中上层影响较弱。     

钻孔摩擦灌注桩岩土设计参数取值商榷

桩周岩土极限摩阻力及其桩尖处岩土的容许承载力是公路工程钻(挖)孔摩擦灌注桩单桩竖向承载力计算的重要岩土工程设计参数,其取值是否适当事关工程安危和工程费用的经济合理.对此,工程勘察设计人员不仅应遵照<公路桥涵地基与基础设计规范>有关规定外,还应考虑场地地基岩土的地质时代、场地工程地质条件、岩土工程性质及有关因素合理取值,不可机械地依规范查表确定,这是岩土工程师应具有的最基本技能.     

北极苔原Ny-lesund地区短期气候特征

利用我国北极黄河站所在地,德国Koldwey站1994—2003年的逐时常规气象资料,对北极苔原Ny lesund地区短期气候特征进行了初步分析。结果表明,由于受北大西洋暖流的影响,该地是北极同纬度温度最高的地区。岛上气候温暖湿润,即使在隆冬季节,日平均气温都可以升至0℃以上。全年平均风力较小,以东南(SE)风居多。该地区平均增温速度为0. 68℃/10a,是北极增温较快的地区之一。与同期我国北冰洋浮冰区考察数据相比较,Ny lesund气候更温暖湿润,风速要小得多。在Ny lesund地区,美国国家环境预测中心/美国国家大气研究中心(NCEP/NCAR)的近地面气温的再分析结果,与Koldwey站实测常规地面资料相比,在冬季基本一致,而在夏季则差异较大。     

土钉与锚杆联合支护在深基坑工程中的应用

结合深圳市星海阁办公楼的工程实例,从周边环境对深基坑支护的特殊要求及复杂的地质条件出发,论述了采用土钉与锚杆联合支护形式的依据.介绍了在深基坑支护施工中采取的具体措施后期效果.同时分析了这种联合支护结构形式的力学特点,通过将两者联合使用,可实现锚杆支护结构水平侧移小和土钉支护结构受力合理的优点.且土钉与锚杆联合支护,使得上部锚杆和中下部的土钉墙两者形成了统一的受力整体,共同抵抗荷载和变形.     

锚杆支护及在高承压水土层基坑中的应用

在邻海地区富含高承压水的土层中施工预应力锚杆支护工程的难度很大.介绍了锚杆的构造、作用机理、施工工艺以及决定锚杆施工质量的关键技术.以深圳某商住楼基坑施工为例,探讨了在承压水土层中采用锚杆支护的方法,创造性地提出了"先堵水后注浆"的施工工艺,可供沿海、沿江地区的类似工程借鉴.     

Element mobility during pyrite weathering: implications for acid and heavy metal pollution at mining-impacted sites

Based on back scattered electron images and electron micro-probe analysis results, four alteration layers, including a transition layer, a reticulated ferric oxide layer, a nubby ferric oxide layer and a cellular ferric oxide layer, were identified in the naturally weathering products of pyrite. These layers represent a progressive alteration sequence of pyrite under weathering conditions. The cellular ferric oxide layer correlates with the strongest weathering phase and results from the dissolution of nubby ferric oxide by acidic porewater. Leaching coefficient was introduced to better express the response of element mobility to the degree of pyrite weathering. Its variation shows that the mobility of S, Co and Bi is stronger than As, Cu and Zn. Sulfur in pyrite is oxidized to sulfuric acid and sulfate that are basically released into to porewater, and heavy metals Co and Bi are evidently released by acid dissolution. As, Cu and Zn are enriched in ferric oxide by adsorption and by co-precipitation, but they would re-release to the environment via desorption or dissolution when porewater pH becomes low enough. Consequently, Co, Bi, As, Cu and Zn may pose a substantial impact on water quality. Considering that metal mobility and its concentration in mine waste are two important factors influencing heavy metal pollution at mining-impacted sites, Bi and Co are more important pollutants in this case.     

利用可见光/近红外反射光谱估算土壤总氮含量的实验研究

利用土壤的室内反射率光谱，探讨土壤氮元素的高光谱机理。利用土壤光谱各吸收带的特征参数与总氮含量进行逐步回归运算，确定与氮元素关系比较密切的几个吸收带。计算出这几个特征吸收带内土壤反射率的变化形式：一阶导数(FDR)、倒数(1/R)、倒数之对数(log(1/R))、波段深度(Depth)，并与总氮含量进行逐步回归分析，得到比较理想的结果：建模样本的Ra^2(修正的判定系数)分别为0．789、0．753、0．736、0．699，验证样本的Ra^2分别为0．759、0．468、0．794、0．725。可见土壤的反射率光谱与氮元素含量之间存在比较明显的相关性，可见光／近红外反射光谱具有快速估算土壤中氮元素含量的潜力。