红树植物木榄叶中挥发油的化学成分

以正己烷为溶剂,采用回流提取法提取红树植物木榄叶中的挥发油,运用毛细管气相色谱-质谱联用技术分离检测得到40个峰,鉴定了其中的32种成分,被鉴定成分占挥发油总量的91.92%,其主要成分为烷烃类(30.31%)、萜类化合物(25.22%)、芳香化合物(14.07%)、酸(10.60%)、酯(5.36%)和烯(3.49%).     

姬松茸提取物组分体外抗病毒感染活性的研究

为了探明姬松茸提取物的体外抗病毒感染活性及其作用方式,进而为水产养殖鱼类高效抗淋巴囊肿病毒(lymphocystis disease virus,LCDV)感染活性物质的开发和鲆蝶类淋巴囊肿病的防治奠定基础,利用热水浸提和酒精沉淀法得到了5种姬松茸提取物组分(E1～5),并利用MTT、细胞病变程度观察等方法研究了5种组分对LCDV感染体外培养大菱鲆鳍细胞(turbot fin cells,TF细胞)的影响作用.细胞毒性实验结果显示,5种组分对体外培养TF细胞均无毒性.细胞病变程度结果表明,本文所得5种姬松茸提取物组分尤其是E5组分具有显著的抗LCDV感染TF细胞的活性.不同方式感染的实验结果进一步显示,5种姬松茸提取物组分抗LCDV感染TF细胞的作用可能主要是通过直接灭活病毒和/或阻断病毒吸附细胞来实现的.     

长江和黄河入海沉积物不同粒级中长石/石英比值及化学风化程度评价

长石/石英(F/Q)比值是评估碎屑沉积物化学风化强度的传统指标.在长江大通站和黄河利津站及相应河口区各取9个沉积物样品,将其<125 μm的部分按1间隔分离成7组不同的粒级,用X-ray衍射法半定量分析测定了全样和不同粒级沉积物中石英和长石的相对含量,计算了长石/石英(F/Q)、钾长石/石英(Fk/Q)、斜长石/石英(Fp/Q)比值,据此评估了长江和黄河入海沉积物化学风化强度随粒级的变化.结果显示取自黄河样品的F/Q,Fk/Q和Fp/Q比值在总体上显著高于长江样品,与长江流域的化学风化强度高于黄河的结论一致,可以作为流域沉积物化学风化强度替代指标.长江样品的F/Q,Fk/Q和Fp/Q比值随粒级变细持续变低,黄河样品则呈波动式下降.黄河样品的F/Q高出长江样品的部分主要发生在＜32 μm的细粒级,在粗粒级区间差别很小,当沉积物粒级下降到一定区间后F/Q差异出现快速增加,显示长江流域沉积物的风化程度高于黄河主要发生在较细粒级.上述比值在黄河样品的2～4 μm粒级中高出长江样品3～5倍,是凸显两河化学风化强度差别的敏感粒级,也可以作为两河物源示踪的指标.     

西南地区近21年来NDVI变化特征分析

利用美国国家航天航空局（NASA）归一化植被指数（GIMMS NDVI）资料,初步分析了近21年（1982~2002）来西南地区植被变化特征。结果发现：21年来西南地区植被覆盖状况较好,总体呈增加趋势,同时也存在较明显的季节和区域差异：春季西南大部分地区植被呈较明显的增加趋势。夏季全区NDVI以显著的减小趋势为主,尤以90年代中期以后更为明显。秋季NDVI与夏季类似同样表现为减少趋势,并且范围有所增加。冬季ND-VI以增加为主,存在明显的东西反向特征,东部以减少为主,西部则以增加为主。     

Crystal Structure and Geometry-Optimization Study of N-(2-hydroxy-1-naphthaldene)-4-aminoantipyrme

N-(2-hydroxy-1-naphthaldene)-4-aminoantipyrine has been synthesized. The structure is determined by X-ray diffraction method and elemental analysis. The crystal system belongs to orthorhombic space group P(2)2(1)2(1). The geometry has been ob-tained from the density functional theory (DFT) method and the B3LYP method employing the 6-31G* basis sets. The calculated results propose that the latter is close to the experimental data. The structural parameters from the theory are close to those of the crystal and the calculated total energy of coordination is -31677.172 eV. The energy of HOMO and LUMO and the energy gap are 5.179 eV, -1.603 eV and 3.577 eV, respectively.     

基于近景摄影测量法计算掘进隧洞中切穿顶拱的裂隙面产状

基于近景摄影测量原理,利用掘进隧洞掌子面上裂隙信息,提出了确定裂隙面产状的方法,并通过将被裂隙所切穿的顶拱曲面沿某一方向拉伸的”曲化平”方法,将弧形线转化成直线,然后应用矢量叉乘确定裂隙面产状,实现了对切穿顶拱的裂隙面产状的计算。最后,通过算例验证了该方法的可行性。     

传统海图和电子海图一体化数据模型的构建与应用研究

针对国内在一定时期内既要生产传统纸质海图保证传统导航,又要生产电子海图满足电子导航的需求,构建了一个能够包容S-57电子海图和传统海图信息全集的一体化海图数据模型,基于此模型分析了两种数据到一体化数据模型的转换机制,并应用此模型开发原型系统,实现了二者之间的一体化组织和切换显示,为探索传统海图和电子海图的数据融合提供了思路和参考。     

复合加载条件下吸力式沉箱基础承载特性数值分析

吸力式沉箱基础的承载特性是海洋工程结构设施建造与设计中的一个关键问题。这种新型的深水海洋基础型式,通常承受竖向上拔荷载与水平荷载的共同作用,其工作性能与设计理论远远不能满足工程实践的需要。本文采用有限元分析方法对吸力式沉箱基础的极限承载特性进行数值计算。以大型通用有限元分析软件ABAQUS为平台,通过二次开发,数值实现了Swipe试验加载方法和固定位移比分析方法,针对不同的沉箱长径比、土的强度折减系数,探讨了沉箱基础在垂直上拔荷载和水平荷载单调联合作用下的极限承载力,通过对不同荷载组合的数值计算构造了复合加载条件下沉箱基础破坏包络面。     

波浪作用下孔隙海床-管线动力相互作用分析

波浪作用下海床中的孔隙水压力与有效应力是影响海底管线稳定性的主要因素。然而,在目前的海床响应分析中一般将管线假定为刚性,并不能合理地考虑海床与管线之间的相互作用效应,同时也没有考虑土体和管线加速度对海床动力响应的惯性影响,从而无法确定由此所引起的管线内应力。为此考虑管线的柔性,分别采用饱和孔隙介质的Biot动力固结理论和弹性动力学理论列出了海床与管线的控制方程,进而采用摩擦接触理论考虑海床与管线之间的相互作用效应,基于有限元方法建立了海床-管线相互作用的计算模型及其数值算法。通过变动参数对比计算讨论了管线几何尺寸、海床土性参数对波浪所引起的管线周围海床孔隙水压力和管线内应力的影响。     

Application of Strontium Isotopic Stratigraphy to DatingMarine Sedimentary Units: A Case Study from the PermianStratotype Section in Southern China

The calibration of sedimentary rock absolute dates is one of the difficulties in sedimentological and stratigraphic research. Since strontium(Sr) resides in seawater much longer(≈106 a) than the seawater intermixing time(≈103 a), the Sr isotopic composition of global seawater is uniform at any time and results in a stable system throughout geological history,based on which a global Sr isotope composition dating database has been established for age-calibration of marine strata.The Permian stratigraphic sections in the northern part of the Upper Yangtze block, southern China, record continuous marine sediments with clear stratigraphic boundaries and is suitable for stratigraphic dating of Sr isotopes. Based on sampling and Sr isotopic compositions of Permian carbonate strata in the northern part of the Upper Yangtze, a Permian Sr isotope evolution curve was established. According to the basic principles of Sr isotope stratigraphy, the global Strontium isotope age database can be used to calibrate the Permian stratigraphic dates in the northern Upper Yangtze. The results show that the Sr isotope evolution curves for the marine carbonate rocks in the Permian stratigraphic section of the Upper Yangtze present a decreasing trend from the mid-Qixia stage(P2) to the mid-Wujiaping stage(P3), and then rise from the middle Wujiaping stage to the end of Changxing stage(P3). When the Permian Sr-isotope evolution curve is compared with the global Sr isotope evolution curve in the northern Upper Yangtze, the two are consistent in their long-term evolutionary trend, indicating that Permian global geological events are important controlling factors for the composition and evolution of Sr isotopes. The 87 Sr/86 Sr value decreased gradually in the background of large-scale regressions at the turn of middle to late Permian period, revealing that the Emeishan basalt eruption occurred near the Maokou/Wujiaping boundary(GLB). Srisotope stratigraphy dating was performed on the boundaries of the Qixia Formation/Maokou Formation, Maokou Formation/Wujiaping Formation(GLB), Wujiaping Formation/Changxing Formation(WCB) and the Permian/Triassic(PTB) using the Global Strontium Isotope Age Database. The results are 270.4 Ma, 261.2 Ma, 254.5 Ma and 249.7 Ma,respectively. Based on this, the eruption age of the Emeishan basalts is defined at about 261.2 Ma., which is more coincident with that acquired from other previous dating methods on the eruption age of the Emeishan basalts, and therefore proves that the application of Sr isotopic stratigraphy to dating marine sedimentary units is an effective method.