Unstructured,anisotropic mesh generation for the Northwestern European continental shelf,the continental slope and the neighbouring ocean

A new mesh refinement strategy for generating high quality unstructured meshes of the Northwestern European continental shelf, the continental slope and the neighbouring ocean is presented. Our objective is to demonstrate the ability of anisotropic unstructured meshes to adequately address the challenge of simulating the hydrodynamics occurring in these three regions within a unique mesh. The refinement criteria blend several hydrodynamic considerations as the tidal wave propagation on the continental shelf and the hydrostatic consistency condition in steep areas. Several meshes illustrate both the validity and the efficiency of the refinement strategy. The selection of the refinement parameters is discussed. Finally, an attempt is made to take into account tidal ellipses, providing another cause for anisotropy in the mesh.     

First comparisons of precipitable water vapor estimation using GPS and water vapor radiometers at the Royal Observatory of Belgium

We compare precipitable water vapor (PWV) time series measured by water vapor radiometers (WVRs) to PWV time series estimated using global positioning system (GPS) observations in a regional network of stations in western Europe. Inside this network, we focus on the baseline Brussels – Wettzell which presents the advantage to have the collocation of a GPS receiver and a WVR at both endpoints. The comparison between our GPS and WVR estimations of precipitable water vapor shows an agreement at the millimeter level. In addition, we show that the zenith total delay (ZTD) estimations computed with our GPS processing strategy agrees with the GPS estimations of ZTD done by the CODE analysis center at the millimeter level. Electronic Publication     

Conjoint modeling of residential group preferences: A comparison of the internal validity of hierarchical information integration approaches

 In this paper, two approaches for measuring residential group preferences, based on the method of Hierarchical Information Integration (HII), are compared. In particular, the hypothesis that group-based preference models estimated from integrated HII experiments better predict group preferences than part individual-based group models estimated from classical HII experiments is tested. To that effect, the models' ability to predict group preferences for new residential alternatives is compared in a study of residential preferences of co-ops. Results indicate that integrated HII group experiments indeed result in better predictions of residential preferences.     

Fault-controlled dolomitization at Swan Hills Simonette oil field (Devonian), deep basin west-central Alberta, Canada

The partly dolomitized Swan Hills Formation (Middle‐Upper Devonian) in the Simonette oil field of west‐central Alberta underwent a complex diagenetic history, which occurred in environments ranging from near surface to deep (>2500 m) burial. Five petrographically and geochemically distinct dolomites that include both cementing and replacive varieties post‐date stylolites in limestones (depths >500 m). These include early planar varieties and later saddle dolomites. Fluid inclusion data from saddle dolomite cements (T_h=137–190 °C) suggest that some precipitated at burial temperatures higher than the temperatures indicated by reflectance data (T_peak=160 °C). Thus, at least some dolomitizing fluids were ‘hydrothermal’. Fluorescence microscopy identified three populations of primary hydrocarbon‐bearing fluid inclusions and confirms that saddle dolomitization overlapped with Upper Cretaceous oil migration. The source of early dolomitizing fluids probably was Devonian or Mississippian seawater that was mixed with a more ⁸⁷Sr‐rich fluid. Fabric‐destructive and fabric‐preserving dolostones are over 35 m thick in the Swan Hills buildup and basal platform adjacent to faults, thinning to less than 10 cm thick in the buildup between 5 and 8 km away from the faults. This ‘plume‐like’ geometry suggests that early and late dolomitization events were fault controlled. Late diagenetic fluids were, in part, derived from the crystalline basement or Palaeozoic siliciclastic aquifers, based on ⁸⁷Sr/⁸⁶Sr values up to 0·7370 from saddle dolomite, calcite and sphalerite cements, and ²⁰⁶Pb/²⁰⁴Pb of 22·86 from galena samples. Flow of dolomitizing and mineralizing fluids occurred during burial greater than 500 m, both vertically along reactivated faults and laterally in the buildup along units that retained primary and/or secondary porosity.     

Two-dimensional modelling of some CFC replacement compounds

The Cambridge 2-D Eulerian model has been used to study the potential atmospheric distributions and lifetimes of a number of CFC replacement compounds and their degradation products. The study has focused on HFC 134a and HCFCs 123, 141b and 142b and the major products formed by their atmospheric degradation. The loss of these compounds and their products by hydroxyl radical attack, photolysis and in-cloud hydrolysis have been investigated. The study has shown that HCFCs 141b and 142b have sufficiently long lifetimes to enter the stratosphere in significant quantities, where degradation leads to an increase in the total stratospheric chlorine concentration. The study has also highlighted areas where further experimental work would be valuable, in particular characterisation of the product channels for the degradation reactions and determination of the removal rates of the products in the aqueous phase.     

Major-element vapor fractionation on the lunar surface: An unusual lithic fragment from the Luna 20 fines

A 250-μm fragment in the Luna 20 fines has a very fine-grained “igneous” texture and has the composition (wt.%): SiO₂, 41.1; TiO₂, 0.35; Al₂O₃, 27.2; Cr₂O₃, 0.14; FeO, 4.2; MnO, 0.06; MgO, 8.5; CaO, 17.8; Na₂O, 0.05; and K₂O < 0.02. It contains ～ 65% plagioclase An_99–100, ～ 15% olivine Fo₉₀, ～ 2% Mg-Al spinel and the remainder an unusual interstitial phase with composition SiO₂, 34.8; TiO₂, 1.78; Al₂O₃, 18.3; Cr₂O₃, 0.04; FeO, 14.1; MnO, 0.22; MgO, 5.0; CaO, 24.1; Na₂O, 0.34; K₂O < 0.02. This fragment probably represents a portion of a normal highland rock (anorthositic norite) which was heated to a very high temperature by impact, lost volatiles including SiO₂, and then partially crystallized. The observed phases and their inferred crystallization sequence are consistent with experimental results in the system CaOMgOAl₂O₃SiO₂ (Schairer and Yoder, 1969), assuming the unusual phase to be a residual glass. This type of internal fractionation, leading to silica depletion in the residuum, is different from that normally observed in lunar rocks and is attributed to slightly lower bulk SiO₂ resulting from vapor fractionation due to impact (which also results in lower Na₂O and other volatiles). Because differentiation of the type shown by this fragment is rare in lunar materials, we infer that such major-element vapor fractionation is uncommon on the surface of the moon. The experimental CaOMgOAl₂O₃SiO₂ phase relations also have a bearing on the lunar model proposed by D.L. Anderson in 1973: his “refractory” original lunar composition would differentiate to produce silica deficient liquids, like the unusual phase in our fragment, rather than the normal lunar crustal rocks.     

Oxide minerals in lithic fragments from Luna 20 fines

One hundred and seventy-six oxide mineral grains in the Luna 20 samples were analyzed by electron microprobe. Spinel is the most abundant oxide, occurring in troctolite fragments. Next most abundant is ilmenite, which occurs in all rock types except those containing spinel. Chromite also occurs in all rock types except those containing spinel. Minor amounts of ulvöspinel, armalcolite, zirkelite, baddeleyite and an unidentified TiO₂-rich phase were also found.Spinel grains are predominantly spinel-hercynite solid solutions, commonly with very minor chromite. The $\text{Fe}\text{(Fe + Mg)}$ ratio is generally lower than in spinel from Apollo 14 rocks. Chromites in non-mare rocks are similar to those from mare rocks. Ilmenite of mare origin is Mg-poor and Zr-rich compared to non-mare ilmenite; these elements may therefore be useful in determining the origin of ilmenite grains.Phase equilibria considerations suggest that spinel troctolite crystallized from a melt high in alumina; a likely candidate is the high-alumina basalt of Prinzet al. (1973a).Sub-micron wide rods of metallic Fe occur in plagioclase grains and may have formed by sub-solidus reduction processes.     

Cretaceous stratigraphy and palaeoenvironments of the Southern Petén Basin, Guatemala

The Cretaceous deposits of the Southern Petén Basin, an oil-producing province, are located to the south of the Yucatan Platform and to the east of the Chiapas Carbonate Platform of Mexico. The succession in the southern part of this basin has been studied both in wells and at outcrop by microfacies analysis. It is composed of 5000 m of shallow marine carbonates and evaporites with a few thin layers of pelagic limestones rich in organic carbon and planktic foraminifera deposited during peak transgressions or maximum flooding. The sedimentation of this thick succession was not continuous, and the section is punctuated by subaerial erosional bounding surfaces and a single hardground which marks the final drowning of the carbonate platform during the late Maastrichtian. New age determinations have been obtained on the basis of planktic and benthic foraminifera from the Aptian to Santonian Cobán Formation, D, C, B and A Members. Cobán C (Albian) and B (Cenomanian) Members are the present oil reservoirs. The rudist and alveolinid limestones of late Campanian and Maastrichtian age referred to the Campur Formation in the Southern Petén Basin are here reassigned to the Angostura Formation, as recognized in the Chiapas area. The Actela Formation is defined here to encompass the limestone breccia deposits that occur at the Cretaceous–Tertiary boundary and extend into the Parvularugoglobigerina eugubina Zone of early Danian age. The D, C, B and A Members of the Cobán Formation and the Angostura Formation represent second order transgressive and regressive trends in a passive margin area where the deposits indicate a succession of various environments, including fluviatile, salinas, shallow marine carbonate platform, outer shelf and intrashelf basin. High subsidence rates, sea-level changes and tectonic uplift controlled the sedimentation.

Abstract

Les formations crétacées du sud-est du Bassin du Petén, région pétrolière du nord du Guatemala, sont situées au Sud du Yucatan et à l'Est du Chiapas au Mexique. Ces sédiments ont été étudiés à la fois dans deux puits et à l'affleurement par l'analyse des microfaciès. Cet ensemble sédimentaire est composé de 5000 m de carbonates de plate-forme de faible profondeur et d'évaporites, dans lesquels s'intercalent de minces couches de calcaires pélagiques riches en matière organique et en foraminifères planctoniques. Ces calcaires pélagiques se sont déposés lors des maximums de transgressions. La sédimentation de cette épaisse série n'est pas continue et est ponctuée par quelques surfaces d'érosion sub-aérienne et une surface durcie qui souligne l'ennoyage définitif de la plate-forme carbonatée au Maastrichtien terminal. De nouvelles datations ont été obtenues sur la formation Cobán et ses membres D, C, B et A qui s'étagent de l'Aptien au Santonien. Les membres C (albien) et B (cénomanien) constituent les réservoirs productifs. Les calcaires à rudistes et à alveolinidés du Campanien supérieur–Maastrichtien ont été appelés à tort au Petén formation Campur. Ils doivent, selon nous, être attribués à la formation Angostura comme au Chiapas voisin, où affleurent des faciès comparables et de même âge. Une nouvelle formation est créée (formation Actela) pour les brèches calcaires de la limite Crétacé–Tertiaire et de la Zone à Eugubina du Danien inférieur. Les membres D, C, B, A de la formation Cobán et la formation Angostura représentent des cycles transgressifs–régressifs de deuxième ordre. Sur cette marge passive du Petén, les dépôts correspondent à des environnements variés comme des terres émergées soumises à une altération karstique et à des dépôts fluviatiles, des salinas, des plates-formes carbonatées marines, des shelf externes et des bassins intra plate-forme. La sédimentation a été, ici, contrôlée par une forte vitesse de subsidence, les variations du niveau marin et des soulèvements tectoniques.