Governance arrangements targeting diversity in Europe: how New Public Management impacts working with social cohesion

This article analyses how policies to foster social cohesion within diverse and unequal urban contexts are affected by New Public Management and austerity policies. Based on the analysis of a handful of governance arrangements in three cities that differ in their institutional structure and diversity policy approaches (Copenhagen, Leipzig and Milan), it is shown that negative effects are quite widespread yet cushioned by a strong welfare state structure, solid local government and high priority given to the recognition of diversity. Nevertheless, the shift towards the application of market logic to social work reduces innovative potential, increases efforts spent on procedures and weakens public coordination.     

Environmental suitability of ceramic raw materials: a geochemical approach to volatile emissions and leaching potentials

Growing environmental concern is promoting the necessity of additional ceramic tests. The use of unknown materials with potential contamination conditions requires further studies to demonstrate that the piece encapsulates the pollutant and that during its firing it does not produce the emission of harmful volatile elements. The objective of this work was to perform both tests in a ceramic paste made with slip-casting wastes and electro-plating residues. The leaching methods for determining the encapsulation of potential harmful elements were performed following the TCLP, EP-Tox norm. Having precise chemical analysis of both crude and fired brick, the problem of emissions losses during the firing can be solved by the gain/loss techniques used in geological studies. In particular, the Isocon method that permits a quick visualization of the lost elements is useful. Once the volatile elements were determined, their amount was calculated considering a constant element and the chemical concentrations normalized by the loss of ignition, or using the crude/fired brick ratio densities. The leaching tests indicate that the ceramic brick does not produce harmful leachates according to Argentinean specifications. The leachates of B and Ca are high. Ca does not seem to be a problem while the B content is beyond the permitted limits. During the firing, volatilized elements are Ag, Br, Cl, F, Hg, S, Se, and H₂O. The loss of Ag, Br, and Se are negligible. For F and Cl the potential emission rate is very low (100 mg/kg) while in the case of S, the 2,600 mg/kg rate is high. However, extrapolated emission rates at the chimney assuming an air-to-brick ratio of 2.5 N m³/kg, are approximately 1,040 mg/N m³ for S and 40 mg/N m³ for F and Cl, falling inside environmentally acceptable values. The geochemical procedures proved to be useful tools to assess the element mobilization during firing of ceramic wares and in the analyzed case, the results indicate that the paste is environmentally acceptable.     

Partition of arsenic in soils sediments and the origin of naturally elevated concentrations in groundwater of the southern pampa region (Argentina)

Excessive arsenic concentrations above the Argentinean and WHO guidelines for drinking water (10 μg L⁻¹) affects shallow aquifers of the southern Pampean Plain (Argentina) hosted in the Pampean and the Post Pampean formations (loess and reworked loess; Plio-Pleistocene–Holocene). Health problems related to high As concentrations in drinking waters are known as Endemic Regional Chronic Hydroarsenicism. Hydrochemistry of shallow groundwaters and soil geochemistry were investigated aiming to (1) understand the partition of As in the solid phase and its relationship with unacceptable As concentrations in waters, (2) identify the provision source of As to groundwaters. Only 5% of the samples had As concentrations <10 μg L⁻¹; in 27% As concentrations ranged from 10 to 50 μg L⁻¹ and in 58% it reached 60–500 μg L⁻¹. The coarse fraction (50–2,000 μm) hosts about 27% of the total As in the solid phase, being positively correlated to Ba (p < 0.01; r ² = 0.93). About 70% is included in the <2 μm fraction and had positive correlations of As–Fe (p < 0.05; r ² = 0.85) and As–Cr (p < 0.05; r ² = 0.68). Soils and sediment sand fractions of vadose zones are the primary sources of As in shallow groundwater while adsorption–desorption processes, codisolution–coprecipitation, and evaporation during the dry seasons raise As concentrations in waters exceeding the guideline value for drinking water.     

Magmatism and fenitization in the Cretaceous potassium-alkaline-carbonatitic complex of Ipanema S?o Paulo State, Brazil

The Ipanema alkaline-carbonatitic complex is part of the Meso-Cenozoic alkaline magmatism located within the southeastern part of the Brazilian Platform. Drill-core and field sampling have indicated the occurrence of glimmerites, with subordinate shonkinites (mela-syenites), clinopyroxene-bearing glimmerites, diorites and syenites. The glimmerites are cross-cut by lamprophyric dykes and calciocarbonatites. Fenitization has deeply affected the country rocks, originating dioritic and syenitic rocks. The Ipanema rocks show a distinct potassic affinity. The initial Sr-Nd- isotopic composition of the Ipanema rocks (⁸⁷Sr/⁸⁶Sr?=?0.70661–0.70754 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51169–0.51181) is similar to that of tholeiitic and potassium-rich-alkaline rocks of the Eastern Paraguay. Stable isotope data for the Ipanema calciocarbonatite suggest interaction with fluids at temperatures typical of hydrothermal stages, as hypothesized for other carbonatite complexes from southeastern Brazil. The chemical differences between the lamprophyre, glimmerites, carbonatites, apatitites and magnetitites, and the absence of marked REE enrichment in the evolved lithologies, all indicate that fractional crystallization and accumulus of liquidus phases in a magma reservoir, likely coupled with liquid immiscibility processes, may have played an important role in the genesis of the Ipanema rocks.     

Sedimentary record of Late Paleozoic rift and break-up in Northern Gondwana: a case history from the Thini Chu Group and Tamba-Kurkur Formation (Dolpo Tethys Himalaya,Nepal)

The Gottero unit of the Northern Apennines, Italy, is representative of the sedimentary cover of the Ligure-Piemontese oceanic lithosphere. This unit consists of a thick sedimentary sequence that includes Valanginian-Santonian pelagic deposits and Campanian-early Paleocene turbiditic deposits. The latter are overlain by early Paleocene trench deposits related to frontal tectonic erosion of the accretionary wedge slope. This sequence is interpreted as recording trenchward motion of the oceanic lithosphere.

The Gottero unit records a pre-Late Oligocene, complex deformation history related to subduction and accretion events. This deformation history has developed through underthrusting (D1a), underplating (D1b and D1c) and later exhumation (D2a and D2b) episodes. The folding phase related to the main underplating sub-phase (D1b) is predated by a sub-phase (D1a) connected to rapid fluid escape and followed by a sub-phase dominated by the development of shear zones (D1c). The D1b sub-phase is characterized by similar folds and a slaty cleavage developed under P/T conditions of 0.4GPa/210°-270 °C. The D1c sub-phase, characterized by west-verging thrusts, is particularly signficative in understanding the dynamics of the Ligure-Piemontese accretionary wedge because it testifies active shortening of the Gottero unit also after its transfer to the prism. In addition, sub-phase D1c represents the transition from the sub-phases connected to accretion and the tectonics dominated by extension, characterized by parallel folds and low-to high-angle normal faults. The gravity driven extension is represented by the D2a and D2b sub-phases and can be interpreted as the result of the thicknening of the Ligure-Piemontese accretionary wedge, produced by continuous underplating at its base but also by shortening of the previously underplated units. These final tectonic events resulted in the exhumation of the Gottero unit to the surface during the Early Oligocene, when this Unit became one of the source areas of the conglomerates deposited in the Tertiary Piedmont basin.

This deformation history suggests the occurrence of a complex sequence of deformations during the transition from accretion to exhumation, even in the intermediate levels of the accretionary wedge.     

Grain-size dependence of sediment composition and environmental bias in provenance studies

This article investigates both experimentally and theoretically the compositional changes associated with textural effects and hydraulic sorting during sediment transport and deposition, which cause systematic distortion in quantitative provenance analysis (“environmental bias”). Traditional procedures aimed at eliminating textural noise find limited success. The Gazzi–Dickinson method cannot remove hydrodynamic-related modal variability. Multiple size-window strategies are time-consuming. Narrow or moving size-window strategies represent misleading or impractical short cuts, being less convenient options than simply analysing each sample in bulk. New concepts introduced here unravel the superposed causes of compositional variability in modern sediments. Intrasample modal variability, fundamentally explained by settling-equivalence relationships, can be accurately modelled mathematically. Intersample modal variability, principally resulting from selective entrainment, can be assessed and removed by a simple principle. In absence of provenance changes and environmental bias, the weighted average density of terrigenous grains (SRD index) should be equal, for each sample and each grain-size class of each sample, to the weighted average density of source rocks. By correcting relative abundances of detrital minerals in proportion to their densities, we can restore the appropriate SRD index for any provenance and subprovenance type in each sample or grain-size class. Modal variability is effectively reduced by this procedure, which can be applied confidently to modern sediments deposited by tractive currents in any environment. Good results are obtained even for placer sands and finest classes where heavy-mineral concentration is strongest. Such “SRD correction” also successfully compensates for biased narrow-window modes, thus providing a numerical solution of general validity to the problem of environmental bias in sedimentary petrology. After compensating for settling-equivalence and selective-entrainment effects, residual size-dependent compositional variability may be provenance-related. Minor in Ganga–Brahmaputra sediments, provenance-related effects are spectacularly displayed in the Nile basin, where volcaniclastic silt mixes with basement-derived quartzofeldspathic sand and wind-blown Saharan quartz.     

Populus nigra L. establishment and fluvial landform construction: biogeomorphic dynamics within a channelized river

Populations of the riparian pioneer species Populus nigra L. which establish on alluvial bars within river channels modulate sediment dynamics and fluvial landforms. Dense cohorts of P. nigra have colonized gravel point bars along the channelized River Garonne, France, during the last 20 years and have enhanced the vertical, lateral and longitudinal development of the bars. For this period, the geomorphic characteristics of two wooded point bars on this laterally stable river are closely linked to the spatial distribution and intensity of establishment and resistance of different cohorts of P. nigra. Furthermore, P. nigra colonization dynamics were controlled by engineer effects of this same species. This relationship is illustrated by a significant correlation between key geomorphic and biological variables measured in situ and characterized with a set of four aerial photographs taken between 2000 and 2010. The development of wooded point bars, which are discrete biogeomorphic units, over the studied period, appear to result from a specific biogeomorphic positive feedback of matter aggregation and vegetation establishment related to sediment trapping and stabilization by pioneer engineer plants. We propose a conceptual model of biogeomorphic unit construction for channelized, lateral stable rivers. We consider the resultant biogeomorphic units as functional from an ecological point of view because P. nigra enhances at the cohort scale (i) its own inherent capacity to resist hydrogeomorphic disturbances, and (ii) its resilience capacity as a result of successful colonization, especially downstream of mature poplar stands. Copyright © 2016 John Wiley & Sons, Ltd.     

Tracking sediment provenance and erosional evolution of the western Greater Caucasus

This article investigates landscape characteristics and sediment composition in the western Greater Caucasus by using multiple methods at different timescales. Our ultimate goal is to compare short‐term versus long‐term trends in erosional processes and to reconstruct spatio‐temporal changes in sediment fluxes as controlled by partitioning of crustal shortening and rock uplift in the orogenic belt. Areas of active recent uplift are assessed by quantitative geomorphological techniques [digital elevation model (DEM) analysis of stream profiles and their deviation from equilibrium] and compared with regions of rapid exhumation over longer time intervals as previously determined by fission‐track and cosmogenic‐nuclide analyses. Complementary information from petrographic and heavy‐mineral analyses of modern sands and ancient sandstones is used to evaluate erosion integrated throughout the history of the orogen. River catchments displaying the highest relief, as shown by channel‐steepness indices, correspond with the areas of most rapid exhumation as outlined by thermochronological data. The region of high stream gradients is spatially associated with the highest topography around Mount Elbrus, where sedimentary cover strata have long been completely eroded and river sediments display the highest metamorphic indices and generally high heavy‐mineral concentrations. This study reinforces the suggestion that the bedrock–channel network can reveal much of the evolution of tectonically active landscapes, and implies that the controls on channel gradient ultimately dictate the topography and the relief along the Greater Caucasus. Our integrated datasets, obtained during a decade of continuing research, display a general agreement and regularity of erosion patterns through time, and consistently indicate westward decreasing rates of erosional unroofing from the central part of the range to the Black Sea. Copyright © 2014 John Wiley & Sons, Ltd.     

Occurrence,distribution and partitioning of nonionic surfactants and pharmaceuticals in the urbanized Long Island Sound Estuary (NY)

This work deals with the environmental distribution of nonionic surfactants (nonylphenol and alcohol ethoxylates), their metabolites (NP, nonylphenol; NPEC, nonylphenol ethoxycarboxylates; and PEG, polyethylene glycols) and a selection of 64 pharmaceuticals in the Long Island Sound (LIS) Estuary which receives important sewage discharges from New York City (NYC). Most target compounds were efficiently removed (>95%) in one wastewater treatment plant monitored, with the exception of NPEC and some specific drugs (e.g., hydrochlorothiazide). Concentrations of surfactants (1.4–4.5 μg L⁻¹) and pharmaceuticals (0.1–0.3 μg L⁻¹) in seawater were influenced by tides and sampling depth, consistent with salinity differences. Surfactants levels in suspended solids samples were higher than 1 μg g⁻¹, whereas only most hydrophobic or positively charged pharmaceuticals could be found (e.g., tamoxifen, clarithromycin). Maximum levels of target compounds in LIS sediments (PEG at highest concentrations, 2.8 μg g⁻¹) were measured nearest NYC, sharply decreasing with distance from major sewage inputs.