Monsoon driven changes in phytoplankton populations in the eastern Arabian Sea as revealed by microscopy and HPLC pigment analysis

Like the rest of the Arabian Sea, the west coast of India is subject to semi-annual wind reversals associated with the monsoon cycle that result in two periods of elevated phytoplankton productivity, one during the northeast (NE) monsoon (November–February) and the other during the southwest (SW) monsoon (June–September). Although the seasonality of phytoplankton biomass in these coastal waters is well known, the abundance and composition of phytoplankton populations associated with this distinct and predictable seasonal cycle is poorly known. Here we present for the first time, the results of a study on the community structure of phytoplankton for this region, derived from HPLC pigment analysis and microscopic cell counts. Our sampling strategy allowed for large spatial and temporal coverage over regions representative of the coastal and offshore waters, and over seasons that included the NE and the SW monsoon. Monthly observations at a fixed coastal station in particular, allowed us to follow changes in phytoplankton community structure associated with the development of anoxia. Together these measurements helped establish a pattern of seasonal change of three major groups of phytoplankton: diatoms, dinoflagellates and cyanobacteria that appeared to be tightly coupled with hydrographic and chemical changes associated with the monsoonal cycle. During the SW monsoon when nitrate concentrations were high, diatoms were dominant but prymnesiophytes were present as well. By October, as nitrate fell to below detection levels and anoxic conditions began to develop on the shelf below the shallow pycnocline, both diatom and prymensiophytes declined sharply giving way to dinoflagellates. In the well oxygenated surface waters, where both nitrate and ammonium were below detection limits, pico-cyanobacterial populations became dominant.During the NE monsoon, a mixed diatom-dinoflagellate population was quickly replaced by blooms of Trichodesmium erythraeum and Noctiluca miliaris with higher amounts of zeaxanthin, β-carotene, Chl b and prasinoxanthin. Trichodesmium trichomes were noticed in the water column as early as December when nitrate concentrations became limiting. The low phytoplankton biomass and high ammonium concentrations argue that active grazing populations may be responsible for preventing diatom-dinoflagellate populations from establishing themselves to bloom proportions in the eastern Arabian Sea during the early NE monsoon. Trichodesmium continued its dominance well into May, when nutrient enrichment associated with its death and decay helped simulate the growth of both diatoms and dinoflagellates. Given that anoxic conditions are becoming more pervasive in the eastern Arabian Sea, our observations in particular, those of a shift towards dinoflagellate dominance during the development of anoxia assume particular importance.     

Three-Dimensional Interpolation and Lithofacies Analysis of Granular Composition Data for Earthquake-Engineering Characterization of Shallow Soil

In Japan, many major cities are located on tectonic basins which are surrounded by faults and underlain by soft alluvial materials. Because these areas are subject to earthquake damages, it is important to determine their seismic engineering characteristics. Geotechnical databases which contain many borehole logs are useful information sources for this type of analysis. Each datum stored in the database has a value or an attribute, and its location is irregular in both horizontal and vertical directions. A new interpolation method based on the optimization principle is proposed here to deal with such three-dimensionally distributed data. Susceptibility of unconsolidated ground to liquefaction is known to be related to the content of loose and saturated sand. The mixture ratio of several soil types in a deposit, i.e., granular composition, is strongly influenced by the sedimentary environment. There are two numerical methods: the optimization principle method (OPM) used to determine three-dimensional distribution of granular composition and the model used to evaluate liquefaction. The application of the proposed methods to two locations in Japan indicated that the zones with high susceptibility to liquefaction were indeed those that had suffered from liquefaction during past earthquakes.     

Coupling of boundary and finite elements for soil-structure interaction problems

The investigation of complex soil-structure interaction problems is usually carried out with numerical solution procedures such as the finite element or the boundary element method. It must be noted, however, that the choice of one or the other of these approaches is not just a matter of preferences; depending on the type of the problem under consideration, either boundary or finite elements may be more advantageous. A considerable expansion in the computational power can be obtained, on the other hand, if one resorts to hybrid schemes which retain the main advantages of the two methods and eliminate their respective disadvantages. This paper presents results obtained with a boundary element-finite element coupling procedure, and discusses its applicability to some representative soil-structure interaction problems. The structures considered are elastic systems, such as foundations, tunnels and filled trenches (modelled by finite elements), which are coupled with homogeneous elastic halfspaces (modelled by boundary elements). The examples demonstrate the importance of using a model that includes wave radiation effects. The coupling approach is formulated entirely in the time domain so that an extension of the algorithm to non-linear analyses seems to present no further difficulties.     

Natural analogues for the transuranic actinide elements: An investigation in Minas Gerais,Brazil

A highly weathered deposit of thorium and rare earth elements located near the summit of a hill in the state of Minas Gerais, Brazil, is being studied as an analogue for a radioactive waste repository that sometime in the distant future may be eroded to the surface or intruded by groundwater Thorium serves as an analogue for Pu⁴⁺, and La³⁺ as an analogue for Cm³⁺ and Am³⁺ The mobilization rate constants of the analogue elements by groundwater are so slow (of the order of 10⁻⁹ per year) as to suggest that essentially complete radioactive decay of the transuranic actinides would occur in place even under the relatively unfavorable conditions that exist at a site such as this     

Early Paleozoic Structural and Metamorphic Evolution of Western Sierra de San Luis (Argentina), in Relation to Cuyania Accretion

Structural, metamorphic and isotopic data obtained from the Nogoli Metamorphic Complex of western Sierra de San Luis indicate that the Early Paleozoic Famatinian Orogeny overprinted an already structured and metamorphosed older basement. The older geological features are relict NW trending fabric associated with high-grade (amphibolite facies) regional metamorphism preserved within thin strips of schists and paragneisses and in the core of mafic to ultramafic lenses. Arc magmatism, medium P (Barrovian type)/high T (amphibolite to granulite facies) regional metamorphism and penetrative NNE to NE trending foliation are related to the building of the Famatinian orogenic belt. The P-T conditions of the Famatinian prograde metamorphism reached a pressure peak of ca. 8 kb, with a thermal peak from -750°C up to -820°C. U-Pb conventional and chemical dating and Ar-Ar plateau ages constrain the peak of the main orogenic phase related to the Famatinian belt to 470–457 Ma (Early to Mid-Ordovician). Greenschist facies retrograde metamorphism closely associated with shear zones and secondary Ar-Ar plateau and Sm-Nd ages suggest that a late to post-orogenic phase of the Famatinian belt was active at least since -445 Ma. This phase continued during the Silurian to Late Devonian times through multiple reactivation of early shear zones. The Famatinian Orogeny reset a previous thermal history and therefore, the timing of the relict fabric could not be constrained conclusively with radiometric dates. Despite this difficulty, a range of 520 to 490 Ma suggests some inheritance from Pampean events registered by the older NW-SE fabric. The Early to Mid-Ordovician regional metamorphism and ductile deformation of the western Sierra de San Luis is interpreted as the orogenic effects of the collision of the allochthonous Cuyania terrane with the autochthonous proto-Pacific margin of Gondwana during the Famatinian Orogeny.     

Verification of the Contribution of Vehicular Traffic to the Total NMVOC Emissions in Germany and the Importance of the NO3 Chemistry in the City Air

In 1997 and 1998 several field campaigns for monitoring non-methane volatile organic compounds (NMVOCs) and nitrogen oxides (NO_x) were carried out in a road traffic tunnel and in the city center of Wuppertal, Germany. C₂–C₁₀ aliphatic and aromatic hydrocarbons were monitored using a compact GC instrument. DOAS White and long path systems were used to measure aromatic hydrocarbons and oxygenated aromatic compounds. A formaldehyde monitor was used to measure formaldehyde. Chemiluminescence NO analysers with NO₂ converter were used for measuring NO and NO₂. The high mixing ratios of the NMVOCs observed in the road traffic tunnel, especially 2.9 ppbv phenol, 1.5ppbv para-cresol and 4.4 ppbv benzaldehyde, in comparison with themeasured background concentration clearly indicate that these compounds were directly emitted from road traffic. Para-Cresol was for the first timeselectively detected as primary pollutant from traffic. From the measured data a NMVOC profile of the tunnel air and the city air, normalised to benzene (ppbC/ppbC), was derived. For most compounds the observed city air NMVOC profile is almost identical with that obtained in the traffic tunnel. Since benzene originates mainly from road traffic emission, the comparison of the normalised emission ratios indicate that the road traffic emissions in Wuppertal have still the largest impact on the city air composition, which is in contrast to the German emission inventory. In both NMVOC profiles, aromatic compounds have remarkably large contributions of more than 40 ppbC%. In addtion, total NMVOC/NO_x ratios from 0.6 up to 3.0ppbC/ppb in the traffic tunnel air and 3.4± 0.5 in the city air of Wuppertal were obtained. From the observed para-cresol/toluene and ortho-cresol/toluene ratios in the city air, evidence was found thatalso during daytime NO₃ radical reactions play an important role in urban air.     

Groundwater Level Prediction/Forecasting and Assessment of Uncertainty Using SGS and ARIMA Models: A Case Study in the Bauru Aquifer System (Brazil)

Natural Resources Research - Best water management practices should involve the prediction of the availability of groundwater resources. To predict/forecast and consequently manage these water...     

Linking shock textures revealed by BSE,CL, and EBSD with U‐Pb data (LA‐ICP‐MS and SIMS) from zircon from the Araguainha impact structure,Brazil

A silicious impact melt rock from polymict impact breccia of the northern part of the alkali granite core of the Araguainha impact structure, central Brazil, has been investigated. The melt rock is thought to represent a large mass of impact‐generated melt in suevite. In particular, a diverse population of zircon grains, with different impact‐induced microstructures, has been analyzed for U‐Pb isotopic systematics. Backscattered electron and cathodoluminescence images reveal heterogeneous intragrain domains with vesicular, granular, vesicular plus granular, and vesicular plus (presumably) baddeleyite textures, among others. The small likely baddeleyite inclusions are not only preferentially located along grain margins but also occur locally within grain interiors. LA‐ICP‐MS U‐Pb data from different domains yield lower intercept ages of 220, 240, and 260 Ma, a result difficult to reconcile with the previous “best age” estimate for the impact event at 254.7 ± 2.7 Ma. SIMS U‐Pb data, too, show a relatively large range of ages from 245 to 262 Ma. A subset of granular grains that yielded concordant SIMS ages were analyzed for crystallographic orientation by EBSD. Orientation mapping shows that this population consists of approximately micrometer‐sized neoblasts that preserve systematic orientation evidence for the former presence of the high‐pressure polymorph reidite. In one partially granular grain (#36), the neoblasts occur in linear arrays that likely represent former reidite lamellae. Such grains are referred to as FRIGN zircon. The best estimate for the age of the Araguainha impact event from our data set from a previously not analyzed type of impact melt rock is based on concordant SIMS data from FRIGN zircon grains. This age is 251.5 ± 2.9 Ma (2σ, MSWD = 0.45, p = 0.50, n = 4 analyses on three grains), indistinguishable from previous estimates based on zircon and monazite from other impact melt lithologies at Araguainha. Our work provides a new example of how FRIGN zircon can be combined with in situ U‐Pb geochronology to extract an accurate age for an impact event.     

Do the shallow‐water habitats of a hypersaline tropical estuary act as nursery grounds for fishes?

Fish assemblages were studied in a hypersaline tropical estuary in Northeastern Brazil. A total of 104 species were collected by beach seine during the dry and rainy seasons of 2012. Two families, Atherinopsidae and Gerreidae, were numerically dominant in all zones of the estuary; juveniles of Atherinella brasiliensis, Eucinostomus argenteus, Lile piquitinga, Ulaema lefroyi, Lutjanus analis and Sphoeroides greeleyi contributed 77% of the total catch. The factors that best explained the fish abundance pattern were salinity and depth, which were related to spatial segregation. Species richness was lowest in the upper zone, an area with high salinity and shallow depth. The distinct roles of structurally different habitats (submerged macrophyte beds and mangrove prop‐roots) and the influence of physicochemical conditions in the middle zone of the estuary may influence taxonomic diversity. The middle zone of the estuary is the one most attractive to juveniles of reef species (Lutjanidae and Serranidae). The fish assemblages are clearly dominated by marine estuarine dependent species, highlighting the importance of the ecosystem as a nursery ground for marine species of the Brazilian coast.