Determination of Te,As, Bi,Sb and Se (TABS) in Geological Reference Materials and GeoPT Proficiency Test Materials by Hydride Generation‐Atomic Fluorescence Spectrometry (HG‐AFS)

The study of Te, As, Bi, Sb and Se (TABS) has increased over the past years due to their use in the development of low‐carbon energy technologies. However, there is a scarcity of mass fraction values of TABS in geological reference materials. This underlines the difficulty in undertaking routine determinations of these elements. The mass fractions of TABS were determined in geological reference materials using hydride generation‐atomic fluorescence spectrometry (HG‐AFS), calibrated with standard solutions. Comparisons with literature values were used to validate the method. Samples from the GeoPT proficiency test were also analysed. For most elements, there are no assigned or even provisional values for many of the GeoPT and reference materials because of the wide range of results reported. For mass fractions above the quantification limit of the method, our results are in good agreement with the median of GeoPT results. Thus, we propose GeoPT median values as informational values for these elements. In contrast, at mass fractions < 0.5 µg g^?1 median values of Se from GeoPT are systematically higher than our results. Our Se results are in agreement with the reference materials down to 0.02 µg g^?1, which suggest that many of the results for Se reported in GeoPT testing are too high.     

Construction and assessment of a logistic regression model applied to short-term forecasting of thunderstorms in León (Spain)

Forecasting thunderstorms is one of the most difficult tasks in weather prediction due to the scarce knowledge on how to characterise the mechanisms taking part in the formation of thunderstorms. New tools based upon the objective recognition of appropriate conceptual models have been developed in the last years. A good example of this are the statistical models, based on variables that characterise the preconvective atmospheric conditions.This paper presents the results obtained by applying a short-term forecast model to thunderstorms during the summer periods in León (Spain). This model makes use of the logistic function as a binary forecasting technique determining storm/no storm. The logistic function used was a combination of 15 previously selected meteorological variables. The model has been constructed with the data collected on 152 occasions, and it has been verified on 77 other occasions.The skill scores obtained show that the use of statistical models combining the data, provided by variables characterizing the preconvective conditions and the triggering mechanisms, represent an important step in the difficult task of short-term thunderstorm forecasting.     

A short-term forecast model for hail

Predicting the occurrence of hailstorms is one of the most complicated tasks in weather forecasting because of the small area of land that is usually affected, and because of the short time hail events last. Today there are a number of parameters available that may be used to characterize preconvective conditions and predict the beginning of convection. However, forecast models based on stability indices should be developed separately for each geographic area.The databases available were used in this study with two aims in mind: determining which meteorological variables or indices obtained from a radiosonde in the study zone are more relevant in characterizing preconvective conditions; and, secondly, setting up an objective short-term forecast model for storms on the basis of one or more meteorological parameters.The logistic regression was used to establish the dichotomy risk/no risk of storms. A function was developed combining seven meteorological variables. The results show that the forecast model has a Probability of Detection of 0.87 and a False Alarm Ratio of 0.18.     

Early Paleozoic Structural and Metamorphic Evolution of Western Sierra de San Luis (Argentina), in Relation to Cuyania Accretion

Structural, metamorphic and isotopic data obtained from the Nogoli Metamorphic Complex of western Sierra de San Luis indicate that the Early Paleozoic Famatinian Orogeny overprinted an already structured and metamorphosed older basement. The older geological features are relict NW trending fabric associated with high-grade (amphibolite facies) regional metamorphism preserved within thin strips of schists and paragneisses and in the core of mafic to ultramafic lenses. Arc magmatism, medium P (Barrovian type)/high T (amphibolite to granulite facies) regional metamorphism and penetrative NNE to NE trending foliation are related to the building of the Famatinian orogenic belt. The P-T conditions of the Famatinian prograde metamorphism reached a pressure peak of ca. 8 kb, with a thermal peak from -750°C up to -820°C. U-Pb conventional and chemical dating and Ar-Ar plateau ages constrain the peak of the main orogenic phase related to the Famatinian belt to 470–457 Ma (Early to Mid-Ordovician). Greenschist facies retrograde metamorphism closely associated with shear zones and secondary Ar-Ar plateau and Sm-Nd ages suggest that a late to post-orogenic phase of the Famatinian belt was active at least since -445 Ma. This phase continued during the Silurian to Late Devonian times through multiple reactivation of early shear zones. The Famatinian Orogeny reset a previous thermal history and therefore, the timing of the relict fabric could not be constrained conclusively with radiometric dates. Despite this difficulty, a range of 520 to 490 Ma suggests some inheritance from Pampean events registered by the older NW-SE fabric. The Early to Mid-Ordovician regional metamorphism and ductile deformation of the western Sierra de San Luis is interpreted as the orogenic effects of the collision of the allochthonous Cuyania terrane with the autochthonous proto-Pacific margin of Gondwana during the Famatinian Orogeny.     

Tracking sediment provenance and erosional evolution of the western Greater Caucasus

This article investigates landscape characteristics and sediment composition in the western Greater Caucasus by using multiple methods at different timescales. Our ultimate goal is to compare short‐term versus long‐term trends in erosional processes and to reconstruct spatio‐temporal changes in sediment fluxes as controlled by partitioning of crustal shortening and rock uplift in the orogenic belt. Areas of active recent uplift are assessed by quantitative geomorphological techniques [digital elevation model (DEM) analysis of stream profiles and their deviation from equilibrium] and compared with regions of rapid exhumation over longer time intervals as previously determined by fission‐track and cosmogenic‐nuclide analyses. Complementary information from petrographic and heavy‐mineral analyses of modern sands and ancient sandstones is used to evaluate erosion integrated throughout the history of the orogen. River catchments displaying the highest relief, as shown by channel‐steepness indices, correspond with the areas of most rapid exhumation as outlined by thermochronological data. The region of high stream gradients is spatially associated with the highest topography around Mount Elbrus, where sedimentary cover strata have long been completely eroded and river sediments display the highest metamorphic indices and generally high heavy‐mineral concentrations. This study reinforces the suggestion that the bedrock–channel network can reveal much of the evolution of tectonically active landscapes, and implies that the controls on channel gradient ultimately dictate the topography and the relief along the Greater Caucasus. Our integrated datasets, obtained during a decade of continuing research, display a general agreement and regularity of erosion patterns through time, and consistently indicate westward decreasing rates of erosional unroofing from the central part of the range to the Black Sea. Copyright © 2014 John Wiley & Sons, Ltd.     

Assessing the performance of a foraminifera-based transfer function to estimate sea-level changes in northern Portugal

We assessed the performance of a transfer function model for sea-level studies using salt-marsh foraminifera from two estuaries of northern Portugal. An independent data set of 12 samples and 13 sub-fossil samples from a core were used to evaluate if reconstructions and errors derived from current models are adequate. Initial transfer function models provided very strong results as indicated by cross-validation (component 2; r² = 0.80-0.82; RMSEP ranged from 10.7 to 12.3 cm) and improved its performance by ca. 10% when sample size reached ca. 50. Results derived using an independent test data set indicate that cross-validation is a very effective approach and produces conservative errors when compared to observed errors. We additionally explored the possible effect of transforming the concentration data into percent in the error estimations by comparing the results obtained based on the use of both concentration and compositional data. Results indicate that this type of transformation does not affect the performance of the transfer function. Results derived from a reconstruction of sub-fossil samples from a core indicate that high-resolution sea-level reconstructions are possible, but show that depositional environments have to be selected carefully in order to minimize the impact of possible taphonomical loss.     

Magmatism and fenitization in the Cretaceous potassium-alkaline-carbonatitic complex of Ipanema S?o Paulo State, Brazil

The Ipanema alkaline-carbonatitic complex is part of the Meso-Cenozoic alkaline magmatism located within the southeastern part of the Brazilian Platform. Drill-core and field sampling have indicated the occurrence of glimmerites, with subordinate shonkinites (mela-syenites), clinopyroxene-bearing glimmerites, diorites and syenites. The glimmerites are cross-cut by lamprophyric dykes and calciocarbonatites. Fenitization has deeply affected the country rocks, originating dioritic and syenitic rocks. The Ipanema rocks show a distinct potassic affinity. The initial Sr-Nd- isotopic composition of the Ipanema rocks (⁸⁷Sr/⁸⁶Sr?=?0.70661–0.70754 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51169–0.51181) is similar to that of tholeiitic and potassium-rich-alkaline rocks of the Eastern Paraguay. Stable isotope data for the Ipanema calciocarbonatite suggest interaction with fluids at temperatures typical of hydrothermal stages, as hypothesized for other carbonatite complexes from southeastern Brazil. The chemical differences between the lamprophyre, glimmerites, carbonatites, apatitites and magnetitites, and the absence of marked REE enrichment in the evolved lithologies, all indicate that fractional crystallization and accumulus of liquidus phases in a magma reservoir, likely coupled with liquid immiscibility processes, may have played an important role in the genesis of the Ipanema rocks.     

The ichthyofauna and abiotic hydrological environment of the Ria de Aveiro,Portugal

The abiotic hydrological environment and the community dynamics of the fish fauna were investigated in the Ria de Aveiro, an estuarine coastal lagoon system (43 km²), which has both marine and fluvial influences. Abiotic hydrological and fish community parameters were recorded routinely during 12 months at ten stations. Temperature ranged between 9.5°C and 26.0°C, salinity between 0.0‰ and 32.0‰, dissolved oxygen between 0.8 mg 1^?1 and 15.4 mg 1^?1, pH between 6.1 and 9.4, and transparency between 4.4% and 100.0%. No significant differences were observed in temperature and dissolved oxygen among stations, or in seasonal variation in transparency. Nineteen thousand thirty-one fish specimens comprising 55 species were sampled. Abundance, biomass, and species richness were highest in summer and late winter at stations near the lagoon entrance. Sedentary species were most numerous, marine migratory species had the highest biomass, and the category “occasional species” had the highest number of species. Atherinidae, Mugilidae, and Gobiidae were the most important families. Eight species represented about 80% of the total fish abundance and biomass but only six species occurred in all the months and at all the stations. It was concluded that the Ria de Aveiro, with high seasonal and spatial abiotic variation, has a very rich and representative fish community compared with temperate and tropical estuaries and estuarine coastal lagoons around the world.