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61.
GERNOT ARP CHRISTIAN OSTERTAG‐HENNING SELÇÜK YÜCEKENT JOACHIM REITNER VOLKER THIEL 《Sedimentology》2008,55(5):1227-1251
Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe2+ and Mn2+ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO3 precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO3 precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ13C in conjunction with evaporite pseudomorphs showing extremely low δ13CCarb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition. 相似文献
62.
气相色谱法测定地下水中六六六结果的不确定度评定 总被引:7,自引:4,他引:3
依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。 相似文献
63.
Correlations between heavy metals and organic carbon extracted by dry oxidation procedure in urban roadside soils 总被引:1,自引:0,他引:1
Xue Song Wang 《Environmental Geology》2008,54(2):269-273
The organic fraction in soils has a significant influence on heavy metal transport. In this study, the organic carbon content
was measured by dry oxidation procedure from 21 Xuzhou urban roadside soils to assess the relationships between the concentrations
of heavy metals (Pb, Cu, Zn, and Cr) and the amount of organic carbon. The anthropogenic heavy metals (e.g. Pb, Cu, Zn) were
strongly correlated with organic carbon (denoted by Corg−c) extracted by dry oxidation while natural heavy metal (e.g. Cr) showed no correlation to the Corg−c. The anthropogenic heavy metals were also strongly correlated with the amount of the total carbon. These results show that
the anthropogenic heavy metals are mainly enriched in the organic matter in the Xuzhou urban roadside soils. 相似文献
64.
Application of MODFLOW and geographic information system to groundwater flow simulation in North China Plain, China 总被引:2,自引:0,他引:2
Shiqin Wang Jingli Shao Xianfang Song Yongbo Zhang Zhibin Huo Xiaoyuan Zhou 《Environmental Geology》2008,55(7):1449-1462
MODFLOW is a groundwater modeling program. It can be compiled and remedied according to the practical applications. Because
of its structure and fixed data format, MODFLOW can be integrated with Geographic Information Systems (GIS) technology for
water resource management. The North China Plain (NCP), which is the politic, economic and cultural center of China, is facing
with water resources shortage and water pollution. Groundwater is the main water resource for industrial, agricultural and
domestic usage. It is necessary to evaluate the groundwater resources of the NCP as an entire aquifer system. With the development
of computer and internet information technology it is also necessary to integrate the groundwater model with the GIS technology.
Because the geological and hydrogeological data in the NCP was mainly in MAPGIS format, the powerful function of GIS of disposing
of and analyzing spatial data and computer languages such as Visual C and Visual Basic were used to define the relationship
between the original data and model data. After analyzing the geological and hydrogeological conditions of the NCP, the groundwater
flow numerical simulation modeling was constructed with MODFLOW. On the basis of GIS, a dynamic evaluation system for groundwater
resources under the internet circumstance was completed. During the process of constructing the groundwater model, a water
budget was analyzed, which showed a negative budget in the NCP. The simulation period was from 1 January 2002 to 31 December
2003. During this period, the total recharge of the groundwater system was 49,374 × 106 m3 and the total discharge was 56,530 × 106 m3 the budget deficit was −7,156 × 106 m3. In this integrated system, the original data including graphs and attribution data could be stored in the database. When
the process of evaluating and predicting groundwater flow was started, these data were transformed into files that the core
program of MODFLOW could read. The calculated water level and drawdown could be displayed and reviewed online. 相似文献
65.
Qiang Wang Derek A. Wyman Jifeng Xu Yusheng Wan Chaofeng Li Feng Zi Ziqi Jiang Huaning Qiu Zhuyin Chu Zhenhua Zhao Yanhui Dong 《Contributions to Mineralogy and Petrology》2008,155(4):473-490
New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched
basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized
by high Sr/Y (25–45), La/Yb (14–42) and Na2O/K2O (12–49) ratios, high Al2O3 (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and εND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments
of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive εND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle
normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids.
A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite.
The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series”
recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and
southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates
that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane. 相似文献
66.
67.
Numerical estimation of REV and permeability tensor for fractured rock masses by composite element method 总被引:2,自引:0,他引:2
The Monte Carlo method is used to generate parent stochastic discrete fracture network, from which a series of fractured rock samples of different sizes and orientations are extracted. The fracture network combined with a regular grid forms composite element mesh of the fractured rock sample, in which each composite element is composed of sub‐elements incised by fracture segments. The composite element method (CEM) for the seepage is implemented to obtain the nodal hydraulic potential as well as the seepage flow rates through the fractured rock samples. The application of CEM enables a large quantity of stochastic tests for the fractured rock samples because the pre‐process is facilitated greatly. By changing the sizes and orientations of the samples, the analysis of the seepage characteristics is realized to evaluate the variation of the permeability components, the existence of the permeability tensor and the representative element volume. The feasibility and effectiveness are illustrated in a numerical example. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
68.
Biaxial test simulations using a packing of polygonal particles 总被引:1,自引:0,他引:1
The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
69.
We test the hypothesis that flexural isostatic compensation of the mass removed by enhanced Quaternary erosion is responsible for uplift of the Western European Alps and their forelands. We use two well‐preserved and well‐dated (1.8 Ma) abandonment surfaces of foreland basin remnants in SE France (the Chambaran and Valensole plateaux) as passive benchmarks for tilting of the foreland. Estimating their initial slope from morphometric scaling relationships, we determine bulk post‐depositional tilting of 0.5–0.8% for these surfaces. The calculated isostatic response of the Alpine lithosphere to erosional unloading, using the method recently proposed by Champagnac et al. [Geology 35 (2007) 195–198] , yields a predicted tilting of 0.3–0.4% in the considered areas, explaining approximately half of the determined post‐depositional tilting. Such long‐term deformation being insensitive to cyclic loading/unloading because of glaciations, we suspect the other half to be related to as yet undetermined long‐wavelength and long‐lived tectonic process(es). 相似文献
70.
A U–Pb sensitive high‐resolution ion microprobe (SHRIMP) age of 654.5 ± 3.8 Ma from an ash bed immediately below the Nantuo Formation in South China provides the lowest age constraint for the Nantuo glaciation, which has been correlated with the global ‘Marinoan’ glaciation. A U–Pb SHRIMP age of 636.3 ± 4.9 Ma from a fallout tuff within the basal layer of the Nantuo Formation, along with the existing age of 635.2 ± 0.6 Ma from its overlying Doushantuo cap carbonate, suggests that the traditionally defined Nantuo Formation may have been deposited in a short time period at the end of the Nantuo glaciation. In combination with available ages globally, the data support a relatively short duration and rapid termination of ‘Marinoan’ glaciations. 相似文献