单道扫描电感耦合等离子体发射光谱法测定地质样品中的微量稀土元素

采用Na_2O_2熔融矿样,水提取,加三乙醇胺、EGTA做掩蔽剂。经氢型阳离子交换树脂交换分离富集稀土元素,由于选择了合适的仪器条件及测定波长,有效地消除了电感耦合等离子体发射光谱法(ICP-AES)测定过程中的基体干扰和光谱干扰。应用于地质样品中的稀土元素分析,获得了满意的准确度、精密度及检出限。     

惠民凹陷南坡石炭二叠系煤层二次生气模式

利用开放体系程序升温热模拟实验方法,对惠民凹陷南坡石炭—二叠系煤岩样品的热演化规律进行了研究,建立了该区石炭二叠系含煤地层有机质的生气模式,探讨了影响二次生气潜力的各种主控因素,为准确评价其资源潜力和计算远景资源量奠定了基础,对渤海湾盆地其他类似地区煤型气勘探具有指导意义。      

异常压力与油气分布

随着油气勘探活动的不断加深，国内外相继发现了许多异常高压油气田。据不完全统计，全世界已发现超压盆地１８０多个，其中１６０多个为富含油气盆地。异常高压油气田约占全球油气田３０％左右，因此，对异常压力的研究，具有举足轻重的意义。本文介绍了异常地层压力的概念、特征及分类；详细论述了异常压力的成因，即烃类生成作用、欠压实作用、液态烃类的裂解作用、粘土矿物的后生成岩作用、构造作用、温度变化等；系统阐述了世界典型含油气盆地的超压形成机制、超压体系中油气初次运移机理以及超压与油气分布关系；并在此基础上，归纳总结出了五种超压油气藏成藏模式，即：（１）位于超压体系中的低渗超压油气藏；（２）位于超压层系中，以礁灰岩（或浊积砂岩）为储层的高压油气藏；（３）位于超压带上倾方向，以退覆三角洲平原和分流河道砂岩为储层的常压或过渡带超压油气藏；（４）位于超压带上、下部的超压油气藏；（５）位于远离超压体系的泄压区常压油气藏，本文对指导、加深新老油气区勘探具有实际应用价值。     

黔中开阳磷矿沉积区震旦纪陡山沱期定量岩相古地理重建*

磷矿的沉积和成矿与成磷期的古地理环境密切相关。本文首次将“单因素分析多因素综合作图法”运用于开阳地区震旦纪陡山沱期沉积型磷矿床的成矿分析和找矿预测上。通过选取陡山沱组及其各岩性段的地层厚度及磷矿层品位作为单因素,确定开阳地区古地理格局;结合地层岩性组合、沉积特征等多因素综合分析,恢复开阳地区成矿期沉积环境,编制陡山沱早期、中期和晚期岩相古地理图。根据定量岩相古地理重建结果,认为开阳地区陡山沱期整体处于南靠黔中古陆、地势南高北低、局部地形复杂的滨岸海滩沉积环境,其中临滨带为最有利成矿带,局部地形变化也会造成矿层厚度、品位的差异;矿层受到的水流冲蚀、暴露、淋滤及再沉积作用是导致矿石品位显著提升的关键因素。通过定量岩相古地理学精确还原成矿期古地理环境、解析多期次沉积成矿过程,对于确定磷矿控矿因素、构建找矿预测模型和预测矿体空间位置具有重要意义。     

Major element geochemistry of purple soils/rocks in the red Sichuan Basin, China: implications of their diagenesis and pedogenesis

Major element compositions and chemical weathering features of the purple soils and their corresponding rocks in the Red Sichuan Basin, China were studied in this paper to infer the diagenetic features of the purple rocks and the pedogenetic features of the purple soils. The results showed that all of the rock and soil samples, except those from Yibin, have strongly similar major element compositions and the distribution patterns of their major element compositions are similar to those of the upper continental crust. Chemical index of alteration, chemical index of weathering and Na₂O/K₂O indicate that the purple soils and rocks have similar chemical weathering intensities, whereas the Al₂O₃–CaO* + Na₂O–K₂O (A–CN–K) relationship, suggests that chemical weathering was strong during diagenesis of the purple rocks, but weak during pedogenesis of the purple soils. Variations in major element compositions of the purplish rock samples, except that from Yibin, do not primarily reflect differences in compositions of the sediment source, sediment recycling and potassium metasomatism, and therefore the effects of chemical weathering on the major element compositions were mainly dependent on climate condition and the residence time of material exposed to chemical weathering. Chemical weathering of the purple rocks reached only moderate degrees under the general influence of warm and humid climate during Jurassic and Cretaceous. Warmer and more humid climate conditions partly resulted in stronger chemical weathering of rocks in the southern region of the basin than in the central and western region, whereas shorter residence time of material in upslope position partly resulted in weaker chemical weathering of rocks in the eastern region than in the central and western region. The same climate and stable tectonic setting led to comparable chemical weathering intensities of rocks in the Ziliujing and Jiaguan Formations. Gradually colder and dryer climate from Early Jurassic to Middle Jurassic then to Late Jurassic and shorter residence time in tectonically active setting of Middle Jurassic and late Late Jurassic resulted in the following order of chemical weathering intensity of the purple Jurassic rocks: Ziliujing Formation ? Shaximiao Formation ≈ Suining Formation > Penglaizhen Formation.     

刚果(金)地质特征与主要矿产资源概况

刚果(金)主要由刚果盆地和环盆地高原组成,盆地主要由中生代到新生代地层及近现代沉积物组成,沿着盆地内边缘分布有泛非时期的火山沉积物,环盆地高原主要为抬升的前寒武纪基底。刚果(金)优势金属矿产资源主要分布环盆地高原的加丹加新元古代铜-钴多金属成矿带、KIB-KAB中元古代锡-铌-钽-钨多金属成矿带、刚果东北太古代绿岩带型金-铁多金属成矿带上,而金刚石则主要分布开赛及东北部地区中新生代金刚石成矿区内。     

珠江口盆地珠一坳陷古近系“源-汇”系统分类及石油地质意义

珠一坳陷深层古近系两套优质生烃层系内发育的储层具有近源成藏的优势,但其非均质性强、低孔渗的特点制约了油气勘探,研究与此直接相关的“源-汇”系统,对于寻找富烃优储耦合的有利区意义重大.以构造运动和盆山地貌为基础,结合断陷湖盆以半地堑为基本单元的结构特点,划分了盆地级、半地堑级和区带级的三级“源-汇”系统.盆地级分为外源、内源型两类,可用来宏观分析优质烃源岩分布;半地堑级分为陡坡、缓坡和长轴型3类,对于定性评价储层优劣具有较大意义;区带级分为迁移型、转换型、稳定型3类,为有利区目标评价和井点选择提供参考.研究认为迁移型和转换型“源-汇”系统可形成良好的生储盖配置,是最为有利的油气富集区,应作为古近系重点勘探对象.      

博格达山晚石炭纪造山活动的变形地质记录

主要由钙碱性火山岩、火山碎屑岩组成的博格达古岛弧是天山缝合造山带的重要组成部分 ,是一个发育较成熟的山链 ,其演化经历了晚古生代的韧性剪切收缩 ;中生代伸展调整及新生代再造山过程。晚古生代的造山活动在博格达山有很好的地质记录 ,并以显著的韧性剪切变形带的形成和发育同造山的褶皱构造为特点。剪切变形带内同构造的石英脉中的锆石U PbSHRIMP测年结果与山链中花岗岩、辉长岩年龄颇为一致 (311～ 316Ma) ,这个年龄反映在结束洋盆散聚、碰撞焊接的晚华力西期造山过程中 ,博格达古岛弧内存在一次虽不甚强烈 ,但又较为明显的构造岩浆事件 ,其成因可能与引起石炭纪大规模裂陆式喷发的深部断裂构造重新活动有关。     

叠前时间偏移方法在煤田勘探中的应用

根据克希霍夫积分法的原理,介绍了叠前时间偏移的方法特点,实现过程,以及对地震资料的要求,依托国家重大产业技术专项“西部煤炭资源高精度三维地震勘探”工程,对“青海省鱼卡煤田四井田高精度三维地震勘探”资料进行叠前时间偏移,结果表明其能较好地解决成像质量差、能量聚焦不明显、绕射波收敛不理想等方面的难题。通过与叠后时间偏移对比,对于大倾角地层、断块小且多的破碎带、陡倾角不对称向斜等地质问题,其叠前时间偏移剖面成像质量都有明显的提高,反映的构造关系更加清晰,同相轴连续性增强。总结该方法在多个矿区的推广经验．认为合理的观测系统、较高的资料信噪比,准确的测量资料及较高的中表层速度调查精度是做好叠前时间偏移的前提。     

Re–Os and U–Pb Geochronology of Porphyry and Skarn Types Copper Deposits in Jilin Province,NE China

Jilin Province in NE China lies on the eastern edge of the Xing–Meng Orogenic Belt. Mineral exploration in this area has resulted in the discovery of numerous large, medium, and small sized Cu, Mo, Au, and Co deposits. To better understand the formation and distribution of both the porphyry and skarn types Cu deposits of the region, we examined the geological characteristics of the deposits and applied zircon U–Pb and molybdenite Re–Os isotope dating to constrain the age of the mineralization. The Binghugou Cu deposit yields a zircon U–Pb age for quartz diorite of 128.1 ± 1.6 Ma; the Chang'anpu Cu deposit yields a zircon U–Pb age for granite porphyry of 117.0 ± 1.4 Ma; the Ermi Cu deposit yields a zircon U–Pb age for granite porphyry of 96.8 ± 1.1 Ma; the Tongshan Cu deposit yields molybdenite Re–Os model ages of 128.7 to 130.2 Ma, an isochron age of 129.0 ± 1.6 Ma, and a weighted mean model age of 129.2 ± 0.7 Ma; and the Tianhexing Cu deposit yields molybdenite Re–Os model ages of 113.9 to 115.2 Ma, an isochron age of 114.7 ± 1.2 Ma, and a weighted mean model age of 114.7 ± 0.7 Ma. The new ages, combined with existing geochronology data, show that intense porphyry and skarn types Cu mineralization was coeval with Cretaceous magmatism. The geotectonic processes responsible for the genesis of the Cu mineralization were probably related to lithospheric thinning. By analyzing the accumulated molybdenite Re–Os, zircon U–Pb, and Ar–Ar ages for NE China, it is concluded that the Cu deposits formed during multiple events coinciding with periods of magmatic activity. We have identified five phases of mineralization: early Paleozoic (~476 Ma), late Paleozoic (286.5–273.6 Ma), early Mesozoic (~228.7 Ma), Jurassic (194.8–137.1 Ma), and Cretaceous (131.2–96.8 Ma). Although Cu deposits formed during each phase, most of the Cu mineralization occurred during the Cretaceous.