Mineral inclusions and geochemical characteristics of microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, Canada

A mineral inclusion, carbon isotope, nitrogen content, nitrogen aggregation state and morphological study of 576 microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, was conducted. Mineral inclusion data show the diamonds are largely eclogitic (64%), followed by peridotitic (25%) and ultradeep (11%). The paragenetic abundances are similar to macrodiamonds from the DO27 kimberlite (Davies, R.M., Griffin, W.L., O'Reilly, S.Y., 1999. Diamonds from the deep: pipe DO27, Slave craton, Canada. In: Gurney, J.J., Gurney, J.L., Pascoe, M.D., Richardson, S.H. (Eds.), The J. B. Dawson Vol., Proc. 7th Internat. Kimberlite Conf., Red Roof Designs, Cape Town, pp. 148–155) but differ to diamonds from nearby kimberlites at Ekati (e.g., Lithos (2004); Tappert, R., Stachel, T., Harris, J.W., Brey, G.P., 2004. Mineral Inclusions in Diamonds from the Panda Kimberlite, S. P., Canada. 8th International Kimberlite Conference, extended abstracts) and Snap Lake to the south (Dokl. Earth Sci. 380 (7) (2001) 806), that are dominated by peridotitic stones.

Eclogitic diamonds with variable inclusion compositions and temperatures of formation (1040–1300 °C) crystallised at variable lithospheric depths sometimes in changing chemical environments. A large range to very ¹³C-depleted C-isotope compositions (δ¹³C=−35.8‰ to −2.2‰) and an NMORB bulk composition, calculated from trace elements in garnet and clinopyroxene inclusions, are consistent with an origin from subducted oceanic crust and sediments. Carbon isotopes in the peridotitic diamonds have mantle compositions (δ¹³C mode −4.0‰). Mineral inclusion compositions are largely harzburgitic. Variable temperatures of formation (garnet T_Ni=800–1300 °C) suggest the peridotitic diamonds originate from the shallow ultra-depleted and deeper less depleted layers of the central Slave lithosphere. Carbon isotopes (δ¹³C av.=−5.1‰) and mineral inclusions in the ultradeep diamonds suggest they formed in peridotitic mantle (670 km). The diamonds may have been entrained in a plume and subcreted to the base of the central Slave lithosphere.

Poorly aggregated nitrogen (IaA without platelets) in a large number of eclogitic (67%) and peridotitic (32%) diamonds, with similar nitrogen contents, indicates the diamonds were stored in the mantle at low temperatures (1060–<1100 °C) following crystallisation in the Archean. Type IaA diamonds have largely cubo-octahedral growth forms, and Type II and Type IaAB diamonds, with higher nitrogen aggregation states, mostly have octahedral morphologies. However, no correlation between these groups and their mineral inclusion compositions, C-isotopes, and N-contents rules out the possibility of unique source origins and suggests eclogitic and peridotitic diamonds experienced variable mantle thermal states. Variation in mineral inclusion chemistries in single diamonds, possible overgrowths of ¹³C-depleted eclogitic diamond on diamonds with peridotitic and ultradeep inclusions, and Type I ultradeep diamond with low N-aggregation is consistent with diamond growth over time in changing chemical environments.     

Soft X-ray spectroscopic studies of the reaction of fractured pyrite surfaces with Cr(VI)-containing aqueous solutions

We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation.     

Exploring effects of climate change on Northern Plains American Indian health

American Indians have unique vulnerabilities to the impacts of climate change because of the links among ecosystems, cultural practices, and public health, but also as a result of limited resources available to address infrastructure needs. On the Crow Reservation in south-central Montana, a Northern Plains American Indian Reservation, there are community concerns about the consequences of climate change impacts for community health and local ecosystems. Observations made by Tribal Elders about decreasing annual snowfall and milder winter temperatures over the 20th century initiated an investigation of local climate and hydrologic data by the Tribal College. The resulting analysis of meteorological data confirmed the decline in annual snowfall and an increase in frost free days. In addition, the data show a shift in precipitation from winter to early spring. The number of days exceeding 90 ?F (32 ?C) has doubled in the past century. Streamflow data show a long-term trend of declining discharge. Elders noted that the changes are affecting fish distribution within local streams and plant species which provide subsistence foods. Concerns about warmer summer temperatures also include heat exposure during outdoor ceremonies that involve days of fasting without food or water. Additional community concerns about the effects of climate change include increasing flood frequency and fire severity, as well as declining water quality. The authors call for local research to understand and document current effects and project future impacts as a basis for planning adaptive strategies.     

The coalescence and organization of lahars at Semeru volcano, Indonesia

We present multi-parameter geophysical measurements of rainfall-induced lahars at Semeru Volcano, East Java, using two observation sites 510 m apart, 11.5 km from the summit. Our study site in the Curah Lengkong channel is composed of a 30-m wide box-valley, with a base of gravel and lava bedrock, representing an ideal geometry for high density measurements of active lahars. Instrumentation included pore-pressure sensors (stage), a broad-band seismograph (arrival times, vibrational energy, and turbulence), video footage, and direct bucket sampling. A total of 8 rainfall-induced lahars were recorded, with durations of 1–3 h, heights 0.5–2 m, and peak velocities 3–6 m/s. Flow types ranged from dilute to dense hyperconcentrated flows. These recorded flows were commonly composed of partly coalesced, discrete and unsteady gravity current packets, represented by multiple peaks within each lahar. These packets most likely originate from multiple lahar sources, and can be traced between instrument sites. Those with the highest concentrations and greatest wetted areas were often located mid-lahar at our measured reach, accelerating towards the flow front. As these lahars travel downstream, the individual packets thus coalesce and the flow develops a more organised structure. Observations of different degrees of coalescence between these discrete flow packets illustrate that a single mature debris flow may have formed from multiple dynamically independent lahars, each with different origins.     

Inversion of arrival-times in a region of dilatancy anisotropy

Shear-wave splitting has been identified in many three-component seismograms from two separate field experiments on a section of the North Anatolian Fault in North-West Turkey. These observations are consistent with shear-wave propagation through a zone of extensive-dilitancy anisotropy. A preliminary attempt has been made to confirm this interpretation by simultaneously inverting suites of arrival-times for hypocentral locations and for parameters describing an anisotropic halfspace. Although the inversion procedure is not globally convergent, it is possible to recognize the true solution by systematically varying the initial conditions. Applied to selected data sets, the inversion defines several anisotropic models that fit the data significantly better than a simple isotropic model, and display the anisotropy required by the shear-wave splitting. However, most of these anisotropic models are not superior when they are used to individually locate events in a much larger data set. However, for each experiment, there is a single model that produces clearly superior locations for the larger data sets than those of other anisotropic or simple isotropic models. Both models display similar velocity variations which are characteristic of propagation through distributions of biplanar cracks displaying orthorhombic symmetry. The principal axes of the two models are oriented in similar directions and are within 20° of the principal axis of regional stress derived from fault-plane solutions. The solutions indicate low velocities close to the tensional axis, as would be expected in extensive-dilatancy anisotropy.     

Military geology and the Battle of Gettysburg, July 1863

Gettysburg – the most costly of all battles of the American Civil War, and one of the most significant battles ever fought. Contested in rural Pennsylvania, the Battle of Gettysburg took place after a chance encounter by the Confederate Army of Northern Virginia (General Robert E. Lee) with the Union Army of the Potomac (Major-General George Meade). It was to prove the turning point in the war, the so-called 'high tide' of the Confederacy, as after Gettysburg the fortunes of war turned in favour of the Union. Fought over three days in early July 1863, the battle continues to be analyzed and re-analyzed from all perspectives. Significantly, it was the first battle to be re-interpreted from the perspective of its geology, by Andrew Brown of the Pennsylvania State Survey in the early 1960s. It continues to fascinate geologists interested in the overall impact of geology and terrain in determining the outcome of battle. This article examines why Gettysburg has been so influential in shaping our understanding of geology in warfare.     

A comparison of theoretical Sv emission line strengths with extreme ultraviolet observations of a sunspot

Electron impact excitation rates for transitions in the S v ion, calculated with theR-matrix code, are used to derive the electron temperature sensitive emission line ratiosR ₁ =I(854.8 Å)/I(786.9 Å),R ₂ =I(852.2 Å)/I(786.9 Å),R ₃ =I(849.2 Å)/I(786.9 Å), andR ₄ =I(1199.1 Å)/I(786.9 Å), which are found to be significantly different from previous estimates. A comparison of the present results with observational data for a sunspot obtained with the Harvard S-055 spectrometer on boardSkylab reveals generally good agreement between theory and experiment, except in the case ofR ₁, which is probably due to blending in the 854.8 Å feature. The possible effects of Lyman continuum absorption on the observed line ratios is briefly discussed.     

Speculation on martian north polar wind circulation and the resultant orientations of polar sand dunes

Dunes in the Martian north polar erg show two dominant orientations. When seen at frost cap minimum, dunes north of 80°N record east winds, dunes south of 80°N record west winds. Many of the transverse dunes are considered to be reversing dunes. Dunes in two fields may have reversed at least once during the lifetime of the Viking Orbiters. Poor agreement exists among published predictive models of north polar winds and the interpretations derived from the major published map of the north polar dunes. We propose that the average polar winds are: (1) strong, off-pole northwest winds in fall; (2) moderate west winds in winter; (3) latitude-dependent weak to strong off-pole northeast winds in spring; and (4) weak west winds in summer. Viking images of near-polar clouds confirm much of the hypothesis. Images discussed in other studies can be given alternative interpretations that support this hypothesis also. Over millenia, the combination of reversing west and east winds could produce the binodal distributions of dune orientations observed at the north pole.