Models of the wave boundary layer

A general approach to model the structure of the wave boundary layer, based on the nonlinear Reynolds equations in a curvilinear system of coordinates, is described. Both spectral and numerical grid models are used. The energetic interactions between wind and wave in terms of Miles' parameter are studied. For waves outrunning or running against the wind, the range of the inverse flux of energy is found. For waves running slower than the wind, quadratic growth of is established. Vertical profiles of the wave momentum flux for different fetches are given. Following P. Janssen, a one-dimensional analytical model of the wave boundary layer is suggested. The effect of waves on the drag coefficient is analyzed.     

Spectroscopic constraints on growth of Siberian mixed-habit diamonds

Notable within-crystal variability of mineralogical and geochemical properties of single natural diamonds are commonly attributed to changing chemistry of parental fluids, sources of carbon and redox conditions of diamond precipitation. A distinct type of compositional heterogeneity (mixed-habit structure) is well-known to occur in diamonds as well as in many other minerals due to purely “structural” reasons that are unequal crystal chemistry of crystallographically different faces and selective absorption and fractionation of impurities between adjacent growth pyramids. Based on the combined cathodoluminescence, Fourier-transformed infrared spectroscopy and photoluminescence spectroscopy, study of nine diamond crystals with different growth histories and external morphology, but all showing mixed-habit patterns at different growth stages, we show that mixed-diamonds may grow in closed system conditions or with a slowly decreasing growth rate from a media with a much lower impurity content than previously thought. Intracrystal nitrogen distribution seems to be a function of growth rate even in the cases of unusual impurity partitioning between growth sectors. Generally poor with IR-active hydrogen at moderate nitrogen aggregation parameters, studied diamonds likely resemble the low hydrogen content from the growth medium that, for cubic diamonds, was typically suggested hydrogen-rich and a crucial factor for growth of cubic and mixed-habit diamonds. We also show that mixed-habit diamond growth may occur not only in peridotitic suite but also in an extended field of geochemical affinities from high-Ni to low-Ni or maybe even Ni-free environments, such as pyroxenitic or eclogitic.     

Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.     

Observations of atmospheric water vapor above the Tharsis volcanoes on Mars with the OMEGA/MEx imaging spectrometer

The OMEGA imaging spectrometer onboard the Mars Express spacecraft is particularly well suited to study in detail specific regions of Mars, thanks to its high spatial resolution and its high signal-to-noise ratio. We investigate the behavior of atmospheric water vapor over the four big volcanoes located on the Tharsis plateau (Olympus, Ascraeus, Pavonis and Arsia Mons) using the 2.6 μm band, which is the strongest and most sensitive H₂O band in the OMEGA spectral range. Our data sample covers the end of MY26 and the whole MY27, with gaps only in the late northern spring and in northern autumn. The most striking result of our retrievals is the increase of water vapor mixing ratio from the valley to the summit of volcanoes. Corresponding column density is often almost constant, despite a factor of ∼5 decrease in air mass from the bottom to the top. This peculiar water enrichment on the volcanoes is present in 75% of the orbits in our sample. The seasonal distribution of such enrichment hints at a seasonal dependence, with a minimum during the northern summer and a maximum around the northern spring equinox. The enrichment possibly also has a diurnal trend, being the orbits with a high degree of enrichment concentrated in the early morning. However, the season and the solar time of the observations, due to the motion of the spacecraft, are correlated, then the two dependences cannot be clearly disentangled. Several orbits exhibit also spatially localized enrichment structures, usually ring- or crescent-shaped. We retrieve also the height of the saturation level over the volcanoes. The results show a strong minimum around the aphelion season, due to the low temperatures, while it raises quickly before and after this period. The enrichment is possibly generated by the local circulation characteristic of the volcano region, which can transport upslope significant quantities of water vapor. The low altitude of the saturation level during the early summer can then hinder the transport of water during this season. The influence of the coupling between atmosphere and surface, due mainly to the action of the regoliths, can also contribute partially to the observed phenomenon.     

Interaction of surface waves at very close wavenumbers

We show that interaction of two monochromatic waves at the water surface enters a different dynamic regime if their wavenumbers become very close. The study is conducted by means of a fully nonlinear wave model. In the course of evolution of the two waves, downshifting of the initial wave energy and growth of the first mode occur depending on wave steepness and dk/k. Behaviour of these features changes if dk/k?<?0.0025: both downshifting and growth rate become independent of dk/k, accompanied by rapid transfer of wave energy to large scales.     

Numerical modeling of 3D fully nonlinear potential periodic waves

A simple and exact numerical scheme for long-term simulations of 3D potential fully nonlinear periodic gravity waves is suggested. The scheme is based on the surface-following nonorthogonal curvilinear coordinate system. Velocity potential is represented as a sum of analytical and nonlinear components. The Poisson equation for the nonlinear component of velocity potential is solved iteratively. Fourier transform method, the second-order accuracy approximation of vertical derivatives on a stretched vertical grid and the fourth-order Runge–Kutta time stepping are used. The scheme is validated by simulation of steep Stokes waves. A one-processor version of the model for PC allows us to simulate evolution of a wave field with thousands degrees of freedom for hundreds of wave periods. The scheme is designed for investigation of nonlinear 2D surface waves, generation of extreme waves, and direct calculations of nonlinear interactions.     

Features of the long-term transformation of the Krasnodar reservoir,near the mouth of the Kuban River,Russia

The article considers the long-term(1941–2018) transformation of the Krasnodar valley reservoir, the largest in the North Caucasus. The main functions of the Krasnodar reservoir are irrigation of rice systems and flood protection of land in the Krasnodar reservoir region and the Republic of Adygea. According to topographic maps, Landsat satellite images(1974–2018) and field observations(2016–2018), four stages of transformation of the floodplain reservoir are identified. The selected stages are characterized by both natural causes(the transformation of the filling deltas into the extended deltas, etc.) and man-made causes(runoff diversions in the delta areas, etc.). The key factor of transformation is the formation of deltas of rivers flowing into the reservoir. Each of the selected stages, against the background of a gradual reduction in the area and volume of the reservoir, is characterized by the peculiarities of the formation of river deltas with the formation of genetically homogeneous sections of delta regions. During the period of operation of the reservoir, the delta of the main Kuban River moved up to 32.4 km and took away an area of 35.4 km~2 of the reservoir. During the formation of the deltas of the Kuban and Belaya rivers, a bridge was formed on the Krasnodar reservoir. The evolution of the delta regions led to the division of the reservoir into two autonomous reservoirs. The total area of the delta regions was 85.9 km~2 by 2018, i.e., 21% of the initial area of the reservoir. The transformation of the Krasnodar reservoir leads to a decrease in its regulated volume and gradual degradation.     

Post-glacial diatom and geochemical records of ecological status and water level changes of Lake Vorota,Western Beringia

Journal of Paleolimnology - In this study, radiocarbon-dated geochemical and diatom records from Lake Vorota located within the informal meteorological ‘pole of cold’ of the northern...     

Late Glacial and Holocene Palaeoenvironmental Changes in the Rostov-Yaroslavl’ Area, West Central Russia

Three lake sediment sequences (lakes Nero, Chashnitsy, Zaozer’e) from the Rostov-Jaroslavl’ region north of Moscow were studied to provide information on palaeoclimatic and palaeoenvironmental changes during the past 15,000 cal yr. The multi-proxy study (i.e., pollen, macrofossils, mineral magnetic measurements, total carbon, nitrogen and sulphur) is chronologically constrained by AMS ¹⁴C measurements. Lake Nero provided the longest sedimentary record back to ca. 15,000 cal yr BP, while sediment accumulation began around ca. 11,000 cal yr BP in the two other lakes, possibly due to melting of permafrost. Limnic plant macrofossil remains suggest increased lake productivity and higher mean summer temperatures after 14,500 cal yr BP. While the late glacial vegetation was dominated by Betula and Salix shrubs and various herbs, it appears that Betula sect. Albae became established as early as 14,000 cal yr BP. Major hydrological changes in the region led to distinctly lower lake levels, starting 13,000 cal yr BP in Lake Nero and ca. 9000 cal yr BP in lakes Chashnitsy and Zaozer’e, which are situated at higher elevations. These changes resulted in sedimentary hiatuses in all three lakes that lasted 3500–4500 cal yr. Mixed broad-leaved – coniferous forests were widespread in the area between 8200 and 6100 cal yr BP and developed into dense, species-rich forests between 6100 and 2500 cal yr BP, during what was likely the warmest interval of the studied sequences. Agricultural activity is documented since 500 cal yr BP, but probably began earlier, since Rostov was a major capital by 862 A.D. This apparent gap may be caused by additional sedimentary hiatuses around 2500 and 500 cal yr BP.