The recovery of the old nova RS Car (1895)

Low-resolution spectra, taken at La Silla (ESO), identify the old nova RS Car (1895) as a ∼18 mag star located 7 arcsec southwest from the previous published position. This suggests a much brighter absolute magnitude of the old nova, M _v ∼5.4, than previously suspected. The spectrum reveals a continuum energy distribution typical of optically thick accretion discs and quite a high excitation state of the gas. The possible detection of the AlO λ 4843 emission band is discussed.     

Two refractory Wild 2 terminal particles from a carrot‐shaped track characterized combining MIR/FIR/Raman microspectroscopy and FE‐SEM/EDS analyses

We present the analyses results of two bulk Terminal Particles, C2112,7,171,0,0 and C2112,9,171,0,0, derived from the Jupiter‐family comet 81P/Wild 2 returned by the Stardust mission. Each particle embedded in a slab of silica aerogel was pressed in a diamond cell. This preparation, as expected, made it difficult to identify the minerals and organic materials present in these particles. This problem was overcome using a combination of three different analytical techniques, viz. FE‐SEM/EDS, IR, and Raman microspectroscopy that allowed identifying the minerals and small amounts of amorphous carbon present in both particles. TP2 and TP3 were dominated by Ca‐free and low‐Ca, Mg‐rich, Mg,Fe‐olivine. The presence of melilite in both particles is supported by IR microspectroscopy, but is not confirmed by Raman microspectroscopy, possibly because the amounts are too small to be detected. TP2 and TP3 show similar silicate mineral compositions, but Ni‐free and low‐Ni, subsulfur (Fe,Ni)S grains are present in TP2 only. TP2 contains indigenous amorphous carbon hot spots; no indigenous carbon was identified in TP3. These nonchondritic particles probably originated in a differentiated body. This work found an unanticipated carbon contamination following the FE‐SEM/EDS analyses. It is suggested that organic materials in the embedding silica aerogel are irradiated during FE‐SEM/EDS analyses creating a carbon gas that develops a strong fluorescence continuum. The combination of the selected analytical techniques can be used to characterize bulk Wild 2 particles without the need of extraction and removal of the encapsulating aerogel. This approach offers a relatively fast sample preparation procedure, but compressing the samples can cause spurious artifacts, viz. silica contamination. Because of the combination of techniques, we account for these artifacts.     

Meiofauna of the deep Eastern Mediterranean Sea: distribution and abundance in relation to bacterial biomass, organic matter composition and other environmental factors

Quantitative information on the abundance and biomass of metazoan meiofauna was obtained from samples collected at 15 deep-sea stations in the Eastern Mediterranean Sea (533–2400m). Meiofaunal abundance was compared to bacterial biomass and other environmental factors such as the total sedimentary organic matter content, the concentrations of the main biochemical classes of organic compounds (i.e. proteins, carbohydrates and lipids) and to ATP. To estimate the sedimentation potential of primary organic matter, sediment bound chloroplastic pigment equivalents (CPE) were assayed. Meiofaunal density was very low ranging from 4 ind.10cm⁻² (Station A4, 1658m depth) to 290 ind.10cm⁻² (Station A12, 636m depth). Nematodes were the numerically dominant taxon (68% of total meiofauna) and were usually confined to the top 6cm of the sediments. Total meiofaunal biomass ranged from 2.78μgC 10cm⁻² (Station A4) to 598.34μgC 10cm⁻² (Station 15A). There was a significant decrease in the density of metazoan meiofauna with water depth. Bacterial biomass largely dominated the total biomass (as the sum of bacterial and meiofaunal biomass) with an average of 73.2% and accounted for 35.8% of the living biomass (as ATP carbon) whereas meiofaunal biomass accounted only for 6.56%. Bacterial biomass was significantly related to the DNA concentrations of the sediment. A significant correlation between ATP concentration and CPE content was also found. No correlations were found between meiofauna, ATP and CPE, or between meiofauna and bacterial parameters. The significant relationship between meiofaunal density and the ratio of labile organic matter/total organic matter indicates that deep-sea meiofauna inhabiting an extremely oligotrophic environment (such as the Eastern Mediterranean) may be more nutritionally dependent upon the quality than on the quantity of sedimentary organic matter.     

A laboratory study of the initial structure and the overconsolidation effects on the undrained monotonic behavior of sandy soil from Chlef region in northern Algeria

The effects of initial state of the samples and the overconsolidation ratio (OCR) on the behavior of Chlef sand were studied in this article. For this purpose, the results of two series of undrained monotonic triaxial compression tests on medium dense sand are presented. In the first test series, the influence of the specimen's fabric and confining pressure has been studied. The tests were conducted at initial confining pressure of 50, 100, and 200 kPa. Two methods of sample preparation, which included the dry funnel pluviation and the wet deposition, were utilized. All the samples were subjected to a monotonic loading after consolidation phase. The results of the tests demonstrate that an increase in initial confining pressure leads to an increase in the resistance to liquefaction. The results also show that the samples prepared with the dry funnel pluviation method exhibit a greater resistance to liquefaction than those prepared with the wet deposition method. In the second series of tests, the overconsolidation influence on the resistance to the sand liquefaction has been realized on samples at an effective stress of 100 kPa for OCR varying between 1 and 8. The tests show that the increase of OCR improves the stiffness of sand and accelerates the appearance of dilatancy.     

A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.     

Improved initial ensemble generation coupled with ensemble square root filters and inflation to estimate uncertainty

The performance of the Ensemble Kalman Filter method (EnKF) depends on the sample size compared to the dimension of the parameters space. In real applications insufficient sampling may result in spurious correlations which reduce the accuracy of the filter with a strong underestimation of the uncertainty. Covariance localization and inflation are common solutions to these problems. The Ensemble Square Root Filters (ESRF) is also better to estimate uncertainty with respect to the EnKF. In this work we propose a method that limits the consequences of sampling errors by means of a convenient generation of the initial ensemble. This regeneration is based on a Stationary Orthogonal-Base Representation (SOBR) obtained via a singular value decomposition of a stationary covariance matrix estimated from the ensemble. The technique is tested on a 2D single phase reservoir and compared with the other common techniques. The evaluation is based on a reference solution obtained with a very large ensemble (one million members) which remove the spurious correlations. The example gives evidence that the SOBR technique is a valid alternative to reduce the effect of sampling error. In addition, when the SOBR method is applied in combination with the ESRF and inflation, it gives the best performance in terms of uncertainty estimation and oil production forecast.     

A crystal-chemical investigation of Cr substitution in muscovite by XANES spectroscopy

 This work introduces a novel procedure to fit the scattering features of XANES spectra. The procedure was applied and validated on a chromium-containing muscovite for which structural and crystal-chemical characterization is available from literature. The simulation, which involved clusters formed by up to 90 atoms, proved to be effective in representing the Cr local environment, even if the system is characterized by a very low metal content, as demonstrated by the extremely good correspondence with experimental data. Received: 23 May 2002 / Accepted: 6 November 2002