Synthesis, crystal structure and crystal chemistry of ferri-clinoholmquistite, ?Li 2Mg 3Fe 3+ 2Si 8O 22(OH) 2

This work reports the synthesis of ferri-clinoholmquistite, nominally _Li2(Mg₃Fe³⁺₂)Si₈O₂₂(OH)₂, at varying f_O2 conditions. Amphibole compositions were characterized by X-ray (powder and single-crystal) diffraction, microchemical (EMPA) and spectroscopic (FTIR, Mössbauer and Raman) techniques. Under reducing conditions ( NNO+1, where NNO = Nickel–Nickel oxide buffer), the amphibole yield is very high (>90%), but its composition, and in particular the FeO/Fe₂O₃ ratio, departs significantly from the nominal one. Under oxidizing conditions ( NNO+1.5), the amphibole yield is much lower (<60%, with Li-pyroxene abundant), but its composition is close to the ideal stoichiometry. The exchange vector of relevance for the studied system is ^M2(Mg,Fe²⁺) ^M4(Mg,Fe²⁺) ^M2Fe³⁺_–1 ^M4Li_–1, which is still rather unexplored in natural systems. Amphibole crystals of suitable size for structure refinement were obtained only at 800 °C, 0.4 GPa and NNO conditions (sample 152), and have C2/m symmetry. The X-ray powder patterns for all other samples were indexed in the same symmetry; the amphibole closest to ideal composition has a = 9.428(1) Å, b = 17.878(3) Å, c = 5.282(1) Å, = 102.06(2)°, V = 870.8(3) ų. Mössbauer spectra show that Fe³⁺ is strongly ordered at M2 in all samples, whereas Fe²⁺ is disordered over the B and C sites. FTIR analysis shows that the amount of ^CFe²⁺ increases for increasingly reducing conditions. FTIR data also provide strong evidence for slight but significant amounts of Li at the A sites.     

Structure modelling and cation partitioning of spinel solid solutions at high <Emphasis Type="Italic">T</Emphasis>,<Emphasis Type="Italic">P</Emphasis> conditions

This paper presents evaluation of cation distributions from diffraction data collected at high T, P, and is an extension of the spinel structure modelling procedure by Lavina et al. (2002). Optimised cation-to-oxygen distances are modified for thermal expansion and compressibility at T and P of interest following Hazen and Prewitt (1977) and Hazen and Yang (1999). The procedure is applied to literature data concerning hercynite, spinel s.s., Zn aluminate, Zn ferrite, magnetite and the (Fe₃O₄)_{1– x} (MgAl₂O₄) _x join. Calculated cation distribution is strongly affected by standard deviations in cell parameters and oxygen coordinates. The underestimated values often reported in the literature for powder profile refinements may strongly affect the cation distribution; however, if standard deviations are increased to physically realistic values, consistent results are obtained. For P up to 10 GPa, reasonable evaluations of cation distribution are obtained for spinel s.s., Zn aluminate and magnetite, whereas for Zn ferrite they are limited to 1.8 GPa. For P beyond 10 GPa, compressibility cannot be assumed to be linear; the relationship between cell parameter and pressure is well-defined, but the inaccuracy of oxygen coordinate prevents simple modelling of bond distances with pressure.     

Sedimentology and luminescence ages of Glacial Lake Humber deposits in the central Vale of York

The sedimentary sequence through the Hemingbrough Formation exposed at two sites in the central part of the Vale of York, south of the Escrick moraine ridge, is described and used to reconstruct the palaeoenvironmental history of Glacial Lake Humber. Interbedded wave ripples and laminated silts and clays at both sites indicate that Lake Humber was characterised by fluctuating water levels, often no deeper than wave base. Optically stimulated luminescence ages of 21.0 ± 1.9, 21.9 ± 2.0, and 24.1 ± 2.2 kyr returned from two wave-rippled sandy beds within the glaciolacustrine sequence at Hemingbrough, c. 10 km south of the Escrick moraine ridge, provide the first direct chronological determination for the low-level phase of Lake Humber. As these beds are principally attributed to glacial meltwater emanating from the Vale of York ice lobe of the British Ice Sheet, when its margin was at or near the Escrick moraine ridge, this corroborates the interpretation that this ridge marks the LGM ice limit.     

Analytical and numerical results on the stability of a planetary precessional model

A model for planetary precession is investigated using analytical and numerical techniques. A Hamiltonian function governing the model is derived in terms of action-angle Andoyer-Déprit variables under the assumption of equatorial symmetry. As a first approximation a simplified Hamiltonian with zero-eccentricity is considered and stability estimates are derived using KAM theory. A validation of the analytical results is performed computing Poincaré surfaces of section for the circular and elliptical model. We also investigate the role of the eccentricity and its connection with the appearance of resonances. Special attention is devoted to the particular case of the Earth–Moon system. This revised version was published online in July 2006 with corrections to the Cover Date.     

How many Stakes are Required to Measure the Mass Balance of a Glacier?

Glacier mass balance is estimated for South Cascade Glacier and Maclure Glacier using a one-dimensional regression of mass balance with altitude as an alternative to the traditional approach of contouring mass balance values. One attractive feature of regression is that it can be applied to sparse data sets where contouring is not possible and can provide an objective error of the resulting estimate. Regression methods yielded mass balance values equivalent to contouring methods. The effect of the number of mass balance measurements on the final value for the glacier showed that sample sizes as small as five stakes provided reasonable estimates, although the error estimates were greater than for larger sample sizes. Different spatial patterns of measurement locations showed no appreciable influence on the final value as long as different surface altitudes were intermittently sampled over the altitude range of the glacier. Two different regression equations were examined, a quadratic, and a piecewise linear spline, and comparison of results showed little sensitivity to the type of equation. These results point to the dominant effect of the gradient of mass balance with altitude of alpine glaciers compared to transverse variations. The number of mass balance measurements required to determine the glacier balance appears to be scale invariant for small glaciers and five to ten stakes are sufficient.     

Laboratory Study on the Hydraulic Conductivity and Pore Pressure of Sand-Silt Mixtures

The hydraulic conductivity plays a major role on the excess pore pressure generation during monotonic and cyclic loading of granular soils with fines. This paper aims to determine how much the hydraulic conductivity and pore pressure response of the sand-silt mixtures are affected by the percentage of fines and void ratio of the soil. The results of flexible wall permeameter and undrained monotonic triaxial tests performed on samples reconstituted from Chlef River sand with 0, 10, 20, 30, 40, and 50% nonplastic silt at an effective confining stress of 100 kPa and two relative densities (D_r = 20, and 91%) are presented and discussed. It was found that the pore pressure increases linearly with the increase of the fines content and logarithmically with the increase of the intergranular void ratio. The results obtained from this study reveal that the saturated hydraulic conductivity (k) of the sand mixed with 50% low plastic fines can be, on average, four orders of magnitude smaller than that of the clean sand. The results show also that the hydraulic conductivity decreases hyperbolically with the increase of the fines content and the intergranular void ratio.     

Laboratory Investigation on the Effects of Overconsolidation and Saturation on Undrained Monotonic Shear Behavior of Granular Material

In order to study pore water response and static liquefaction characteristics of silty sand, which has previously experienced liquefaction, two series of monotonic triaxial tests were run on medium dense sand specimens (RD = 50%) at confining pressure of 100 kPa. In the first test series, the influence of the soil saturation under undrained static loading has been studied. It summarizes results of monotonic tests performed on Chlef sand at various values of the Skempton's pore pressure coefficient. Analysis of experimental results gives valuable insights on the effect of soil saturation on sand response to undrained monotonic paths. In the second series of tests, the overconsolidation influence on the resistance to the sands liquefaction has been realized on samples at various values of overconsolidation ratios (OCR). It was found that the increase of overconsolidation ratio (OCR) increases the resistance of sands to liquefaction.     

Effects of limestone petrography and calcite microstructure on OPC clinker raw meals burnability

Mineralogy and Petrology - Limestone represents the main raw material for ordinary Portland cement clinker production. In this study eight natural limestones from different geological environments...