Massive stars exploding in a He-rich circumstellar medium – I. Type Ibn (SN 2006jc-like) events

We present new spectroscopic and photometric data of the Type Ibn supernovae 2006jc, 2000er and 2002ao. We discuss the general properties of this recently proposed supernova family, which also includes SN 1999cq. The early-time monitoring of SN 2000er traces the evolution of this class of objects during the first few days after the shock breakout. An overall similarity in the photometric and spectroscopic evolution is found among the members of this group, which would be unexpected if the energy in these core-collapse events was dominated by the interaction between supernova ejecta and circumstellar medium. Type Ibn supernovae appear to be rather normal Type Ib/c supernova explosions which occur within a He-rich circumstellar environment. SNe Ibn are therefore likely produced by the explosion of Wolf–Rayet progenitors still embedded in the He-rich material lost by the star in recent mass-loss episodes, which resemble known luminous blue variable eruptions. The evolved Wolf–Rayet star could either result from the evolution of a very massive star or be the more evolved member of a massive binary system. We also suggest that there are a number of arguments in favour of a Type Ibn classification for the historical SN 1885A (S-Andromedae), previously considered as an anomalous Type Ia event with some resemblance to SN 1991bg.     

Frequency‐dependent multi‐offset phase analysis of surface waves: an example of high‐resolution characterization of a riparian aquifer

Multi‐offset phase analysis of seismic surface waves is an established technique for the extraction of dispersion curves with high spatial resolution and, consequently, for the investigation of the subsurface in terms of shear wave velocity distribution. However, field applications are rarely documented in the published literature. In this paper, we discuss an implementation of the multi‐offset phase analysis consisting of the estimation of the Rayleigh wave velocity by means of a moving window with a frequency‐dependent length. This allows maximizing the lateral resolution at high frequencies while warranting stability at the lower frequencies. In this way, we can retrieve the shallow lateral variability with high accuracy and, at the same time, obtain a robust surface‐wave velocity measurement at depth. In this paper, we apply this methodology to a dataset collected for hydrogeophysical purposes and compare the inversion results with those obtained by using refraction seismics and electrical resistivity tomography. The surface‐wave results are in good agreement with those provided by the other methods and demonstrate a superior capability in retrieving both lateral and vertical velocity variations, including inversions. Our results are further corroborated by the lithological information from a borehole drilled on the acquisition line. The availability of multi‐offset phase analysis data also allows disentangling a fairly complex interpretation of the other geophysical results.     

Quaternary landscape evolution and erosion rates for an intramontane Neogene basin (Guadix–Baza basin, SE Spain)

The landscape evolution in Neogene intramontane basins is a result of the interaction of climatic, lithologic, and tectonic factors. When sedimentation ceases and a basin enters an erosional stage, estimating erosion rates across the entire basin can offer a good view of landscape evolution. In this work, the erosion rates in the Guadix–Baza basin have been calculated based on a volumetric estimate of sediment loss by river erosion since the Late Pleistocene. To do so, the distribution of a glacis surface at ca. 43 kyr, characterised by a calcrete layer that caps the basin infilling, has been reconstructed. To support this age, new radiometric data of the glacis are presented. The volume of sediment loss by water erosion has been calculated for the entire basin by comparing the reconstructed geomorphic surface and the present-day topography. The resulting erosion rates vary between 4.28 and 6.57 m³ ha^− 1 yr^− 1, and are the consequence of the interaction of climatic, lithologic, topographic, and tectonic factors. Individual erosion rates for the Guadix and Baza sub-basins (11.80 m³ ha^− 1 yr^− 1 and 1.77 m³ ha^− 1 yr^− 1 respectively) suggest different stages of drainage pattern evolution in the two sub-basins. We attribute the lower values obtained in the Baza sub-basin to the down-throw of this sub-basin caused by very recent activity along the Baza fault.     

A Functional Data Analysis Approach to Surrogate Modeling in Reservoir and Geomechanics Uncertainty Quantification

Uncertainty quantification for geomechanical and reservoir predictions is in general a computationally intensive problem, especially if a direct Monte Carlo approach with large numbers of full-physics simulations is used. A common solution to this problem, well-known for the fluid flow simulations, is the adoption of surrogate modeling approximating the physical behavior with respect to variations in uncertain parameters. The objective of this work is the quantification of such uncertainty both within geomechanical predictions and fluid-flow predictions using a specific surrogate modeling technique, which is based on a functional approach. The methodology realizes an approximation of full-physics simulated outputs that are varying in time and space when uncertainty parameters are changed, particularly important for the prediction of uncertainty in vertical displacement resulting from geomechanical modeling. The developed methodology has been applied both to a subsidence uncertainty quantification example and to a real reservoir forecast risk assessment. The surrogate quality obtained with these applications confirms that the proposed method makes it possible to perform reliable time–space varying dependent risk assessment with a low computational cost, provided the uncertainty space is low-dimensional.     

The P21/m↔ C2/m phase transition in synthetic amphibole Na NaMg Mg5 Si8 O22 (OH)2: thermodynamic and crystal-chemical evaluation

The P2₁/mC2/m displacive phase transition in the synthetic end-member amphibole Na NaMg Mg₅ Si₈ O₂₂ (OH)₂ has been studied by monitoring changes in unit-cell parameters and the intensities of superlattice reflections at 25–400 °C. This amphibole allows investigation of the effects of compositional variations at the A- and B-group sites upon the transition. Polynomial fitting of a 24 Landau potential to the evolution of the order parameter with T yielded a T _c of 257 ± 3 °C, and Landau coefficients compatible with a second-order transition. Structure refinement of single-crystal data collected at 25, 140, 270 and 370 °C allowed modelling of the structural changes as a function of T and symmetry. Crystal-chemical analysis suggests that differences in T _c in cummingtonites and in the crystal of this work depend mainly upon the relations between the aggregate ionic radii of the B- and C-group cations. Electronic Supplementary Material: of Table 5 is available in the online version of this article at http://dx.doi.org/10.1007/s00269-003-0348-9     

Controlled time–temperature oxidation reaction in a synthetic Mg-hercynite

The oxidation of a synthetic hercynite with composition Fe²⁺ _0.699Mg_0.301Al_1.941Fe³⁺ _0.059O₄ was investigated by X-ray single-crystal diffraction. Heating runs at 500°C up to 212 h did not produce detectable oxidation, but only a small variation in oxygen coordinate u, consistent with very limited reordering of Mg and Al in tetrahedral (T) and octahedral (M) sites, respectively. Oxidation began after the first run at 600°C, producing progressive decreases in u, cell parameter a and the mean atomic number in T site. After 1,842 h at 600°C, the transformation was close to equilibrium, with about 70% of ferrous iron transformed into ferric. This produced about 0.17 vacancies per formula unit, and caused a great increase in the displacement parameters of oxygen and M sites. Vacancies were strongly ordered in M sites, and the oxygen displacement parameter becames anisotropic, unlike stoichiometric spinels—because some of the oxygen coordination polyhedra have a vacancy instead of a cation in one vertex. The behaviour of displacement parameters in this case supports the calculated point defect distribution.     

A Reliable Method for Determining the Oxidation State of Manganese at the Microscale in Mn Oxides via Raman Spectroscopy

Manganese oxides are important geomaterials, widespread in terrestrial and Martian environments. Characterisation of the oxidation state of Mn is a central issue in science; this task has been addressed up to the present by X‐ray spectroscopy or diffraction techniques. The former, however, requires access to synchrotron facilities, while the latter does not provide crystal‐chemical information at the local scale. In this work, we compare a large set of Raman data from well‐characterised samples, already published by the same authors of this paper or as found in the literature. We show a clear correlation between the oxidation state of Mn and the wavenumber of peculiar bands; octahedrally co‐ordinated Mn²⁺ is recognised by a band around 530 cm^?1, Mn³⁺ by a band around 580 cm^?1 and Mn⁴⁺ by a band around 630 cm^?1, while tetrahedrally co‐ordinated Mn²⁺ is recognisable by a band around 650 cm^?1. Strongly distorted Mn³⁺ octahedra are indicated by the appearance of Jahn–Teller modes. Our method allows a reliable, easily accessible tool to characterise the oxidation states of Mn in oxides, also suitable for microscale mapping. It provides a robust analytical basis for the use of these minerals as redox indicators in geology/geochemistry, in exoplanetary research or for monitoring technological processes.