Confirmation of a meteoritic component in impact‐melt rocks of the Chesapeake Bay impact structure,Virginia, USA—Evidence from osmium isotopic and PGE systematics

Abstract— The osmium isotope ratios and platinum‐group element (PGE) concentrations of impact‐melt rocks in the Chesapeake Bay impact structure were determined. The impact‐melt rocks come from the cored part of a lower‐crater section of suevitic crystalline‐clast breccia in an 823 m scientific test hole over the central uplift at Cape Charles, Virginia. The ¹⁸⁷Os/¹⁸⁸Os ratios of impact‐melt rocks range from 0.151 to 0.518. The rhenium and platinum‐group element (PGE) concentrations of these rocks are 30–270x higher than concentrations in basement gneiss, and together with the osmium isotopes indicate a substantial meteoritic component in some impact‐melt rocks. Because the PGE abundances in the impact‐melt rocks are dominated by the target materials, interelemental ratios of the impact‐melt rocks are highly variable and nonchondritic. The chemical nature of the projectile for the Chesapeake Bay impact structure cannot be constrained at this time. Model mixing calculations between chondritic and crustal components suggest that most impact‐melt rocks include a bulk meteoritic component of 0.01–0.1% by mass. Several impact‐melt rocks with lowest initial ¹⁸⁷Os/¹⁸⁸Os ratios and the highest osmium concentrations could have been produced by additions of 0.1%–0.2% of a meteoritic component. In these samples, as much as 70% of the total Os may be of meteoritic origin. At the calculated proportions of a meteoritic component (0.01–0.1% by mass), no mixtures of the investigated target rocks and sediments can reproduce the observed PGE abundances of the impact‐melt rocks, suggesting that other PGE enrichment processes operated along with the meteoritic contamination. Possible explanations are 1) participation of unsampled target materials with high PGE abundances in the impact‐melt rocks, and 2) variable fractionations of PGE during syn‐ to post‐impact events.     

Stationary distribution function for non-adiabatic particle motion in a one dimensional current sheet

The problem of pitch angle scattering in field configurations similar to those found in the geomagnetic tail has been studied previously by Tsyganenko (1982). Tsyganenko used a scattering matrix to map pitch angle distributions through the current sheet. By using numerical solutions of the resulting integral equations he showed for weakly non-adiabatic particles the Stationary Distribution Function (SDF) was isotropic. Using his procedure the SDF was found to develop anisotropies with increasing non-adiabaticity. The work presented here shows analytically that for any degree of scattering the SDF must be isotropic for a general planar field reversal. Computations of particle trajectories have been used to verify some aspects of the analytic work.     

Inhomogeneous substrate analysis using EM300 backscatter imagery

Backscatter reflectivity from multibeam echo-sounders provides a powerful tool to efficiently characterize seafloor substrates. A comprehensive EM300 bathymetric and backscatter survey has been completed of Cook Strait, in central New Zealand. This paper presents a detailed analysis of the realtime corrections applied to the raw EM300 multibeam data and additional corrections required to compute angular variations of the backscatter strength. The corrections, including the local absorption coefficient, the influence of seafloor topography and sound refraction in the water column, are determined for different Cook Strait seafloor substrates. Modifying MB-System software code, we extracted the backscatter signal parameters in order to quantify the raw backscatter strength and apply additional processing. Profiles of backscatter strength versus incidence angle were computed for a variety of sites characterized by flat seafloor and homogeneous substrates, and for which ground-truth data were available. For each homogeneous site, different but characteristic backscatter profiles are observed that can be interpreted in terms of sediment facies. To analyze heterogeneous substrates, we present a statistical technique, based on a 3-dimensional distribution of (incidence angle, backscatter strength) couples that preserves geological information of the substrate components. This analysis, using backscatter data acquired on a submarine volcano, north of New Zealand, clearly differentiates soft sediments and lava flows within a heterogeneous substrate.     

Bathymetry of the Tonga Trench and Forearc: a map series

Four new bathymetric maps of the Tonga Trench and forearc between 14 °S and 27 °S display the important morphologic and structural features of this dynamic convergent margin. The maps document a number of important geologic features of the margin. Major normal faults and fault lineaments on the Tonga platform can be traced along and across the upper trench slope. Numerous submarine canyons incised in the landward slope of the trench mark the pathways of sediment transport from the platform to mid- and lower-slope basins. Discontinuities in the trench axis and changes in the morphology of the landward slope can be clearly documented and may be associated with the passage and subduction of the Louisville Ridge and other structures on the subducting Pacific Plate. Changes in the morphology of the forearc as convergence changes from normal in the south to highly-oblique in the north are clearly documented. The bathymetric compilations, gridded at 500- and 200-m resolutions and extending along 500 km of the landward trench slope and axis, provide complete coverage of the outer forearc from the latitude of the Louisville Ridge-Tonga Trench collision to the northern terminus of the Tonga Ridge. These maps should serve as a valuable reference for other sea-going programs in the region, particularly the Ocean Drilling Program (ODP) and the National Science Foundation MARGINS initiative.     

Short period internal waves over the Huanghe (Yellow River) delta front

Internal waves with periods of about 5 minutes and trough to crest heights of up to 6.2 m were observed acoustically over the actively accreting delta front of the Huanghe (Yellow River) in the western portion of the Gulf of Bohai, Peoples Republic of China. The radian frequency of the internal waves was close to the locally-observed Brunt-Vaisala frequency. Through the relatively short (one hour) duration of an internal wave train, the amplitude was observed to decrease progressively with time. These internal waves may cause resuspension of delta-front sediments.     

The Potential for Environmentally Sound Development of Marine Deposits of Potassic and Phosphatic Minerals Offshore, Southern Africa

Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits.     

Seamount gravity anomaly modelling with variably thick sediment cover

Inversion modelling of marine gravity anomalies to derive predicted seafloor topography has provided significant advance in delineating deep-ocean bathymetry where the seafloor both conforms to the half-space cooling model of seafloor spreading, and largely sediment-free. Similar modelling for elevated ridges and seamounts, that are formed by processes other than seafloor spreading and/or have proximal sediment sources (e.g., continental margins and volcanic arcs), have significantly higher errors when validated against modern shipborne echo-sounding data. A three-dimensional, five-layer gravity model is emulated for the cases of both synthetic and real seamounts, with varying degrees of sediment burial, to establish the sensitivity of variable sediment cover as a source of error. A simple `Gaussian' seamount with base radius of 30 km, 2000 m of relief, has a maximum 140–160 mGal anomaly, that decreases to 50 mGal with the addition of 1 km of sediment cover with simple `flood' geometry. Complete burial, with a typical sediment density of 2300 kg m^–3, results in a 120 mGal difference from a sediment-free seamount model. Increasing sediment density results in an exponential decay of the seamount anomaly. More complex synthetic geometries of varying basement relief and sediment thickness show that the anomaly amplitude remains significant, especially where the latter is >700–800 m thick. For the real case, seamounts of the Three Kings Ridge (northern New Zealand) imaged with seismic reflection data, with varying degrees of sediment cover of up to 1 km, when modelled both with and with-out the inclusion of a sediment layer, typically have rms differences of 30 mGal between observed and modelled gravity anomalies. Significantly, the rms errors are reduced by 50% with the inclusion of a sediment layer that corresponds to a reduction of predicted seafloor topography rms errors of 192–684 m to 78–360 m.     

Effects of benthic biology on bottom boundary layer processes, Dry Tortugas Bank, Florida Keys

 An instrumented tetrapod was deployed for three weeks on the Dry Tortugas Bank at a depth of 26 m in February 1995. Bottom roughness was dominated by shrimp burrows and worm mounds with rms roughness amplitudes ranging from 0.47 to 1.75 cm. Logarithmic velocity profiles show apparent total roughness heights ranging from 0.30 to 1.45 cm, values consistent with observed biological roughness. The bed sediments were weakly bound by an algal crust at the sediment–water interface. When this bound layer was scraped away by a mooring that was accidentally dragged, sharp-crested wave-induced ripples appeared within the resulting swath. We conclude that physically induced roughness is biologically suppressed, but if dominant, would be significantly higher than the prevailing biological roughness.