A climate-related oxidizing event in deep-sea sediment from the Bering Sea

Many cores from the deep basins of the Bering Sea have a thin oxidized zone within otherwise reduced sediment. This oxidized zone began to form about 6000 yr ago and represents an interval of about 3200 yr. Mineralogically, the oxidized and reduced sediments are similar, but chemically they differ. Concentrations of Fe and C are lower, and concentrations of Mn, Ba, Co, Mo, and Ni are higher in the oxidized than in the reduced sediment. Mn is enriched about 10-fold in the oxidized zone relative to its concentration in the reduced sediment, Mo about threefold, and Ba, Co, and Ni about twofold. These data suggest that the oxidized zone developed diagenetically as the result of the balance between the flux of organic matter and the available dissolved oxygen in bottom and interstitial waters.We propose that the Bering Sea was substantially ice covered when global glacial conditions prevailed. during the transition to global interglacial conditions, seasonal meltwater from thawing sea ice formed a lens of fresh water that decreased organic productivity. During the winter seasons, however, sea ice reformed and caused downwelling of dense, oxygen-rich waters to recharge bottom waters. The combination of lower organic productivity and more oxygen-rich bottom water allowed oxidized sediment to accumulate. Once full interglacial conditions were established, the volume of sea ice produced was insufficient to affect either productivity or the supply of dissolved oxygen and so bottom conditions again became reducing.Similar events probably occurred during the onset of global glacial conditions, and similar oxidized layers probably formed at these times. Such oxidized zones are highly unstable, however, in a reducing environment and, once buried beyond the influence of bacterial and infaunal activities, are depleted of their available oxygen and converted to reduced sediment.     

The Late Pleistocene Afton Lodge Clay Formation,Ayrshire, Scotland: evidence for Early to Middle Devensian climatic changes and Late Devensian onshore ice flow and rafting from the Firth of Clyde

An investigation into the late Pleistocene sediments exposed at Afton Lodge has helped to clarify the glacial history of western central Scotland. The sequence includes several allochthonous bodies of ‘shelly clay’ (Afton Lodge Clay Formation) associated with Late Devensian (Weichselian) age diamict. The shelly clay contains abundant marine macro- and microfauna, as well as palynomorphs consistent with its deposition within a shallow marine to estuarine environment. Faunal changes within the main body of marine clay record at least one, millennial-scale cycle of Arctic-Boreal, to Boreal, and back to Arctic-Boreal climatic conditions. A radiocarbon date of over 41 ka ¹⁴C BP obtained from the foraminifera indicates that the marine clays are older than the surrounding till. Afton Lodge is thus one of a suite of ‘high-level’ shelly clay occurrences around the Scottish coasts that are now considered to be glacially transported. Together with closely associated ‘shelly tills’, the rafts were emplaced during an early phase of the last glaciation by ice flowing from the western Grampian Highlands of Scotland through the topographically-confined Firth of Clyde basin. The blocks of marine sediment were detached subglacially, unfrozen, and carried at least 10 km by ice that splayed out onshore against reversed slopes favouring raft emplacement and the creation of closely associated ribbed moraine. Transport of the rafts was facilitated by water-lubricated décollement surfaces and their accretion was accompanied by dewatering. The shelly tills were formed mainly by the attenuation and crushing of rafts of shelly clay during their transport within the subglacial deforming bed.     

Vertical Structure Of Turbulence In Offshore Flow During Rasex

The adjustment of the boundary layer immediately downstream froma coastline is examined based on two levels of eddy correlation data collected on a mast at the shore and six levels of eddy correlation data and profiles of mean variables collected from a mast 2 km offshore during the Risø Air-Sea Experiment. The characteristics of offshore flow are studied in terms of case studies and inter-variable relationships for the entire one-month data set. A turbulent kinetic energy budget is constructed for each case study.The buoyancy generation of turbulence is small compared to shear generation and dissipation. However, weakly stable and weakly unstable cases exhibit completely different vertical structure. With flow of warm air from land over cooler water, modest buoyancy destruction of turbulence and reduced shear generation of turbulence over the less rough sea surface cause the turbulence to rapidly weaken downstream from the coast. The reduction of downward mixing of momentum by the stratification leads to smaller roughness lengths compared to the unstable case. Shear generation at higher levels and advection of stronger turbulence from land often lead to an increase of stress and turbulence energy with height and downward transport of turbulence energy toward the surface.With flow of cool air over a warmer sea surface, a convective internal boundary layer develops downstream from the coast. An overlying relatively thick layer of downward buoyancy flux (virtual temperature flux) is sometimes maintained by shear generation in the accelerating offshore flow.     

Fetch Limited Drag Coefficients

Measurements made at a tower located 2 km off the coast of Denmark inshallow water during the Risø Air Sea Experiment (RASEX) are analyzedto investigate the behaviour of the drag coefficient in the coastal zone.For a given wind speed, the drag coefficient is larger during conditions ofshort fetch (2-5 km) off-shore flow with younger growing waves than it isfor longer fetch (15-25 km) on-shore flow. For the strongest on-shorewinds, wave breaking enhances the drag coefficient. Variation of the neutral drag coefficient in RASEX is dominated byvariation of wave age, frequency bandwidth of the wave spectra and windspeed. The frequency bandwidth is proportional to the broadness of the waveheight spectra and is largest during conditions of light wind speeds. Usingthe RASEX data, simple models of the drag coefficient and roughness length are developed in terms of wind speed, wave age and bandwidth. An off-shoreflow model of the drag coefficient in terms of nondimensional fetch isdeveloped for situations when the wave state is not known.     

460矿床富矿形成中的叠加成矿作用

460矿床不但具有相当的规模,而且有一定储量的富矿石。矿床内部铀品位变化大,有中深部和浅部两个高品位矿石聚集区。决定460矿床富矿形成和定位的主要地质因素是:经过两次预富集作用构成的高铀区城地质背景;由多组断裂构造和火山构造交切及矿前水云母化提供的成矿通道和储矿条件;具有燕山晚期和喜山期发生的热液蚀变成矿作用的相互叠加;矿后只遭到浅度剥蚀,具有良好的保矿条件。