Short-term sedimentation dynamics in the Rhône River Delta. France: The importance of riverine pulsing

Short-term sedimentation patterns were evaluated from August 1992 to May 1993 in different wetland habitats characteristic of the Rhône Delta, including impounded and seasonally-dry saline Arthrocnemum marshes, brackish Juncus, Phragmites, and Scirpus riverine wetlands directly connected to the Rhône River, and Arthrocnemum-dominated marine marshes influenced by the Mediterranean. Short-term sedimentation was measured as sediment accumulation on paper filters which had been placed on the soil surface for several weeks. Total sedimentation and material lost on ignition was significantly related to individual sampling periods, reflecting the importance of short-term processes. High sedimentation at riverine sites (up to 22 g m^?2 d^?1) was related to a combination of river stage and wind events. Marine and impounded wetlands of the Rhône Delta experienced low sedimentation throughout the period of study. Sedimentation rates averaged over the study period were 0.8 g m^?2 d^?1, 1.8 g m^?2 d^?1, and 5.4 g m^?2 d^?1 for marine, impounded, and riverine sites, respectively. Percent material lost on ignition was low in all habitats (average 15%) and followed a seasonal trend with a minimum in late fall and winter (1%). Soil percent organic matter was also low in the top several centimeters (13%), suggesting that inorganic sedimentation is very important for accretion on these wetland surfaces. Coastal flooding was not a significant mechanism for sedimentation in the marine sites during the period of study. Sedimentation is an important factor in elevation change, and this study shows that impounded habitats, the most common “natural environment“ left in the delta, may become vulnerable to sea-level rise in the future if management practices continue to isolate these wetlands from riverine sources of sediment.     

Drainage density changes during rainfall

Observations of stream behaviour during rainfall indicate that previous notions of a simple expanding and contracting network need review and refinement. In a small rural catchment near Armidale, N.S.W. changes in flowing stream length during rainfall have been depicted on flow length graphs which indicate a varied network response to similar rainfall amounts. Channel flow phenomena include discontinuous flow, the generation of flow points within the channel and movement of water downslope from saturated depression sources. Localized physical controls have a significant effect on stream growth which is a sensitive indicator of the catchment response to rainfall. During rapid changes in stream length total flowing length and discharge are highly correlated. A model of the pattern of network expansion and contraction involves several phases of flow contraction.     

Evidence for high‐temperature fractionation of lithium isotopes during differentiation of the Moon

Lithium isotope and abundance data are reported for Apollo 15 and 17 mare basalts and the LaPaz low‐Ti mare basalt meteorites, along with lithium isotope data for carbonaceous, ordinary, and enstatite chondrites, and chondrules from the Allende CV3 meteorite. Apollo 15 low‐Ti mare basalts have lower Li contents and lower δ⁷Li (3.8 ± 1.2‰; all uncertainties are 2 standard deviations) than Apollo 17 high‐Ti mare basalts (δ⁷Li = 5.2 ± 1.2‰), with evolved LaPaz mare basalts having high Li contents, but similar low δ⁷Li (3.7 ± 0.5‰) to Apollo 15 mare basalts. In low‐Ti mare basalt 15555, the highest concentrations of Li occur in late‐stage tridymite (>20 ppm) and plagioclase (11 ± 3 ppm), with olivine (6.1 ± 3.8 ppm), pyroxene (4.2 ± 1.6 ppm), and ilmenite (0.8 ± 0.7 ppm) having lower Li concentrations. Values of δ⁷Li in low‐ and high‐Ti mare basalt sources broadly correlate negatively with ¹⁸O/¹⁶O and positively with ⁵⁶Fe/⁵⁴Fe (low‐Ti: δ⁷Li ≤4‰; δ⁵⁶Fe ≤0.04‰; δ¹⁸O ≥5.7‰; high‐Ti: δ⁷Li >6‰; δ⁵⁶Fe >0.18‰; δ¹⁸O <5.4‰). Lithium does not appear to have acted as a volatile element during planetary formation, with subequal Li contents in mare basalts compared with terrestrial, martian, or vestan basaltic rocks. Observed Li isotopic fractionations in mare basalts can potentially be explained through large‐degree, high‐temperature igneous differentiation of their source regions. Progressive magma ocean crystallization led to enrichment in Li and δ⁷Li in late‐stage liquids, probably as a consequence of preferential retention of ⁷Li and Li in the melt relative to crystallizing solids. Lithium isotopic fractionation has not been observed during extensive differentiation in terrestrial magmatic systems and may only be recognizable during extensive planetary magmatic differentiation under volatile‐poor conditions, as expected for the lunar magma ocean. Our new analyses of chondrites show that they have δ⁷Li ranging between ?2.5‰ and 4‰. The higher δ⁷Li in planetary basalts than in the compilation of chondrites (2.1 ± 1.3‰) demonstrates that differentiated planetary basalts are, on average, isotopically heavier than most chondrites.     

Evidence for distinct proportions of subducted oceanic crust and lithosphere in HIMU-type mantle beneath El Hierro and La Palma, Canary Islands

Shield-stage high-MgO alkalic lavas from La Palma and El Hierro (Canary Islands) have been characterized for their O-Sr-Nd-Os-Pb isotope compositions and major-, trace-, and highly siderophile-element (HSE: Os, Ir, Ru, Pt, Pd, Re) abundances. New data are also reported for associated evolved rocks, and entrained xenoliths. Clear differences in Pd/Ir and isotopic ratios for high Os (>50 ppt) lavas from El Hierro (δ¹⁸O_olivine = 5.17 ± 0.08‰; ⁸⁷Sr/⁸⁶Sr = 0.7029 to 0.7031; ε_Nd = +5.7 to +7.1; ¹⁸⁷Os/¹⁸⁸Os = 0.1481 to 0.1750; ²⁰⁶Pb/²⁰⁴Pb = 19.1 to 19.7; Pd/Ir = 6 ± 3) versus those from La Palma (δ¹⁸O_olivine = 4.87 ± 0.18‰; ⁸⁷Sr/⁸⁶Sr = 0.7031 to 0.7032; ε_Nd = +5.0 to +6.4; ¹⁸⁷Os/¹⁸⁸Os = 0.1421 to 0.1460; ²⁰⁶Pb/²⁰⁴Pb = 19.5 to 20.2; Pd/Ir = 11 ± 4) are revealed from the dataset.Crustal or lithospheric assimilation during magma transport cannot explain variations in isotopic ratios or element abundances of the lavas. Shallow-level crystal-liquid fractionation of olivine, clinopyroxene and associated early-crystallizing minerals (e.g., spinel and HSE-rich phases) controlled compatible element and HSE abundances; there is also evidence for sub-aerial degassing of rhenium. High-MgO lavas are enriched in light rare earth elements, Nb, Ta, U, Th, and depleted in K and Pb, relative to primitive mantle abundance estimates, typical of HIMU-type oceanic island basalts. Trace element abundances and ratios are consistent with low degrees (2-6%) of partial melting of an enriched mantle source, commencing in the garnet stability field (?110 km). Western Canary Island lavas were sulphur undersaturated with estimated parental melt HSE abundances (in ppb) of 0.07 ± 0.05 Os, 0.17 ± 0.16 Ir, 0.34 ± 0.32 Ru, 2.6 ± 2.5 Pt, 1.4 ± 1.2 Pd, 0.39 ± 0.30 Re. These estimates indicate that Canary Island alkali basalts have lower Os, Ir and Ru, but similar Pt, Pd and Re contents to Hawai’ian tholeiites.The HIMU affinities of the lavas, in conjunction with the low δ¹⁸O_olivine and high ²⁰⁶Pb/²⁰⁴Pb for La Palma, and elevated ¹⁸⁷Os/¹⁸⁸Os for El Hierro implies melting of different proportions of recycled oceanic crust and lithosphere. Our preferred model to explain isotopic differences between the islands is generation from peridotitic mantle metasomatised by <10% pyroxenite/eclogite made from variable portions of similar aged recycled oceanic crust and lithosphere. The correspondence of radiogenic ²⁰⁶Pb/²⁰⁴Pb, ¹⁸⁷Os/¹⁸⁸Os, elevated Re/Os and Pt/Os, and low-δ¹⁸O in western Canary Island lavas provides powerful support for recycled oceanic crust and lithosphere to generate the spectrum of HIMU-type ocean island basalt signatures. Persistence of geochemical heterogeneities throughout the stratigraphies of El Hierro and La Palma demonstrate long-term preservation of these recycled components in their mantle sources over relatively short-length scales (∼50 km).     

Geochemical processes controlling arsenic mobility in groundwater: A case study of arsenic mobilization and natural attenuation

The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes.     

Low dispersive modeling of Rayleigh waves on partly staggered grids

In elastic media, finite-difference (FD) implementations of free-surface (FS) boundary conditions on partly staggered grid (PSG) use the highly dispersive vacuum formulation (VPSG). The FS boundary is embedded into a “vacuum” grid layer (null Lame’s constants and negligible density values) where the discretized equations of motion allow computing surface displacements. We place a new set of compound (stress-displacement) nodes along a planar FS and use unilateral mimetic FD discretization of the zero-traction conditions for displacement computation (MPSG). At interior nodes, MPSG reduces to standard VPSG methods and applies fourth-order centered FD along cell diagonals for staggered differentiation combined with nodal second-order FD in time. We perform a dispersion analysis of these methods on a Lamb’s problem and estimate dispersion curves from the phase difference of windowed numerical Rayleigh pulses at two FS receivers. For a given grid sampling criterion (e.g., six or ten nodes per reference S wavelength λ ^S), MPSG dispersion errors are only a quarter of the VPSG method. We also quantify root-mean-square (RMS) misfits of numerical time series relative to analytical waveforms. MPSG RMS misfits barely exceed 10 % when nine nodes sample the minimum S wavelength $\lambda _{\text {MIN}}^{\mathrm {S}}$ in transit (along distances $\sim $ 145 $\lambda _{\text {MIN}}^{\mathrm {S}}$ ). In same tests, VPSG RMS misfits exceed 70 %. We additionally compare MPSG to a consistently fourth-order mimetic method designed on a standard staggered grid. The latter equates the former’s dispersion errors on grids twice denser and shows higher RMS precision only on grids with six or less nodes per $\lambda _{\text {MIN}}^{\mathrm {S}}$ .     

Advancing process‐based watershed hydrological research using near‐surface geophysics: a vision for,and review of,electrical and magnetic geophysical methods

We want to develop a dialogue between geophysicists and hydrologists interested in synergistically advancing process based watershed research. We identify recent advances in geophysical instrumentation, and provide a vision for the use of electrical and magnetic geophysical instrumentation in watershed scale hydrology. The focus of the paper is to identify instrumentation that could significantly advance this vision for geophysics and hydrology during the next 3–5 years. We acknowledge that this is one of a number of possible ways forward and seek only to offer a relatively narrow and achievable vision. The vision focuses on the measurement of geological structure and identification of flow paths using electrical and magnetic methods. The paper identifies instruments, provides examples of their use, and describes how synergy between measurement and modelling could be achieved. Of specific interest are the airborne systems that can cover large areas and are appropriate for watershed studies. Although airborne geophysics has been around for some time, only in the last few years have systems designed exclusively for hydrological applications begun to emerge. These systems, such as airborne electromagnetic (EM) and transient electromagnetic (TEM), could revolutionize hydrogeological interpretations. Our vision centers on developing nested and cross scale electrical and magnetic measurements that can be used to construct a three‐dimensional (3D) electrical or magnetic model of the subsurface in watersheds. The methodological framework assumes a ‘top down’ approach using airborne methods to identify the large scale, dominant architecture of the subsurface. We recognize that the integration of geophysical measurement methods, and data, into watershed process characterization and modelling can only be achieved through dialogue. Especially, through the development of partnerships between geophysicists and hydrologists, partnerships that explore how the application of geophysics can answer critical hydrological science questions, and conversely provide an understanding of the limitations of geophysical measurements and interpretation. Copyright © 2008 John Wiley & Sons, Ltd.     

Deep events in U.K. South Western Approaches

Summary. Apparently planar dipping events are observed in seismic data off south-west Britain within otherwise essentially transparent upper and middle crust. These are believed to represent Variscan thrusts, some of which were re-activated during the post-Carboniferous phase of extension that affected the southern U.K. They can be seen in two extensive commercial seismic surveys recorded to 6 s two-way-time (TWT) and, where laterally persistent, they have been mapped to reveal their essentially planar nature. Commonly these dipping events are associated with deeper, near-horizontal, or gently convex upwards events with which they often appear to converge. Where 'real', these are thought to indicate a complex fault system or possibly the top of the reflective lower crust. The thrusts are seen over the whole area except where granite is known to occur, and commonly exert a major control on the position and subsequent deformation of overlying sedimentary basins.     

Water planning priorities and conflicts in The Hunter Valley,NSW

This paper examines the ability of society to develop and allocate water resources during a time of major drought and industrial growth. Water shortage in the upper Hunter became apparent between 1979 and 1983. Even the well watered Newcastle metropolitan area experienced domestic and commercial restrictions. Strategies to deal with the immediate problems in inland areas included temporary water restrictions, cessation of issue of new irrigation licences, institution of volumetric water allocation to agriculture and appeals for public cooperation. Government was placed under pressure to provide sufficient industrial water, maintain supplies to agriculture and distribute water resource information to private and public sector decision makers. Major regional water planning initiatives were almost as slow to eventuate as those for social infrastructure provision. Such crises are likely to recur. Questions remain as to the desirability and sufficiency of current allocative mechanisms to cope with the future diversity of water needs.     

Resource use in the tropical karstlands of central Belize

Rural tropical ecosystems are subject to many traditional land uses that employ the indigenous karst resources: rock, water, soil, vegetation, and wildlife. Individual resource pressures often are subtle, but their combined impact can precipitate instability in the tropical karst environment, potentially resulting in disruption of food, water, and fuel supplies. The karst of central Belize was used intensively for some six centuries by Maya farmers, but between the 10th and 19th centuries AD most of it reverted to secondary forest. Commercial logging dominated the 19th and early 20th centuries, followed by the expansion of subsistence and commercial agriculture after 1945. In the 1980s resource use has accelerated as population and other pressures increase. Much karst remains forested, but there is increasing clearance for agricultural uses, particularly for citrus cultivation and small-scale mixed agriculture. Soil depletion has begun to occur, water resources are increasingly taxed, and some wildlife is threatened by habitat destruction and increased hunting. Lime production for the citrus industry has promoted quarrying, water extraction, and fuelwood use. Environmental stresses currently do not exceed the threshold of instability, but the rapidly developing rural economy warrants careful monitoring of resource pressures.