Sustainability of Mediterranean Deltaic and Lagoon Wetlands with Sea-Level Rise: The Importance of River Input

We report on a decadal trend of accretionary dynamics in the wetlands of several northwestern Mediterranean deltas and a lagoon system, all of them with high rates of wetland loss. Wetland vertical accretion and surface elevation change were measured at 55 riverine, marine, and impounded sites in four coastal systems: the Ebro delta, Spain; the Rhône delta, France; and the Po delta and Venice Lagoon, Italy. Vertical accretion and elevation change ranged between 0 and 25 mm year^?1 and were strongly correlated. The highest rates of elevation gain occurred at riverine sites where vertical accretion was highest. We conclude that areas with high sediment input, mainly riverine, are the only ones likely to survive accelerated sea-level rise, especially if recent higher estimates of 1 m or more in the twenty-first century prove to be accurate. This is the first study where the importance of river input on wetland survival has been demonstrated at a decadal time scale over a broad geographical area.     

Beyond individual quotas: The role of trust and cooperation in promoting stewardship of five Australian abalone fisheries

Private property rights, such as individual transferable quotas, are thought to encourage fishers to act as resource stewards. To achieve this, however, fishers must be able to cooperate with each other. This paper examines the relationship between trust, cooperation and stewardship in five abalone (Haliotis) fisheries in southeastern Australia. Industry-led resource management initiatives are used as indicators of stewardship, sometimes including substantial sacrifice of catch quota. Higher levels of trust and cooperative capacity enabled greater levels of industry-based resource management in four of the five fisheries. In one case, however, high levels of trust and cooperative capacity did not translate into associated levels of resource management. It is suggested that additional factors, such as perceptions of resource condition, are key determinants of resource stewardship. Private property rights may, therefore, be less important than previously argued.     

Turbidity regimes over fringing coral reefs near a mining site at Lihir Island,Papua New Guinea

An extensive sediment transport survey took place at Lihir Island (Papua New Guinea), where mining operations involve disposal of waste rocks and soil in nearshore waters. To investigate the potential impact of these practices over neighbouring fringing reefs, turbidity and sediment accumulation were measured continuously for extended periods. Turbidity records provided a map of observed impact zones based on turbidity thresholds. The main zoning features were (a) that an extreme turbidity gradient persists between the inner harbour (turbidity levels of 100-1000 mg l(-1)) and the adjacent reefs (turbidity levels in the order of 10 mg l(-1)), and (b) that observed zones conform with pre-operations impact predictions. Accumulation measurements unveiled no significant sediment accumulation over fringing coral reefs. This study contributes to the understanding of the potential impact of sediment discharge to nearshore waters.     

Identifying biologically and physically special or unique sites for inclusion in the protected area design for the Great Barrier Reef Marine Park

A method to identify special and/or unique sites was developed when reviewing the zoning of the Great Barrier Reef Marine Park. Fifty-three (totalling approximately 10,445 km²) of 408 sites were identified as special or unique based on the amount, detail and nature of justification; geographic explicitness; type of information sources; number of independent sources; and national or international obligations. All but four special or unique sites increased in protection after the Zoning Plan was revised, increasing the area of no-take protection for all special or unique sites from 1614 km² (15.4%) to 4013 km² (38.4%).     

Sweet chestnut (Castanea sativa) leaves as a bio-indicator of volcanic gas,aerosol and ash deposition onto the flanks of Mt Etna in 2005–2007

Sweet chestnut leaves (Castanea sativa) collected from the flanks of Mt Etna volcano in 2005–2007 were analysed by inductively-coupled plasma mass spectrometry to investigate the spatial and temporal variability of element concentrations. The aim of this work was to determine whether these leaves are a bio-indicator for volcanic gas, aerosol and ash deposition and to gain new insights into the environmental effects of quiescent and eruptive volcanic plumes. Results show a positive correlation between sample variability in the concentration of elements in Castanea sativa and enrichment factors of elements in the plume. The spatial and temporal variability of chalcophilic elements (As, Cd, Cu, Mo, Tl, Zn) is consistent with prevailing winds transporting eruptive plumes to the south-east of the summit, resulting in enhanced plume deposition onto the flanks of the volcano. Similar spatial and temporal variability was found for the halide-forming elements (Cs, K, Rb) and intermediate elements (Al, Co, Mn). The spatial variability of chalcophilic, intermediate and halide-forming elements during quiescent periods was diminished (relative to eruptive periods) and could not be explained by plume deposition. In contrast, the concentrations of lithophilic elements (Ba, Ca, Mg, Sr) did not show any clear spatial variability even during eruptive periods. Comparisons between enrichment factors for elements in Castanea sativa and literature values for enrichment factors of the volcanic plume, groundwater and lichen were made. Whilst Castanea sativa offers insights into the spatial and temporal variability of deposition, the species may not be a bio-indicator for plume composition due to biological fractionation.     

ROCK HARDNESS: FIELD ASSESSMENT AND GEOMORPHIC IMPORTANCE

The precise correlations between rock hardness, resistance to erosion, and landform development have hitherto been difficult to establish. Rock hardness has proved difficult to assess, particularly in the field, because suitable equipment has not been applied. The Schmidt Test Hammer is demonstrated to be an effective instrument for this purpose. The hammer gives an accurate and rapid measure of surface hardness, which is shown to be useful in the context of weathering and landform development.     

A comparison of pre‐ and post‐remediation water quality,Mineral Creek,Colorado

Pre‐ and post‐remediation data sets are used herein to assess the effectiveness of remedial measures implemented in the headwaters of the Mineral Creek watershed, where contamination from hard rock mining has led to elevated metal concentrations and acidic pH. Collection of pre‐ and post‐remediation data sets generally followed the synoptic mass balance approach, in which numerous stream and inflow locations are sampled for the constituents of interest and estimates of streamflow are determined by tracer dilution. The comparison of pre‐ and post‐remediation data sets is confounded by hydrologic effects and the effects of temporal variation. Hydrologic effects arise due to the relatively wet conditions that preceded the collection of pre‐remediation data, and the relatively dry conditions associated with the post‐remediation data set. This difference leads to a dilution effect in the upper part of the study reach, where pre‐remediation concentrations were diluted by rainfall, and a source area effect in the lower part of the study reach, where a smaller portion of the watershed may have been contributing constituent mass during the drier post‐remediation period. A second confounding factor, temporal variability, violates the steady‐state assumption that underlies the synoptic mass balance approach, leading to false identification of constituent sources and sinks. Despite these complications, remedial actions completed in the Mineral Creek headwaters appear to have led to improvements in stream water quality, as post‐remediation profiles of instream load are consistently lower than the pre‐remediation profiles over the entire study reach for six of the eight constituents considered (aluminium, arsenic, cadmium, copper, iron, and zinc). Concentrations of aluminium, cadmium, copper, lead, and zinc remain above chronic aquatic‐life standards, however, and additional remedial actions may be needed. Future implementations of the synoptic mass balance approach should be preceded by an assessment of temporal variability, and modifications to the synoptic sampling protocol should be made if necessary. Published in 2009 by John Wiley & Sons, Ltd.     

A surface complexation and ion exchange model of Pb and Cd competitive sorption on natural soils

The bioavailability and fate of heavy metals in the environment are often controlled by sorption reactions on the reactive surfaces of soil minerals. We have developed a non-electrostatic equilibrium model (NEM) with both surface complexation and ion exchange reactions to describe the sorption of Pb and Cd in single- and binary-metal systems over a range of pH and metal concentration. Mineralogical and exchange properties of three different acidic soils were used to constrain surface reactions in the model and to estimate surface densities for sorption sites, rather than treating them as adjustable parameters. Soil heterogeneity was modeled with >FeOH and >SOH functional groups, representing Fe- and Al-oxyhydroxide minerals and phyllosilicate clay mineral edge sites, and two ion exchange sites (X⁻ and Y⁻), representing clay mineral exchange. An optimization process was carried out using the entire experimental sorption data set to determine the binding constants for Pb and Cd surface complexation and ion exchange reactions.Modeling results showed that the adsorption of Pb and Cd was distributed between ion exchange sites at low pH values and specific adsorption sites at higher pH values, mainly associated with >FeOH sites. Modeling results confirmed the greater tendency of Cd to be retained on exchange sites compared to Pb, which had a higher affinity than Cd for specific adsorption on >FeOH sites. Lead retention on >FeOH occurred at lower pH than for Cd, suggesting that Pb sorbs to surface hydroxyl groups at pH values at which Cd interacts only with exchange sites. The results from the binary system (both Pb and Cd present) showed that Cd retained in >FeOH sites decreased significantly in the presence of Pb, while the occupancy of Pb in these sites did not change in the presence of Cd. As a consequence of this competition, Cd was shifted to ion exchange sites, where it competes with Pb and possibly Ca (from the background electrolyte). Sorption on >SOH functional groups increased with increasing pH but was small compared to >FeOH sites, with little difference between single- and binary-metal systems. Model reactions and conditional sorption constants for Pb and Cd sorption were tested on a fourth soil that was not used for model optimization. The same reactions and constants were used successfully without adjustment by estimating surface site concentrations from soil mineralogy. The model formulation developed in this study is applicable to acidic mineral soils with low organic matter content. Extension of the model to soils of different composition may require selection of surface reactions that account for differences in clay and oxide mineral composition and organic matter content.     

Experimental techniques for the investigation of dust condensation processes

Two experimental methods by which silicates may be condensed from vapors of their constituents are discussed and compared. Each has some relevance to astrophysical processes, though the experiments are by necessity simpler than the astrophysical environments.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium, held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.