Conservation laws of wave action and potential enstrophy for rossby waves in a stratified atmosphere

The purpose of this article is to discuss the evolution of wave energy, enstrophy and action for atmospheric Rossby waves in a variable mean flow. The presentation is theoretical, but does not represent original research; rather, it is pedagogic in nature. The work of a number of people has been drawn together into a unified account, with much of the algebra implicit in previous work made explicit here. The central results are that wave energy is conserved only when there are no spatial variations in the mean flow, and wave action is conserved even in the presence of such variations as long as they are not in the longitudinal direction. Finally, wave enstrophy is conserved in the presence of arbitrary (slow) mean flow variations.     

On the inter-relationship between grain size sensitive creep and dynamic recrystallization of olivine

The recent theoretical results of Twiss (1976) and Goetze (1978) suggest that at high temperatures and sufficiently high stresses the creep behavior of dry olivine should be dominated by either nonlinear diffusion accommodated grain-boundary sliding or nonlinear Coble creep mechanisms. This would result following the production of a fine grain-size by dynamic recrystallization. For the high-temperature experimental work performed by Karato et al. (1982) dry single crystals of olivine were almost totally recrystallized during creep, and temperature changing experiments were performed on the resulting dynamically recrystallizing polycrystalline aggregates. However, the activation energy for creep determined by Karato et al. (1982) was far higher than that predicted by the models of Twiss (1976) or Goetze (1978), although the conditions required for operation of at least the model of Twiss (1976) apparently were satisfied. The data for the highly recrystallized specimens from the higher stress, lower temperature experiments of Zeuch and Green (1979) and Zeuch (1980) are in good agreement with the results of Karato et al. (1982). These latter experiments were conducted under conditions where either the model of Twiss (1976) or Goetze (1978) should have been applicable. I tentatively conclude that although fine grain sizes were produced in the experiments of Karato et al. (1982), Zeuch and Green (1979) and Zeuch (1980) by dynamic recrystallization, there is no evidence for a transition to grain-boundary diffusional creep mechanisms at high or low stresses despite the predictions of Twiss (1976) or Goetze (1978). Instead, deformation is dominated by dislocation movement with recovery by dynamic recrystallization.     

Electronic structures of sulfide minerals — Theory and experiment

The sulfide minerals exhibit a rich diversity in sturctural chemistry and in electrical, magnetic and other physical properties. Models based on molecular orbital theory and incorporating some elements of band theory can be developed to describe the diverse valence electron behavior in these minerals. Qualitative models can be proposed on the basis of observed properties, and the models can be tested and refined using experimental data from X-ray emission and X-ray photoelectron spectroscopy and quantum mechanical calculations performed on cluster units which form the basic building blocks of the crystals. This approach to chemical bonding in sulfide minerals is illustrated for binary non-transition metal sulfides (ZnS, CdS, HgS, PbS), binary transition metal sulfides (FeS₂, CoS₂, NiS₂, CuS₂ ZnS₂) and more complex sulfides (CuFeS₂, Cu₂S, Ag₂S, CuS, Co₃S₄, CuCo₂S₄, Fe₃S₄). The relationship between qualitative and quantitative theories is reviewed with reference to the pyrite-marcasite-arsenopyrite-loellingite series of minerals. Application of the models to understanding structure-determining principles, relative stabilities, solid solution limits and properties such as color, reflectance and hardness are discussed.     

Geochemistry of the Sweetwater Wash Pluton,California: Implications for “anomalous” trace element behavior during differentiation of felsic magmas

Field relations, mineralogy and major and trace element data for the very felsic, peraluminous Sweetwater Wash pluton establish a differentiation sequence dominantly controlled by fractional crystallization processes. Elements Ba and Sr show depletion by factors of 50–60X from the earliest granite unit analyzed to the late-stage pegmatites and aplites. The strong Ba depletion is largely due to the partitioning behavior of this element in K-feldspar, while the Sr depletion is due to the combined effects of the two feldspars. The 4-fold increase in Rb during crystallization is also predictable from mineral/ melt partition coefficients.Coefficients for the light rare-earth elements (LREE) in major mineral species predict that these elements should behave incompatibly during crystallization and increase with fractionation. In fact, the LREE abundances decrease by a factor of 10–20X during crystallization. This anomalous behavior is commonly observed in felsic plutonic and volcanic sequences. In the Sweetwater Wash pluton monazite occurs in minute quantities, but it is sufficiently abundant to govern the partitioning of LREE and Th during crystallization. Petrographic observations indicate that monazite was on the liquidus throughout most of the crystallization. Analyses of silicate mineral separates suggest that the monazite contains more than 75% of the LREE in the whole rocks.Fractionation of REE-rich accessories (in particular monazite) from felsic magmas may be the general cause of REE depletion during differentiation of these melts. Monazite can easily be mistaken for zircon and, because it typically contains 50% LREE, extremely minute and easily overlooked quantities of monazite can control LREE abundances.     

Sociospatial aspects of Australian aboriginal underdevelopment. Empirical evidence from the East kimberley

Prior to the penetration of the European capitalist economy into central and northern Australia, the Aboriginal mode of production was one of hunting and gathering. Spiritual, economic and social relationships betwen people and land produced a spatial distribution of small bands of people living on their traditional lands. To the incoming white settlers the low population density and type of land use appeared uneconomic. This observation was used as ideological justification for the expropriation and development of the land for commercial pastoralism. This paper discusses the articulation of the Aboriginal and European modes of production in the East Kimberley region of northwest Australia. It argues that the introduced capitalist economy virtually destroyed the Aboriginal means of subsistence, incorporating Aborigines into the new mode of production within various subordinate roles. The exploitation of Aborigines, formerly as labour and now predominantely as consumers, is fundamental to the maintenance of the capitalist mode of production in pastoral areas. The spatial effects of the dominant mode of production have been to centralise Aborigines in locations suited to the various phases of development of the European economy, undermining the traditional Aboriginal social-spatial structure. The centralisation of the Aboriginal population also enhances the opportunities for the further development of the mining industry, which is in direct competition with Aboriginal interests in land. Aboriginal resistance to these spatial tendencies is intense in many quarters, but efforts to return to living on traditional lands and to develop alternative ways of living are hampered by the dominant mode of production.     

The age of carbonatites,kimberlites and lamprophyres from southern West Greenland: recurrent alkaline magmatism during 2500 million years

Alkaline rocks were intruded into the Precambrian basement in southern West Greenland during at least five separate episodes. The Tupertalik carbonatite intrusion was emplaced around or before 2650 m.y.; it is now metamorphosed in granulite facies but is recognisable by its trace element content. Lamprophyre dykes were intruded at ca. 1800 m.y. and again at ca. 1200 m.y. At ca. 600 m.y. the Sarfartôq carbonatite intrusion and extensive kimberlite dykes were emplaced in the Holsteiborg-Strømfjord region. At 225-115 m.y. the Qaqarssuk carbonatite complex was emplaced in the Sukkertoppen region, and numerous lamprophyre and kimberlite dykes were emplaced between Fishenasset and Ivigtut. All these episodes are correlatable with contemporaneous alkaline activity in Canada and Scandinavia and substantiate the periodicity of carbonatite emplacement. The Mesozoic suite of intrusions is related to rifting prior to continental break-up and the formation of the North Atlantic Ocean. The Eocambrian suite of 600 m.y. is thought to have formed under similar conditions during continental break-up and the formation of the Iapetus ocean.     

The detection of weathering in coal by petrographic,rheologic and chemical methods

This study examines petrographic, rheologic, proximate and ultimate analyses techniques, to investigate the effects of natural weathering on coal. The applicability of such tests to both the detection of weathering and to the prediction of the properties of a fresh coal, based upon analyses of a weathered sample, is discussed.Rheologic parameters and a petrographic staining technique showed the most sensitive response to weathering. The latter test is considered the most suitable of these for the detection of weathering, as it is independent of prior knowledge of the properties of the fresh coal and of the petrographic composition. A petrographic approach is also considered most suitable for estimation of fresh coal characteristics from weathered samples. Rank may be closely approximated and petrographic type determined microscopically, even on highly weathered samples, and these two parameters may be used to estimate properties such as volatile matter, calorific value and dilatation. Minor modification should be made to vitrinite reflectance measurements, according to the degree of weathering as revealed by selective staining.