Colloidal Stability and Toxicity of Gold Nanoparticles and Gold Chloride on <Emphasis Type="Italic">Chlamydomonas reinhardtii</Emphasis>

Here we have examined interactions of gold nanoparticles differing in primary particle size and coating with the green algae Chlamydomonas reinhardtii as function of the colloidal stability of the particles in the experimental media used for toxicity studies. Interactions of dissolved Au³⁺ ions with algae were also examined. Included endpoints were photosynthetic yield and algal growth. Morphological and structural effects were examined microscopically and by flow cytometry. The results indicate no significant toxicity of gold nanoparticles to C. reinhardtii. Analysis of published data suggests toxicity of gold nanoparticles on algal growth to relate rather to particular coatings than to the gold core.     

In situ yield behaviour of a coal pillar

Summary An indication of the complete stress-strain behaviour of coal was obtained through instrumenting a headgate yield pillar and monitoring the changes in vertical and horizontal pillar stress, pillar strain, and roof-floor convergence as a function of time and distance from the moving longwall face. A semiautomated monitoring program was conducted over a 5 month period as the longwall face advanced toward and eventually passed the instrumented pillar. The development of a confined core and yield zone within the pillar was confirmed by the vertical and horizontal stress changes. Thein situ pre-failure (208 to 661 MPa) and post-failure moduli (55 to 208 MPa) of the coal were determined from the change in pillar stress versus pillar strain. Thein situ moduli are an order of magnitude lower than the 3450 MPa, commonly assumed for coal.     

Aerodynamic Parameters of a UK City Derived from Morphological Data

Detailed three-dimensional building data and a morphometric model are used to estimate the aerodynamic roughness length z ₀ and displacement height d over a major UK city (Leeds). Firstly, using an adaptive grid, the city is divided into neighbourhood regions that are each of a relatively consistent geometry throughout. Secondly, for each neighbourhood, a number of geometric parameters are calculated. Finally, these are used as input into a morphometric model that considers the influence of height variability to predict aerodynamic roughness length and displacement height. Predictions are compared with estimations made using standard tables of aerodynamic parameters. The comparison suggests that the accuracy of plan-area-density based tables is likely to be limited, and that height-based tables of aerodynamic parameters may be more accurate for UK cities. The displacement heights in the standard tables are shown to be lower than the current predictions. The importance of geometric details in determining z ₀ and d is then explored. Height variability is observed to greatly increase the predicted values. However, building footprint shape only has a significant influence upon the predictions when height variability is not considered. Finally, we develop simple relations to quantify the influence of height variation upon predicted z ₀ and d via the standard deviation of building heights. The difference in these predictions compared to the more complex approach highlights the importance of considering the specific shape of the building-height distributions. Collectively, these results suggest that to accurately predict aerodynamic parameters of real urban areas, height variability must be considered in detail, but it may be acceptable to make simple assumptions about building layout and footprint shape.     

Summer temperature variability across four urban neighborhoods in Knoxville,Tennessee, USA

The urban heat island (UHI) is a well-documented effect of urbanization on local climate, identified by higher temperatures compared to surrounding areas, especially at night and during the warm season. The details of a UHI are city-specific, and microclimates may even exist within a given city. Thus, investigating the spatiotemporal variability of a city’s UHI is an ongoing and critical research need. We deploy ten weather stations across Knoxville, Tennessee, to analyze the city’s UHI and its differential impacts across urban neighborhoods: two each in four neighborhoods, one in more dense tree cover and one in less dense tree cover, and one each in downtown Knoxville and Ijams Nature Center that serve as control locations. Three months of temperature data (beginning 2 July 2014) are analyzed using paired-sample t tests and a three-way analysis of variance. Major findings include the following: (1) Within a given neighborhood, tree cover helps negate daytime heat (resulting in up to 1.19 ^°C lower maximum temperature), but does not have as large of an influence on minimum temperature; (2) largest temperature differences between neighborhoods occur during the day (0.38–1.16 ^°C difference), but larger differences between neighborhoods and the downtown control occur at night (1.04–1.88 ^°C difference); (3) presiding weather (i.e., air mass type) has a significant, consistent impact on the temperature in a given city, and lacks the differential impacts found at a larger-scale in previous studies; (4) distance from city center does not impact temperature as much as land use factors. This is a preliminary step towards informing local planning with a scientific understanding of how mitigation strategies may help minimize the UHI and reduce the effects of extreme weather on public health and well-being.     

Radiative Processes in the Stable Boundary Layer: Part I. Radiative Aspects

The structure of the radiatively dominated stable boundary layer is analysed using idealized calculations at high vertical and spectral resolution. The temperature profile of a nocturnal radiative boundary layer, developing after the evening transition, is found to be well described in terms of radiative cooling to the surface, although radiative exchanges within the atmosphere become increasingly important with time. The treatment of non-black surfaces is discussed in some detail and it is shown that the effect of reducing the surface emissivity is to decrease rather than to increase the radiative cooling rate in the surface layer. It is also argued that an accurate assessment of the impact of non-black surfaces requires careful attention to the spectral and directional characteristics of the surface emissivity. A polar nocturnal boundary layer, developing above snow-covered ground, is simulated and found to reach a slowly evolving state characterized by a strong radiative divergence near the surface that is comparable to observed values. Radiative boundary layers are characterized by large temperature gradients near the surface. An erratum to this article can be found at     

Origin of well-rounded gravels in glacial deposits from Brøggerhalvøya, northwest Spitsbergen: potential problems caused by sediment reworking in the glacial environment

Well-rounded gravels are described from moraine-mound complexes, diamicton forefields and modern englacial thrusts at the margins of four glaciers on the northern side of Brøggerhalvøya, northwest Spitsbergen. Their shape charcteristics are compared with modern and fossil glacigenic, modern beach and Early Weichselian beach gravels from this peninsula. The best discriminators of the well-rounded gravels have been found to be the percentage-frequency roundness histograms, the roundness mid-point and roundness range diagrams and the sphericity-roundness plots. It is concluded that the gravels have been derived by englacial thrusting from Early Weichselian or last interglacial beaches in the inner parts of the fjord and in the low level cirques when sea level reached at least 50m a.s.l. and deposited the beach gravels. The discrimination between gravel in basal diamictons, proglacial outwash and modern beaches is difficult as the reworking has resulted in little particle shape change. The potential major problem caused by reworking in the glacial environment is emphasised. especially when clast shape comparisons from modern environments to older sediments are used.     

MODELING HEADCUT DEVELOPMENT AND MIGRATION IN UPLAND CONCENTRATED FLOWS

On hillslopes and agricultural fields, discrete areas of intense, localized soil erosion commonly take place in the form of migrating headcuts. These erosional features significantly increase soil loss and landscape degradation, yet the unsteady, transient, and migratory habits of headcuts complicate their phenomenological and erosional characterization. Here a unique experimental facility was constructed to examine actively migrating headcuts typical of upland concentrated flows. Essential components of the facility include a deep soil cavity with external drainage, rainfall simulator, capacity for overland flow, and a video recording technique for data collection. Results from these experiments show that： （1） after a short period of adjustment, headcut migration attained a steady-state condition, where the rate of migration, scour hole geometry, and sediment discharge remain constant with time; （2） boundary conditions of higher rates of overland flow, steeper bed slopes, and larger initial headcut heights produced systematically larger scour holes with higher rates of soil erosion; and （3） during migration, the turbulent flow structure within the scour hole remained unchanged, consisting of an overfall nappe at the brink transitioning into a reattached wall jet with two recirculation eddies within the plunge pool. The systematic behavior of headcut development and migration enabled the application of modified jet impingement theory to predict with good success the characteristics of the impinging jet, the depth of maximum scour, the rate of headcut migration, and the rate of sediment erosion. These laboratory data and the analytical formulation can be used in conjunction with soil erosion prediction technology to improve the management of agricultural areas impacted by headcut development and ephemeral gully erosion.