Net autotrophy in a fluvial lake: the relative role of phytoplankton and floating-leaved macrophytes

This study combined water- and sediment flux measurements with mass balances of dissolved gas and inorganic matter to determine the importance of pelagic and benthic processes for whole-system metabolism in a eutrophic fluvial lake. Mass balances of dissolved O₂, inorganic carbon (DIC), nitrogen (DIN), phosphorous (SRP), particulate N (PN) and P (PP) and Chl a were calculated at a nearly monthly frequency by means of repeated sampling at the lake inlet and outlet. Simultaneously, benthic fluxes of gas and nutrients, including denitrification rates, and the biomass of the dominant pleustophyte (Trapa natans) were measured, and fluxes of O₂ and CO₂ across the water–atmosphere interface were estimated from diel changes in outlet concentrations. On an annual scale, Middle Lake exhibited CO₂ supersaturation, averaging 313% (range 86–562%), but was autotrophic with a net O₂ production (6.35 ± 2.05 mol m⁻² y⁻¹), DIC consumption (−31.18 ± 18.77 mol m⁻² y⁻¹) and net export of Chl a downstream (8.38 ± 0.95 mol C m⁻² y⁻¹). Phytoplankton was the main driver of Middle Lake metabolism, with a net primary production estimated at 33.24 mol O₂ m⁻² y⁻¹, corresponding to a sequestration of 4.18 and 0.26 mol m⁻² y⁻¹ of N and P, respectively. At peak biomass, T. natans covered about 18% of Middle Lake’s surface and fixed 2.46, 0.17 and 0.02 mol m⁻² of C, N and P, respectively. Surficial sediments were a sink for O₂ (−14.47 ± 0.65 mol O₂ m⁻² y⁻¹) and a source of DIC and NH₄ ⁺ (18.84 ± 2.80 mol DIC m⁻² y⁻¹ and 0.83 ± 0.16 mol NH₄ ⁺ m⁻² y⁻¹), and dissipated nitrate via denitrification (1.44 ± 0.11 mol NO₃ ⁻ m⁻² y⁻¹). Overall, nutrient uptake by primary producers and regeneration from sediments were a minor fraction of external loads. This work suggests that the creation of fluvial lakes can produce net autotrophic systems, with elevated rates of phytoplanktonic primary production, largely sustained by allochtonous nutrient inputs. These hypereutrophic aquatic bodies are net C sinks, although they simultaneously release CO₂ to the atmosphere.     

Study of the macrophyte assemblages and application of phytobenthic indices to assess the Ecological Status of the Marano‐Grado Lagoon (Italy)

Benthic macrophytes from 19 sites within the Marano‐Grado Lagoon were sampled in July 2007 in order to update the available information on the flora and vegetation and to assess the Ecological Status (ES) within the European Water Framework Directive (WFD). Data on macrophytes were analysed using two phytobenthic indices (EEI and R‐MaQI) recently set up to evaluate the ecological status of transitional environments in the Mediterranean eco‐region. Notwithstanding the extension (c. 160 km²) that places this lagoon as the second largest Italian transitional environment, ecological studies are relatively few. The present research revealed a relatively poor flora, mainly characterized by the dominance of low‐diversity settlements of Ulvaceae. Moreover, the absence of intensive aquaculture activities and commercial big harbours, which account for the new species introductions recorded in other lagoons, limits the presence of non‐autochthonous species. The comparison with previous data ( Curiel et al. 1998 ) highlighted the reduction of macrophyte coverage and biomass, especially Ulvaceae stands, and an increase in species richness. In particular, there was evidence of a worsening of the area north of the Grado bridge. This area, which in the past was colonized by widespread angiosperm coverage, at present is almost lacking in vegetation. According to these observations, by applying both the phytobenthic indices available in the literature for the transitional environments, the Marano‐Grado Lagoon showed a ‘Good–High’ quality in the central part of the basin and near the lagoon inlets and a ‘Poor–Bad’ quality in the northern and southern areas. The evaluation of some physico‐chemical parameters, coupled with the distribution of the angiosperms, also allowed a first delineation of the main lagoon water bodies.     

Dripping into unsaturated rock underground excavations—literature review and geologic and hydrogeologic setting description

A literature review of dripping in underground constructions in deep, unsaturated geologic media was performed as part of a phased study. The objective is to develop and test a formulation that can be used for studying unsaturated flow through rough multi-segmented fractures, with emphasis on predicting dripping initiation time. Geologic and hydrogeologic setting for the Yucca Mountain (YM) and its exploratory studies facility, which is the site where the model will be tested, are described.     

Initial orbit determination using multiple observations

A novel approach for initial orbit determination based on multiple angles-only observations is presented. The proposed technique is iterative and uses Lagrangian coefficients, f and g. The proposed method does not show singularity for the coplanar cases. In addition, the method is capable of handling multiple observations, providing higher accuracy, whereas the level of the algorithm complexity and processor running time remain almost invariant. The technique presented is compared with the Double r-iteration and Gauss’ methods using data corrupted by noise to simulate true measurements. Results show that the proposed method is a valid alternative to the classical methods of orbit determination.     

Potentially modified hydropower production under climate change in the Italian Alps

We present an assessment of the potential impacts of climate change on hydropower production within a paradigmatic, very highly exploited cryospheric area of upper Valtellina valley in the Italian Alps. Based on dependable and unique hydrological measures from our high‐altitude hydrometric network Idrostelvio during 2006–2015, we set up the Poly‐Hydro model to mimic the cryospheric processes driving hydrological flow formation in this high‐altitude area. We then set up an optimization tool, which we call Poly‐Power, to maximize the revenue of the plant manager under given hydrological regimes, namely, by proper operation of the hydroelectric production scheme (reservoirs, pipelines, and power plants) of the area. We then pursue hydrological projections until 2100, feeding Poly‐Hydro with the downscaled outputs of three general circulation models from the Intergovernmental Panel on Climate Change Fifth Assessment Report, under the scenarios Representative Concentration Pathway (RCP) 2.6, RCP 4.5, and RCP 8.5. We assess hydrological flows in two reference decades, that is, at half century (2040–2049), and end of century (2090–2099). We then feed the so obtained hydrological scenarios as inputs to Poly‐Power, and we project future production of hydroelectric power, with and without reoperation of the system. The average annual stream flows for hydropower production decreases along the century under our scenarios (?21 to +7%, on average ? 5% at half century; ?17 to ?2%, average ? 8%, end of century), with ice cover melting unable to offset such decrease. Reduction in snowfall and increase in liquid rainfall are the main factors affecting the modified hydrological regime. Energy production (and revenues) at half century may increase under our scenarios (?9 to +15%, +3% on average). At the end of century in spite of a projected increase on average (?7 to +6%, +1% on average), under the warmest scenario RCP 8.5 decrease of energy production is consistently projected (?4% on average). Our results provide an array of potential scenarios of modified hydropower production under future climate change and may be used for brain storming of adaptation strategies.     

High-temperature vesuvianite: crystal chemistry and surface considerations

A multi-methodical approach has been applied for characterizing the bulk and surface crystal chemical features of a high-temperature vesuvianite crystal from skarns of Mount Somma-Vesuvius Volcano (Naples, Italy). Vesuvianite belongs to the space group P4/nnc with unit cell parameters a = 15.633(1) Å, c = 11.834(1) Å and chemical formula (Ca_18.858 Na_0.028 Ba_0.004 K_0.006 Sr_0.005 □_0.098)_19.000 (Al_8.813 Ti_0.037 Mg_2.954 Mn_0.008 Fe_0.114²⁺ Fe_1.375³⁺ Cr_0.008 B_0.202)_13.511 Si_18.000(O_0.261 F_0.940 OH_7.799)_9.000. Structure refinement, which converges at R = 0.0328, demonstrates a strong positional disorder down the fourfold axes, indicating that the Y1 site is split into two positions (Y1A and Y1B) alternatively occupied. However, because of X4 proximity to Y1B and Y1A, X4 cannot be occupied if Y1B or Y1A are. Overall Y1 occupancy (Y1A + Y1B) reaches approximately 0.5, as common in vesuvianite and occupancy of Y1B site is extremely limited. Moreover, T1 position, limitedly occupied, accommodates the excess of cations generally related to Y position. A small quantity (0.202 apfu) of boron is sited at the T2 site that, like T1, is poorly occupied. The determination of the amount of each element on the (100) vesuvianite surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si_2p, Al_2p, Mg_1s, and Ca_2p core levels, evidences that a greater amount of aluminum and a smaller amount of calcium characterize the surface with respect to the bulk. Although both of these features require further investigation, we may consider the Al increase can be related to preferential orientation of Al-rich sites on the (100) plane. Furthermore, the surface structure of vesuvianite suggests that Al, Ca, and Mg cations maintain coordination features at the surface similar to the bulk. Silica, however, while presenting fourfold coordination, shows also a [1]-fold small coordinated component at binding energy 99.85 eV, due to broken Si–O bonds at the surface. The presence of eight- and nine-coordinated Ca cations is suggested by a large XPS feature resulting from the merging of Ca_2p3/2 and Ca_2p1/2 peaks at 348.45 and 352.05 eV, respectively.     

Upper Pleistocene tectonics in western Sardinia (Italy): Insights from the Sinis peninsula structural high

The Corsica‐Sardinia block is a lithospheric fragment whose recent role in the geodynamics of the central‐Western Mediterranean basin is still enigmatic. The most recent regional structure in Sardinia is the Plio‐Pleistocene Campidano Basin, which is considered in a ‘post‐rift’ stage since the Middle Pleistocene. New structural and stratigraphic geological surveys along with luminescence ages provide evidence to support an ongoing tectonic activity since the Marine Isotopic Stage 7 (MIS7; ca. 220 ka) on the Sinis peninsula, the structural high that bounds the north‐western side of the Campidano Basin. In particular, this paper reveals for the first time the presence of N–S striking normal faults system offsetting late Pleistocene aeolianites (130 ± 12 ka; 82 ± 9 ka).     

Holocene vegetation and fire dynamics in the supra‐mediterranean belt of the Nebrodi Mountains (Sicily,Italy)

High‐resolution pollen, macrofossil and charcoal data, combined with accelerator mass spectrometry ¹⁴C dating and multivariate analysis, were used to reconstruct Holocene vegetation and fire dynamics at Urio Quattrocchi, a small lake in the supra‐mediterranean belt in the Nebrodi Mountains of Sicily (Italy). The data suggest that after 10 000 cal a BP increasing moisture availability supported closed forests with deciduous (Quercus cerris, Fagus sylvatica and Fraxinus spp.) and evergreen (Quercus ilex) species. Species‐rich closed forest persisted until 6850 cal a BP, when Neolithic activities caused a forest decline and affected plant diversity. Secondary forest with abundant Ilex aquifolium recovered between 6650 and 6000 cal a BP, indicating moist conditions. From 5000 cal a BP, agriculture and pastoralism led to the currently fragmented landscape with sparse deciduous forests (Quercus cerris). The study suggests that evergreen broadleaved species were more important at elevations above 1000 m a.s.l. before ca. 5000 cal a BP than subsequently, which might reflect less human impact or warmer‐than‐today climatic conditions between 10 000 and 5000 cal a BP. Despite land use since Neolithic times, deciduous supra‐mediterranean forests were never completely displaced from the Nebrodi Mountains, because of favourable moist conditions that persisted throughout the Holocene. Reconstructed vegetation dynamics document the absence of any pronounced mid‐ or late‐Holocene ‘aridification’ trend at the site, an issue which is controversially debated in Italy and the Mediterranean region. Copyright © 2012 John Wiley & Sons, Ltd.