Diatom response to mid-Holocene climate change in Lago di Massaciuccoli (Tuscany,Italy)

A sedimentary sequence from the Mediterranean coastal basin of Lago di Massaciuccoli (Tuscany, Italy) was analyzed for diatoms, covering two periods over the past ca. 7,000 years. The site was selected because it is situated in a sensitive position at the limit between Mediterranean and Central European climates and biomes. Our focus is on the impact of accelerated human activity during the recent past (water uptake in the catchment, sand extraction, wastewater discharge) and on a phase of evident change between 6,600 and 5,400 cal. BP. The diatom record suggests fresh-water conditions and rather high lake levels until ca. 6,000 years ago. The subsequent shift towards brackish conditions peaked at around 5,500 cal. BP. We relate this shift to a pervasive change towards a drier climate that has been observed elsewhere in the Mediterranean and Northern African regions, and stands in contrast to the shift towards a cooler and more humid climate in the nearby Alps (200–350 km distant) and in central Europe. Pollen and charcoal records from a previous study on the same sedimentary sequence were used to gain additional insights about the causes of the changes in the diatom assemblages and apply numerical methods to search for common trends and correlations.     

Metamorphic CO2 production from calc-silicate rocks via garnet-forming reactions in the CFAS–H2O–CO2 system

The type and kinetics of metamorphic CO₂-producing processes in metacarbonate rocks is of importance to understand the nature and magnitude of orogenic CO₂ cycle. This paper focuses on CO₂ production by garnet-forming reactions occurring in calc-silicate rocks. Phase equilibria in the CaO–FeO–Al₂O₃–SiO₂–CO₂–H₂O (CFAS–CO₂–H₂O) system are investigated using P–T phase diagrams at fixed fluid composition, isobaric T–X(CO₂) phase diagram sections and phase diagram projections in which fluid composition is unconstrained. The relevance of the CFAS–CO₂–H₂O garnet-bearing equilibria during metamorphic evolution of calc-silicate rocks is discussed in the light of the observed microstructures and measured mineral compositions in two representative samples of calc-silicate rocks from eastern Nepal Himalaya. The results of this study demonstrate that calc-silicate rocks may act as a significant CO₂ source during prograde heating and/or early decompression. However, if the system remains closed, fluid–rock interactions may induce hydration of the calc-silicate assemblages and the in situ precipitation of graphite. The interplay between these two contrasting processes (production of CO₂-rich fluids vs. carbon sequestration through graphite precipitation) must be considered when dealing with a global estimate of the role exerted by decarbonation processes on the orogenic CO₂ cycle.     

Effect of cross‐section interpolated bathymetry on 2D hydrodynamic model results in a large river

Two‐dimensional (2D) hydrodynamic models have been increasingly used to quantify aquatic habitat and stream processes, such as sediment transport, streambed morphological evolution, and inundation extents. Because river topography has a strong influence on predicted hydraulic conditions, 2D models require accurate and detailed bathymetric data of the stream channel and surrounding floodplains. Besides collection of mass points to construct high‐resolution three‐dimensional surfaces, bathymetries may be interpolated from cross‐sections. However, limited information is available on the effects of cross‐section spacing and the derived interpolated bathymetry on 2D model results in large river systems. Here, we investigated the effects of cross‐section spacing on flow properties simulated with 2D modeling at low, medium and high discharges in two morphologically different reaches, a simple (almost featureless with low sinuosity) and a complex (presenting pools, riffles, runs, contractions and expansions) reach of the Snake River (Idaho, USA), the tenth largest river in the United States in terms of drainage area. We compared the results from 2D models developed with complete channel bathymetry acquired with multibeam sonar data and photogrammetry, with 2D model results that were developed using interpolated topography from uniformly distributed transects. Results indicate that cross‐sections spaced equal to or greater than 2 times the average channel width (W*) smooths the bathymetry and suppresses flow structures. Conversely, models generated with cross‐sections spaced at 0.5 and 1 W* have stream flow properties, sediment mobility and spatial habitat distribution similar to those of the complete bathymetry. Furthermore, differences in flow properties between interpolated and complete topography models generally increase with discharge and with channel complexity. Copyright © 2013 John Wiley & Sons, Ltd.     

Formal proposal for the Bathonian GSSP (Middle Jurassic) in the Ravin du Bès Section (Bas-Auran, SE France)

The Bathonian Global Stratotype Section and Point (GSSP) is proposed at the base of limestone bed RB071 (bed 23 in Sturani 1967) in the Ravin du Bès Section (43° 57′ 38′′ N, 6° 18′ 55′′ E), Bas-Auran area, “Alpes de Haute Provence” French department. The Ravin du Bès Section, as formal candidate GSSP for the base of the Bathonian Stage, satisfies most of the requirements recommended by the International Commission on Stratigraphy: 1) The exposure extends over 13 m in thickness. At the Bajocian-Bathonian transition, no vertical (bio-, ichno- or tapho-) facies changes, condensation, stratigraphic gaps or hiatuses have been recorded. Structural complexity, synsedimentary and tectonic disturbances, or important alterations by metamorphism are not relevant constraints. 2) There is a well-preserved, abundant and diverse fossil record across the boundary interval, with key markers (ammonites and nannofossils) for worldwide correlation. The base of the Bathonian Stage and Zigzag Zone in Bas-Auran corresponds to the first occurrence level of Gonolkites convergens Buckman, which coincides with the first occurrence of Morphoceras parvum Wetzel. Calcareous nannofossils, as secondary global marker, are present in all beds and allow characterizing the Bajocian-Bathonian transition. 3) Regional analyses of sequence stratigraphy and manganese chemostratigraphy are available. Spectral gamma-ray data corroborate an Early Bathonian deepening half-cycle of second order. 4) The criteria of accessibility, conservation and protection are assured by the “Réserve Naturelle Géologique de Haute Provence”. The Cabo Mondego Section (Portugal) is suggested as the Bathonian auxiliary section and point (ASSP) within this GSSP proposal.     

Identifying run‐off contributions during melt‐induced run‐off events in a glacierized alpine catchment

We analysed contributions to run‐off using hourly stream water samples from seven individual melt‐induced run‐off events (plus one rainfall event) during 2011, 2012 and 2013 in two nested glacierized catchments in the Eastern Italian Alps. Electrical conductivity and stable isotopes of water were used for mixing analysis and two‐component and three‐component hydrograph separation. High‐elevation snowmelt, glacier melt and autumn groundwater were identified as major end‐members. Discharge and tracers in the stream followed the diurnal variations of air temperature but markedly reacted to rainfall inputs. Hysteresis patterns between discharge and electrical conductivity during the melt‐induced run‐off events revealed contrasting loop directions at the two monitored stream sections. Snowmelt contribution to run‐off was highest in June and July (up to 33%), whereas the maximum contribution of glacier melt was reached in August (up to 65%). The maximum groundwater and rainfall contributions were 62% and 11%, respectively. Run‐off events were generally characterized by decreasing snowmelt and increasing glacier melt fractions from the beginning to the end of the summer 2012, while run‐off events in 2013 showed less variable snowmelt and lower glacier melt contributions than in 2012. The results provided essential insights into the complex dynamics of melt‐induced run‐off events and may be of further use in the context of water resource management in alpine catchments. Copyright © 2015 John Wiley & Sons, Ltd.     

Observations of Atmospheric Solitary Waves in the Urban Boundary Layer

The simultaneous operation of a three-axis Doppler sodar system in the centralurban area of Rome and two similar systems in the suburban area, forming atriangle about 20 km on each side, provided evidence of solitary-type wavesin the urban boundary layer. Three events, each lasting from a few minutes toabout 30 min, and ranging in depth from the minimum range of the sodar (39 m) to over 500 m, are reported here. Two events were recognizable onall three sodar records while the third event could be observed at the urbanlocation only. Time-height acoustic echo intensity records showed no-echoregions within the wave indicating transport of trapped recirculating air.This is typical of large amplitude solitary waves. The time series plots ofsodar-derived vertical wind velocity revealed a maximum peak-to-peakvariation of about 5 m s^-1 during periods of wave-associated disturbance.The vertical velocity is found to increase with height up to the top of the closedcirculation within the wave and decreases further above. The normalisedamplitude-wavelength relationship for the two events indicates that theobserved waves are close to a strongly nonlinear regime.     

Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino-silicate glasses

The development of an accurate analytical procedure for determination of dissolved water in complex alumino-silicate glasses via micro-Raman analysis requires the assessment of the spectra topology dependence on glass composition. We report here a detailed study of the respective influence of bulk composition, iron oxidation state and total water content on the absolute and relative intensities of the main Raman bands related to glass network vibrations (LF: ∼490 cm⁻¹; HF: ∼960 cm⁻¹) and total water stretching (H₂O_T: ∼3550 cm⁻¹) in natural glasses. The evolution of spectra topology was examined in (i) 33 anhydrous glasses produced by the re-melting of natural rock samples, which span a very large range of polymerisation degree (NBO/T from 0.00 to 1.16), (ii) 2 sets of synthetic anhydrous basaltic glasses with variable iron oxidation state (Fe³⁺/Fe_T from 0.05 to 0.87), and (iii) 6 sets of natural hydrous glasses (C_H2OT from 0.4 to 7.0 wt%) with NBO/T varying from 0.01 to 0.76.In the explored domain of water concentration, external calibration procedure based on the H₂O_T band height is matrix-independent but its accuracy relies on precise control of the focusing depth and beam energy on the sample. Matrix-dependence strongly affects the internal calibrations based on H₂O_T height scaled to that of LF or HF bands but its effect decreases from acid (low NBO/T, SM) to basic (high NBO/T, SM) glasses. Structural parameters such as NBO/T (non-bridging oxygen per tetrahedron) and SM (sum of structural modifiers) describe the matrix-dependence better than simple compositional parameters (e.g. SiO₂, Na₂O + K₂O). Iron oxidation state has only a minor influence on band topology in basalts and is thus not expected to significantly affect the Raman determinations of water in mafic (e.g. low SiO₂, iron-rich) glasses. Modelling the evolution of the relative band height with polymerisation degree allows us to propose a general equation to predict the dissolved water content in natural glasses:

     

Historical geospatial database for landslide analysis: the Catalogue of Landslide OCcurrences in the Emilia-Romagna Region (CLOCkER)

A review of the content, structure, accuracy, and completeness of the Catalogue of Landslide OCcurrences in the Emilia-Romagna Region (CLOCkER) is presented. CLOCkER is a historical database, designed and developed for all types of landslides in the hilly-mountain area of the Emilia-Romagna section of the Northern Italian Apennines. Historical data have been gathered through a collection of numerous sources, including technical reports, historical archives, scientific literature, and newspapers. The information obtained, which has been evaluated to assess its temporal precision and spatial accuracy, has been recorded in a catalogue consisting of a Database Management System (DBMS) linked to a geographical information system (GIS) interface. The catalogue presently includes 14,416 records of documented landslide occurrences, dating from Middle Ages up to the present. The catalogue is associated with a landslide inventory, continuously updated by the Geological Survey of the Emilia-Romagna Region, where information on the shape, typology, and state of activity of more than 80,000 landslides is included. Our assessment of catalogue quality reveals a satisfactory spatial accuracy and a level of completeness comparable with the theoretical target proposed in the literature for complete inventories. Outputs indicate that CLOCkER can be a reference example useful for other regional historical landslide catalogues. Such reference datasets are useful for a wide range of landslide assessment purposes and can provide practical assistance for stakeholders involved in both scientific and technical fields, forming the basis for landslide temporal trend reconstruction that is essential for landslide hazard evaluation at different spatial-temporal scales. CLOCkER is open access, freely available online.     

Elastic model for the gravity and elevation changes before the 2001 eruption of Etna volcano

For 5 months before the 2001 Mt. Etna eruption, a progressive gravity decrease was measured along a profile of stations on the southern slope of the volcano. Between January and July 2001, the amplitude of the change reached 80 μGal, while the wavelength of the anomaly was of the order of 15 km. Elevation changes observed through GPS measurements during a period encompassing the 5-month gravity decrease, remained within 4–6 cm over the entire volcano and within 2–4 cm in the zone covered by the microgravity profile. We review both gravity and elevation changes by a model assuming the formation of new cracks, uniformly distributed in a rectangular prism. The inversion problem was formulated following a global optimization approach based on the use of Genetic Algorithms. Although it is possible to explain the observed gravity changes by means of the proposed analytical formulation, the results show that calculated elevation changes are significantly higher than those observed. Two alternative hypotheses are proposed to account for this apparent discrepancy: (1) that the assumptions behind the analytical formulation, used to invert the data, are fallacious at Etna, and thus, numerical models should be utilized; (2) that a second process, enabling a considerable mass decrease to occur without deformation, acted together with the formation of new cracks in the source volume.