Giant gas bubbles in a rheomorphic vent fill at the Las Cañadas caldera,Tenerife (Canary Islands)

During rheomorphism subsequent to fallout deposition, a portion of the densely welded fallout of the La Grieta Member flowed back into the vent from where it was erupted, while the rest of it flowed down the outer slopes of the Las Cañadas caldera in Tenerife. The welded fallout and conduit-vent structure are physically connected and constitute a rare example of this type of deposits rooted to its feeder conduit and exposed in the caldera wall. The lower part of the vent-filling rheomorphic rocks shows gas bubbles and cavities that increase in size (up to 4 m) down vent. Bubbles are deformed against other bubbles, against the steep vent walls, flattened parallel to the flow foliation planes, and elongated parallel to the flow lineation and flow fold axes. The preservation of such giant bubbles, rather than their formation, seems to be a pretty unique feature of the phonolitic products investigated here and it is likely the result of the combination of factors that acted to preserve, in the surrounding of the glass transition interval, the sealing and the late stage cooling of a pressurized system. In addition, strain drop at the base of the vent-filling rheomorphic flow caused by flow stopping against vertical vent walls may have promoted rapid gas exsolution and the formation of large bubbles.     

Physical infrastructure interdependency and regional resilience index after the 2011 Tohoku Earthquake in Japan

A resilience index is used to quantify preventive measures, emergency measures, and restoration measures of complex systems, such as physical infrastructures, when they are subjected to natural disasters like earthquakes, hurricanes, floods, etc. Interdependencies among these systems can generate cascading failures or amplification effects, which can also affect the restoration measures right after an extreme event and generate a reduction of the resilience index. In this article, a method is proposed to evaluate the physical infrastructure resilience of a region affected by a disaster considering infrastructure interdependency. It is illustrated using available restoration curves from the March 11 2011 Tohoku Earthquake in Japan. The weights assigned to each infrastructure, which are used to determine resilience, are evaluated using the degree of interdependency indices which are obtain by time series analysis. Results show that the weight coefficients thus obtained do not influence the resilience index significantly; however, the methodology proposed is unbiased from subjective judgment and is able to identify the critical lifelines. Furthermore, the results of the case study presented here suggest that to obtain meaningful estimation of the weight coefficients, it is necessary to consider the period range between two perturbations (e.g., main shock and aftershock). Future infrastructure disruption data (from this and other earthquakes) would be needed to generalize this finding that will allow also to quantify the changes in the restoration curves caused by the magnitude and distance of the shocks from the epicenter, as well as the intrinsic properties of the physical infrastructures. Copyright © 2014 John Wiley & Sons, Ltd.     

Sand transport measurements in Chioggia inlet,Venice lagoon: Theory versus observations

This paper presents results of recent measurements of sand transport made in Chioggia inlet as part of an extensive monitoring programme in the Venetian inlets. Measurements were made in order: (1) to define a relationship between sand transport magnitude and tidal flow; (2) to derive the thresholds for sand transport; (3) to identify the dominant modes of transport; (4) to evaluate the concentration profiles of sand within the benthic boundary layer; (5) to compare bedload transport observations with model predictions using existent bedload formulae; and (6) to produce yearly estimates of bedload transport across the inlet. The vertical distribution of sand in the water column was sampled using modified Helley–Smith bedload samplers at three sites. Transport was found to vary according to the flow and bed grain size, with considerable temporal and spatial variability. A difference of up to three orders of magnitude in transport was observed through the inlet, with higher transport rates measured on the seaward part. The dominant mode of transport in the central inlet was suspension, while bedload was dominant in the mouths. The measured profiles of sand concentration varied with the tidal stage and seabed grain size according to the Rouse parameter (R). R was high at the inlet mouths (1<R<2), indicative of a well-developed bedload layer. The inverse movability number (W_s/U_*) was also higher at these sites and appeared to be grain size dependant. Formulae for bedload transport were tested against field data; stochastic methods such as Einstein–Brown, Engelund–Hansen and Van Rijn produce the best fits. The coupled model SHYFEM-Sedtrans05 appears to simulate well observed transport for most conditions of flow. Long-term bedload predictions indicate a dominant export of sand, with a yearly average of 4500 m³.     

Effects of pore-scale dispersion,degree of heterogeneity,sampling size,and source volume on the concentration moments of conservative solutes in heterogeneous formations

Pore-scale dispersion (PSD), aquifer heterogeneity, sampling volume, and source size influence solute concentrations of conservative tracers transported in heterogeneous porous formations. In this work, we developed a new set of analytical solutions for the concentration ensemble mean, variance, and coefficient of variation (CV), which consider the effects of all these factors. We developed these models as generalizations of the first-order solutions in the log-conductivity variance of point concentration proposed by [Fiori A, Dagan G. Concentration fluctuations in aquifer transport: a rigorous first-order solution and applications. J Contam Hydrol 2000;45(1–2):139–163]. Our first-order solutions compare well with numerical simulations for small and moderate formation heterogeneity and from small to large sampling and source volumes. However, their performance deteriorates for highly heterogeneous formations. Successively, we used our models to study the interplay among sampler size, source volume, and PSD. Our analysis shows a complex and important interaction among these factors. Additionally, we show that the relative importance of these factors is also a function of plume age, of aquifer heterogeneity, and of the measurement location with respect to the mean plume center of gravity. We found that the concentration moments are chiefly controlled by the sampling volume with pore-scale dispersion playing a minor role at short times and for small source volumes. However, the effect of the source volume cannot be neglected when it is larger than the sampling volume. A different behavior occurs for long periods, which may be relevant for old contaminations, or for small injection volumes. In these cases, PSD causes a significant dilution, which is reflected in the concentration statistics. Additionally, at the center of the mean plume, where high concentrations are most likely to occur, we found that sampling volume and PSD are attenuating mechanisms for both concentration ensemble mean and coefficient of variation, except at very large source and sampler sizes, where the coefficient of variation increases with sampler size and PSD. Formation heterogeneity causes a faster reduction of the ensemble mean concentrations and a larger uncertainty at the center of the mean plume. Therefore, our results highlight the importance of considering the combined effect of formation heterogeneity, exposure volume, PSD, source size, and measurement location in performing risk assessment.     

Subsurface mass redistributions at Mount Etna (Italy) during the 1995–1996 explosive activity detected by microgravity studies

Gravity changes are presented from a series of field microgravity surveys conducted at Mt Etna between August 1994 and November 1996, a period including the 1995–1996 explosive summit activity. Data were collected along a microgravity network of 69 stations at a monthly to annual sampling rate, depending on each subarray of the network.
  Results show that seasonal changes in water level within the volcano may induce gravity changes of up to 20  μgal on Etna's southern slope, and indicate that significant magma movement occurred within and below Etna's edifice between 1994 and 1996. In particular, between September 1994 and October 1995, a mass increase of 2 × 10¹⁰  kg occurred 2000  m beneath the summit craters. Between October 1995 and July 1996 this mass was lost, while another 2 × 10¹⁰  kg was injected at about 1000  m  a.s.l. into the 1989 fracture system. From the gravity data alone, it is not possible to distinguish whether the first shallow intrusion (1994–1995) was then injected laterally into the 1989 fracture, or summit activity was fed by the first shallow intrusion, while new magma entered the 1989 fracture system.
  While magma was being redistributed within the volcanic edifice, measurements along an E–W-trending profile on the southern slope of the volcano detected some 1.5 × 10¹¹  kg of magma accumulating 2–3  km below sea level between October 1995 and November 1996.     

Rotating magnetopolytropes: spherical figures of equilibrium due to balance of magnetic field and rotation

In this paper we compute spherical figures of equilibrium resulting from the balance of toroidal magnetic field and rotation. These two distortion effects are assumed to act on rotating magneto-polytropic constant-mass sequences, that is, sequences with each of their members having mass constant and equal to that of the corresponding nondistorted model.     

Transformations of Benzene Photoinduced by Nitrate Salts and Iron Oxide

This paper reports the results of a study on the transformation of benzene in the presence of solid nitrate salts (NaNO₃, NH₄NO₃) under irradiation in a gas-solid photoreactor. Sodium and ammonium nitrate have been chosen as representative of the composition of atmospheric particulate, benzene as a model aromatic molecule. The purpose is to simulate the transformations that aromatic compounds undergo on the surface of dispersed particles in the atmosphere. Irradiation of sodium nitrate causes hydroxylation and nitration of benzene, yielding phenol and nitrobenzene. This is most likely due to the generation of ^•OH and ^•NO₂ radicals upon nitrate photolysis, with ^•OH + O₂ leading to the formation of phenol and ^•OH + ^•NO₂ yielding nitrobenzene. The percentage of oxygen in the reaction environment influences the transformation pathways, with phenol formation being favoured and nitrobenzene formation depressed by high O₂ concentration. In the presence of hematite (α-Fe₂O₃, another component of atmospheric particulate) very relevant formation of nitrobenzene takes place even with 21% oxygen (simulated air), indicating that the interaction between hematite and nitrate can lead to the formation of aromatic nitroderivatives on the surface of atmospheric particulate. The effect of hematite is possibly due to protonation of peroxynitrite, formed upon nitrate photoisomerisation, to peroxynitrous acid, a powerful nitrating agent. A similar effect leads to relevant formation of nitrobenzene under atmospheric conditions upon irradiation of the acid salt ammonium nitrate.     

Pretunnel technology: applications and design methods

The Pretunnel technology allows the final or preliminary lining to be built ahead of a tunnel face. The paper shows how this technology has been used for mechanizing the full-face excavation of large tunnels in difficult ground conditions with minimum settlements. Analytical methods are presented for the analysis of the lining both in deep and shallow applications. Fields of applicability are established using results of parametric studies based on the methods proposed.     

Chemical speciation of arsenic in different marine organisms: Importance in monitoring studies

Arsenic is a widely distributed element in the marine environment. Inorganic and organic compounds have extremely different toxicological effects, and their characterization is thus of great utility when monitoring and assessing the impact of arsenic pollution. In this study both the levels of total arsenic and its chemical speciation were analyzed in several marine organisms collected from Cienfuegos Bay (Cuba) following an episode of acute As-contamination. Fish from the more impacted site were characterized by elevated concentrations of arsenic (up to 500 microg/g d.w.) and inorganic species represented the predominant forms in muscle tissues of these organisms.