用于新生代定年的Ar-Ar法标准样品候选样品初测结果

Ar Ar法定年的特点是必须要有一套年龄从小到大的标准样。迄今用于新生代定年的国内标准样极少。为满足新生代矿物Ar Ar法定年的需要,初选了一个标准样候选者BT 1透长石。样品总重366g,粒级6080目,纯度100%,缩分为100瓶,每瓶3 66g。Ar Ar阶段加热法初测结果为:全部12个阶段给出的总气体年龄为30 8±0 9Ma,412阶段视年龄十分接近,年龄谱平坦,对应的39Ar析出量达96%,坪年龄为29 6±0 4Ma,等时年龄为29 6±0 6Ma,MSWD=1 01。40Ar/36Ar初始值为293 6±3 9,与尼尔值295 5相当。重复测定结果为:全部气体年龄为31 0±0 9Ma(全部9个阶段),坪年龄为29 5±0 4Ma,等时年龄为29 4±0 6Ma,MSWD=1 94,40Ar/36Ar初始值为282 2±6 3。这些结果表明,BT 1透长石不含过剩氩,作为新生代定年的Ar Ar法标准样品候选者是较为理想的。     

Study of statistically correcting model CMAQ-MOS for forecasting regional air quality

Based on analysis of the air pollution observational data at 8 observation sites in Beijing including outer suburbs during the period from September 2004 to March 2005, this paper reveals synchronal and in-phase characteristics in the spatial and temporal variation of air pollutants on a city-proper scale at deferent sites; describes seasonal differences of the pollutant emission influence between the heating and non-heating periods, also significantly local differences of the pollutant emission influence between the urban district and outer suburbs, i.e. the spatial and temporal distribution of air pollutant is closely related with that of the pollutant emission intensity. This study shows that due to complexity of the spatial and temporal distribution of pollution emission sources, the new generation Community Multi-scale Air Quality (CMAQ) model developed by the EPA of USA produced forecasts, as other models did, with a systematic error of significantly lower than observations, albeit the model has better capability than previous models had in predicting the spatial distribution and variation tendency of multi-sort pollutants. The reason might be that the CMAQ adopts average amount of pollutant emission inventory, so that the model is difficult to objectively and finely describe the distribution and variation of pollution emission sources intensity on different spatial and temporal scales in the areas, in which the pollution is to be forecast. In order to correct the systematic prediction error resulting from the average pollutant emission inventory in CMAQ, this study proposes a new way of combining dynamics and statistics and establishes a statistically correcting model CMAQ-MOS for forecasts of regional air quality by utilizing the relationship of CMAQ outputs with corresponding observations, and tests the forecast capability. The investigation of experiments presents that CMAQ-MOS reduces the systematic errors of CMAQ because of the uncertainty of pollution emission inventory and improves the forecast level of air quality. Also this work employed a way of combining point and area forecasting, i.e. taking the products of CMAQ for a center site to forecast air pollution for other sites in vicinity with the scheme of model products "reanalysis" and average over the "area".     

Vertical structures of PM10 and PM 2.5 and their dynamical character in low atmosphere in Beijing urban areas

The vertical structures and their dynamical character of PM2.5 and PM10 over Beijing urban areas are revealed using the 1 min mean continuous mass concentration data of PM2.5 and PM10 at 8, 100, and 320 m heights of the meteorological observation tower of 325 m at Institute of Atmospheric Physics, Chinese Academy of Sciences (IAP CAS tower hereafter) on 10―26 August, 2003, as well as the daily mean mass concentration data of PM2.5 and PM10 and the continuous data of CO and NO2 at 8, 100 (low layer), 200 (middle layer), and 320 m (high layer) heights, in combination with the same period meteorological field observation data of the meteorological tower. The vertical distributions of aerosols observed on IAP CAS tower in Beijing can be roughly divided into two patterns: gradually and rapidly decreasing patterns, I.e. The vertical distribution of aerosols in calm weather or on pollution day belongs to the gradually decreasing pattern, while one on clean day or weak cold air day belongs to the rapidly decreasing pattern. The vertical distributive characters of aerosols were closely related with the dynamical/thermal structure and turbulence character of the atmosphere boundary layer. On the clean day, the low layer PM2.5 and PM10 concentrations were close to those at 8 m height, while the concentrations rapidly decreased at the high layer, and their values were only one half of those at 8 m, especially, the concentration of PM2.5 dropped even more. On the clean day, there existed stronger turbulence below 150 m, aerosols were well mixed, but blocked by the more stronger inversion layer aloft, and meanwhile, at various heights, especially in the high layer, the horizontal wind speed was larger, resulting in the rapid decrease of aerosol concentration, I.e. Resulting in the obvious vertical difference of aerosol concentrations between the low and high layers. On the pollution day, the concentrations of PM2.5 and PM10 at the low, middle, and high layers dropped successively by, on average, about 10% for each layer in comparison with those at 8 m height. On pollution days, in company with the low wind speed, there existed two shallow inversion layers in the boundary layer, but aerosols might be, to some extent, mixed below the inversion layer, therefore, on the pollution day the concentrations of PM2.5 and PM10 dropped with height slowly; and the observational results also show that the concentrations at 320 m height were obviously high under SW and SE winds, but at other heights, the concentrations were not correlated with wind directions. The computational results of footprint analysis suggest that this was due to the fact that the 320 m height was impacted by the pollutants transfer of southerly flow from the southern peripheral heavier polluted areas, such as Baoding, and Shijiazhuang of Hebei Province, Tianjin, and Shandong Province, etc., while the low layer was only affected by Beijing's local pollution source. The computational results of power spectra and periods preliminarily reveal that under the condition of calm weather, the periods of PM10 concentration at various heights of the tower were on the order of minutes, while in cases of larger wind speed, the concentrations of PM2.5 and PM10 at 320 m height not only had the short periods of minute-order, but also the longer periods of hour order. Consistent with the conclusion previously drawn by Ding et al., that air pollutants at different heights and at different sites in Beijing had the character of "in-phase" variation, was also observed for the diurnal variation and mean diurnal variation of PM2.5 and PM10 at various heights of the tower in this experiment, again confirming the "in-phase" temporal/spatial distributive character of air pollutants in the urban canopy of Beijing. The gentle double-peak character of the mean diurnal variation of PM2.5 and PM10 was closely related with the evident/similar diurnal variation of turbulent momentum fluxes, sensible heat fluxes, and turbulent kinetic energy at various heights in the urban canopy. Besides, under the condition of calm weather, the concentration of PM2.5 and PM10 declined with height slowly, it was 90% of 8 m concentration at the low layer, a little lesser than 90% at the middle layer, and 80% at the high layer, respectively. Under the condition of weak cold air weather, the concentration remarkably dropped with height, it was 70% of 8 m concentration at the low layer, and 20%―30% at the middle and high layers, especially the concentration of PM2.5 was even lower.     

多连通域浮式平台波浪载荷水池模型试验研究

大型多连通域浮式平台的典型代表是大型海上旅游浮式综合体,依据概念设计,开展大型多连通域浮式平台的波浪载荷水池模型试验研究,试验对不同海况下4种典型多连通域浮式平台方案进行波浪载荷测量,包括剖面的垂向弯矩、水平弯矩和扭矩等,通过观察试验现象和分析测量数据,获得了不同方案大型多连通域浮式平台的波浪载荷特性。试验结果表明：由于平台质量大、振动阻尼大,所以高频载荷成分小;平台在自由状态下载荷值基本都小于平台只释放垂荡状态载荷值;在方案四高波高状态下,平台波浪载荷的高频成分包含了波浪的非线性、约束柱与平台之间的耦合、平台自身的高频振动等。研究成果可为大型海上旅游浮式综合体的结构设计提供设计载荷输入,支撑平台的强度校核评估。     

水牛蹄型深海集矿机履齿设计及牵引性能研究

作为深海采矿系统的重要组成部分,深海集矿机的技术研究和开发一直是许多国家的难题。为了提高深海集矿机在稀软沉积物上的牵引性能,基于水牛蹄的曲面结构特征和特殊几何结构,设计了一款仿水牛蹄蹄型履齿。以该款履齿的结构参数为研究对象,通过对朗肯被动土压力理论的优化,得到了仿水牛蹄蹄型履齿的牵引力解析解,建立了对应的履齿仿生参数对履齿牵引力的影响公式。结合正交试验方法进行了不同形式履齿在沉积物上运动的单、多履齿剪切试验,将仿水牛蹄蹄型履齿与直型履齿、仿水牛蹄轮廓履齿（另一种仿生履齿）进行对比试验,并通过模型车试验验证了该款履齿的可行性。结果表明：3种履齿中,仿水牛蹄蹄型履齿提供的最大牵引力最高。研究可为进一步优化仿水牛蹄蹄型履齿结构参数和提高深海稀软底质机械的牵引性能提供参考依据。     

玉龙雪山景区游客分布特征分析

基于2001~2009年玉龙雪山景区索道接待人次数据,从客流量的年度变化、季度变化、黄金周变化等方面分析了景区客流时空分布特征。主要结果如下:(1)景区客流量随着时间变化呈逐年上升的趋势且增幅明显;(2)夏季为玉龙雪山景区的旺季,冬季为淡季,景区内部各景点季节性差异大小为:牦牛坪冰川公园云杉坪。(3)黄金周客流量变化呈"单峰"型,中期人数最多;最大日客流量为年内日平均客流量的2.43倍。各景点"五一"、"十一"客流分布集中程度相似,牦牛坪的变化程度最大,冰川公园最小。(4)景区客流量空间分布集中程度高,主要集中于云杉坪和冰川公园。     

基于便携式X射线荧光光谱法的深海沉积物现场成分快速检测及适用性评估

远洋粘土、硅藻软泥、铁锰结核及结壳是常见的深海沉积成因物质类型,在开展深海地质调查工作时及时获得这些物质的成分信息,对于提升海上地质调查效率和认知能力十分重要。通过便携式X射线荧光光谱法（pXRF）对菲律宾海深水区域60个样品进行分析,并结合实验室测试结果,评估pXRF能测出的24种元素含量数据的稳定性、准确性及相关性,探讨pXRF在海上地质调查工作中对于深海沉积物现场成分快速检测的适用性。通过综合对比研究发现,Ca、Cu、Fe、K、P、Pb、Sr、Zn、Zr九种元素稳定性、准确性和相关性较好,可以直接用于定性乃至定量研究工作。Al、Ba、Mn、Mo、Ni、Rb、Si、Ti、Th、V十种元素的三项指标参数等级略低,可用于含量高低判定和趋势分析等定性研究工作。Bi、Cs、Mg、Sb、Sc五种元素的测试效果较差,本法不建议使用。取样量充足且分布均匀、湿样烘干至恒量后研磨过筛、封装时充分压实平整、测试时间增长、选择合适的标准物质校正和检验、重点和异常样品增加测试次数等措施的执行有利于获得高精度的pXRF海上测试数据。未来对更多类型和数量深海样品开展pXRF现场分析,将有利于建立更精准的测试方法流程,达到现场快速揭示样品成分特征、确定底质类型及圈定矿化异常等目的,为海上关键决策的部署和实施提供参考和借鉴。     

Eco-environment range in the source regions of the Yangtze and Yellow rivers

Based on geographical and hydrological extents delimited, four principles are identified, as the bases for delineating the ranges of the source regions of the Yangtze and Yellow rivers in the paper. According to the comprehensive analysis of topographical characteristics, climate conditions, vegetation distribution and hydrological features, the source region ranges for eco-environmental study are defined. The eastern boundary point is Dari hydrological station in the upper reach of the Yellow River. The watershed above Dari hydrological station is the source region of the Yellow River which drains an area of 4.49×104 km2. Natural environment is characterized by the major topographical types of plateau lakes and marshland, gentle landforms, alpine cold semi-arid climate, and steppe and meadow vegetation in the source region of the Yellow River. The eastern boundary point is the convergent site of the Nieqiaqu and the Tongtian River in the upstream of the Yangtze River. The watershed above the convergent site is the source region of the Yangtze River, with a watershed area of 12.24×104 km2. Hills and alpine plain topography, gentle terrain, alpine cold arid and semi-arid climate, and alpine cold grassland and meadow are natural conditions in the source region of the Yangtze River.     

基于马尔科夫链转移概率极限分布的降水过程持续性研究

各地不同气候条件所具有的天气状态转移概率的极限分布实际上代表了各地天气气候的持续性和转折性特征,同时也表明了它的可预报期限。从马尔科夫链理论出发,初步研究了中国160个代表测站逐日天气状态演变过程的极限分布。结果表明,转移概率的极限分布不但其空间分布有明显差异,而且不同季节的极限分布也有明显差异。例如,有的地区仅有2 d持续期,有的可达4—6 d或更长,充分反映出不同地区因其影响的天气系统差异所造成的逐日天气气候的持续性和转折性特征的差异。其研究意义在于,由此可作为天气气候分型区划的一种理论依据。统计分析结果表明,就全中国平均而言,夏季持续期最短,持续期由北向南、由西向东呈增加趋势,且春季平均降水持续期为5.1 d,夏季平均为5.0 d,秋季平均为6.5d,冬季平均为6.2 d。可见夏半年比冬半年的降水持续期短,这可能是因为春夏季的天气系统比较复杂且中小尺度天气系统较多的缘故。这从另一侧面再次证明,各地逐日降水天气状态演变过程具有一定的天气气候状态自然转折的持续性即自然天气周期的气候状况,从而为短期天气预报提供了气候背景。     

官厅水库近三十年的水质演变时序特征

基于过去的研究成果,综述了官厅水库近三十年来的水质演变过程,分阶段探讨了官厅水库水污染的来源和特征。与此同时,从污染物的角度探讨了官厅水库典型污染物的时空变化规律。研究结果表明,官厅水库的水质演变先后经历了四个阶段,依次为1972～1975年以有机毒物和重金属污染为特征的水体污染,1981～1992年以有机污染为主体的水体再污染,1992～1995年增加了大肠杆菌污染的水体复合污染,以及1996年至今以氮磷污染为明显特征的水体有机复合污染。从主要污染物的时间变化上看,库区COD和主要重金属含量均在缓慢上升,挥发酚的含量呈现波动趋势,氨氮和总磷的含量持续大幅度上升。污染物在库区的空间分布规律相似,入库处污染物浓度明显高于出库处的污染物浓度。