Emplacement and Differentiation of the York Haven Diabase Sheet, Pennsylvania

Many of the high-Ti quartz-normative tholeiitic intrusive sheetsin the early Mesozoic rift basins of the Eastern USA exhibitlateral differentiation from mafic cumulate units, through diabase,to relatively evolved iron-rich rock types. We have investigateda representative example in detail, the York Haven sheet inthe Gettysburg basin of south–central Pennsylvania. Itranges in thickness from 330 m to 675 m, and we have sampledit from base to top along four separate stratigraphic sectionsevenly spaced over the extent of the intrusion. The easternmostsection (York Haven) is entirely basaltic bronzite cumulate(average 15 vol. % bronzite), whereas the westernmost (ReesersSummit) consists of diabase and low-MgO diabase with a middleto upper ‘sandwich zone’ of ferrogabbro. The interveningsections feature rock types transitional between the two end-membersequences. Chemically, the rock series shows a gradual eastto west depletion of compatible elements (Mg, Ca, Ni, and Cr),and enrichment of incompatible elements [Ti, Fe, Na, K, P, Cu,Zr, Th, Ta, Hf, Sb, Cs, As, platinum group elements (PGEs),and rare earth elements (REEs)]. We suggest two main processes for the trends observed in theYork Haven sheet. First, flow differentiation during ascentand lateral injection of the parental magma produced a tongueof basaltic bronzite cumulate that thins from southeast to northwestand passes laterally into diabase, and, at the distal end ofthe intrusion, into low-MgO diabase. Then, in the latter stagesof crystallization, densitydriven hydrothermal fluids transportedincompatible elements westward, into structurally higher partsof the intrusion. Reaction of this residual aqueous fluid withpartly crystallized low-MgO diabase produced a zone of ferrogabbrorich in hydrothermal replacement products (e.g., Cl-amphibole,biotite, ferrohypersthene, and skeletal ilmenite) and precipitates(e.g., quartz, fayalite, Cl-apatite, sulfides, and PGE minerals). ^* Present address: US Geological Survey, Hawaiian Volcano Observatory, Hawaii National Park, Hawaii 96718     

Late Holocene estuarine phosphogenesis in Raglan Harbour, New Zealand

A unique instance of Holocene estuarine phosphogenesis has been investigated in Raglan Harbour, on the west coast of North Island, New Zealand. Nodular calcareous concretions, which formed within surficial estuarine muds between 6500 and 3600 years BP, were superficially impregnated by carbonate fluorapatite between 3600 and 1600 years BP. The phosphatized nodules lie beneath a late Quaternary shore platform, which is reinforced by a mass of intertwined bioturbation structures and tubular rootlet casts impregnated by limonite and goethite. Large polygonal cracks, indicative of a desiccatory regime, are locally conspicuous on the platform surface and in the immediately subjacent muds. The phosphogenesis in Raglan Harbour is here related to an episode of lowered sea-level, during which a paludal environment succeeded the estuarine, to be followed, in turn, by a positively and interlude. The subsequent rise of sea-level to its present position over the last 1600 years or so has reinstated the shore platform in its present intertidal situation.     

Geochemistry and origin of a black mudstone in a volcaniclastic environment, Ordovician Lower Rhyolitic Tuff Formation, North Wales, UK

Black mudstones in marine volcaniclastic environments have been interpreted both as non-volcanic ‘background’sedimentation and as fine grained vitric dust from the waning stages of primary volcanism. Although difficult to distinguish by standard petrographic techniques, differentiation between the two is crucial when attempting to determine sedimentation rates or to infer periods of volcanic quiescence. In the Ordovician Lower Rhyolitic Tuff Formation of North Wales such a fine grained black unit at Cwm Idwal is geochemically similar to an underlying rhyolite ash flow tuff. Its chemical index of alteration (CIA) is identical to that of the tuff. These data suggest that the black mudstone unit is a vitric tuff related to the underlying ash flow tuff. Use of a CIA in addition to trace element geochemistry should, in most cases, serve to distinguish tuffs from silicified mudstones.     

Flow properties of turbidity currents in Bute Inlet, British Columbia

Bute Inlet, a fiord along the southwestern coast of British Columbia, Canada, includes a sea-floor sedimentation system 70 km in length which resembles those developed on some large submarine fans. Turbidity currents originate at the head of the flord on the submerged delta fronts of the Homathko and Southgate rivers. They move downslope for about 30 km within a single large incised channel, spill onto a depositional area termed the channel lobe complex, and finally spread out over a low-relief distal splay area that passes 55 km downslope into a flat basin floor. During the present study, turbidity currents in Bute Inlet were studied using sea-floor morphology, bottom sediment distribution, and in-situ instrument packages. The mean velocities of the most recent flows, estimated from surface sediment grain size, has varied between 100–120 cm s^–1 in the incised channel, 20–50 cms^–1 in the channel lobe complex, and < 5 cm s^–1 on the basin floor. Velocities based on channel morphology are poorly constrained but are in the range of 160-425 cm s^–1 in the upper part of the incised channel and 66 cm s^–1 in the lower channel. Calculated flow densities range from 1.049 to 1.028g cm^–3. Turbidity flows monitored in 1986 using submerged instrument packages exceeded 32 m in thickness in the upper part of the incised channel, where the maximum measured velocity was 330 cm s^–1. At the head of the channel lobe complex the maximum velocity had declined to 75 cm s^–1. The density of the monitored flows is estimated at 1.025-1.03g cm^–3. The cored sediments and channel morphology yield estimates of mean flow velocities that are generally greater than those measured by the in-situ instrument packages and estimated from modern surface sediments. The former suggest past flow velocities up to 500 cm s^–1 in the incised channel, about 20 cm s^–1 in spillover deposits along the lower part of the incised channel, and 100-140 cm s^–1 in the distal splay. The contrast between the velocities of modern and past flows suggests that past flows may have been considerably larger and more energetic than those presently occurring in Bute Inlet. The size properties of sediments in the monitored turbidity flows suggest a strong vertical size gradient in the suspended load during transport. The surface and cored sediments fine downslope from the channel lobe complex to distal splay area. Distinctive sedimentary sequences are recognized in cores from the spillover lobes, channel lobe complex, distal splay, and basin floor depositional areas. Many individual turbidites grade downslope from massive T_a divisions in the channel lobe complex and probably in the incised channel to T_a divisions overlain by slurried divisions on the distal splay and largely slurried beds on the basin floor. These facies suggest that individual currents commonly evolve from largely cohesionless suspensions in the incised channel and channel lobe complex to dilute cohesive slurries downslope on the distal splay and basin floor. Many flows in Bute Inlet fail to develop a traction state of sedimentation and the resulting turbidites lack well-developed T_b. T_c, and T_d divisions.     

Recent Volcanism in the Puyehue--Cordon Caulle Region, Southern Andes, Chile (40?5?S): Petrogenesis of Evolved Lavas

Puyehue Volcano (40?5?S) in the southern volcanic zone (33?–46?)of the Andes is a largely basaltic stratovolcano constructedon a highly eroded, dominantly andesitic volcanic center. Duringgrowth of Puyehue Volcano there was a trend from basaltic tomore siliceous lavas, and the most recent eruptions (1921–22,1960) are Cordon Caulle rhyodacites and rhyolites erupted fromfissures northwest of the volcano. These basaltic through rhyoliticlavas define a medium-K₂O suite of tholeiitic affinity withtrace element and Pb-isotopic signatures typical of volcanicrocks associated with subduction zones. Most of the evolved lavas, ranging from andesite to rhyolite,formed by low to moderate pressure ( 5 kb) fractional crystallizationof a plagioclase-dominated anhydrous assemblage. Magma mixingproduced aphyric basaltic andesites with anomalously high incompatibleelement contents and latestage andesites with disequilibriumphenocryst assemblages. The age progression from abundant basaltto younger, less voluminous, more silicic lavas reflects increasinglygreater degrees of fractional crystallization which caused theapparent compositional gap between mixing end members to widen. There is no evidence in the silicic lavas for assimilation ofgeochemically distinctive continental crust. Puyehue basaltsare surprisingly more heterogeneous in ⁸⁷Sr/⁸⁶Sr (0?70378–0?70416)and incompatible element abundance ratios (e.g., La/Sm, Ba/Nb)than the more evolved lavas. This geochemical variability mayreflect subcrustal source heterogeneities or contamination bylower crust. The older basaltic andesites and andesites underlyingthe Puyehue edifice have Sr and Nd isotopic ratios and incompatibleelement abundance ratios within the range of Puyehue basalts.Apparently, similar sources and processes were involved in theirgenesis.     

Differentiation and Compaction in the Palisades Sill, New Jersey

The Palisades Sill was studied chemically and petrographicallyin order to elucidate its differentiation mechanism. Neutronactivation analysis was performed on 53 whole rock samples froma 342-m thick section located near the George Washington bridge.Data for 31 elements in these samples are presented here. Thestudy revealed that at least three and probably four pulsesof magma were intruded into the sill. Following the final pulsethe remaining two-thirds of the thickness of the sill differentiatedprimarily through inefficient fractional crystallization inwhich cumulate material contained 40–50 per cent interstitialmagma. In addition to differentiation by fractional crystallization,postcumulus transport of interstitial magma in the Palisadescumulates played a significant role. Crystallization of thelast of the main body of magma produced a peak in incompatibleclement concentrations at a sandwich horizon located at the300 m level, where the floor and roof of the sill converged.At the time this enriched zone crystallized, the underlying150 m of cumulus material still contained interstitial meltSubsequent buoyancy driven upward transport of interstitialmelt in this zone concentrated incompatible elements 45 m belowthe main peak. A numerical model of the sill was constructed which includesa treatment of compaction, thermal and compositional processes,and crystallization. The model is successful in simulating thedifferentiation of the sill and in particular the postcumulustransport mechanism, although the magnitude of the effect issomewhat less than in the natural system. The reason for thegreater effect in the natural system is probably due to theeffects of water which work to facilitate postcumulus flow.     

Uranium oxidation and probable subaerial weathering of phosphatized limestone from the Pourtales Terrace*

Phosphatized limestones from the Pourtales Terrace, Straits of Florida, have undergone fresh-water diagenesis, as shown by several selective petrologic features such as dissolution of aragonitic skeletal material and preservation and recrystallization of Mg-calcite. This interpretation is supported by the fact that greater than 94% of the uranium in these samples is in the U(VI) oxidation state. On the deeper Pourtales Escarpment, phosphatized limestones show no alteration features indicative of fresh-water diagenesis. The uranium in these samples is a mixture of U(IV) and U(VI) with oxidation-state ratios similar to other sea-floor phosphorites. Our interpretation of these data is that uranium in the terrace samples was oxidized when that area was emergent. The karsted surface of the terrace, therefore, is a result of subaerial exposure of this portion of the Floridan platform. The escarpment samples were never above sea level, and so more closely retain their original uranium oxidation-state ratios.     

Bedform distribution and inferred sand transport on Georges Bank, United States Atlantic Continental Shelf

Four bedform provinces have been identified on Georges Bank using sidescan-sonar and echo-sounding techniques: large sand waves superimposed on sand ridges, small sand waves, megaripples, and featureless seafloor. The large sand waves and sand ridges are found on the bank crest where the surface tidal currents are strongest. Areas of small sand waves and megaripples, formed where tidal currents are moderate in strength, border the area of large sand waves to the north and south. Featureless seafloor is found farthest from the bank crest where surface tidal currents are weakest. Sand-wave asymmetry and surface-sediment texture have been used to infer bedload transport paths on Georges Bank. In the large sand-wave area, bedforms indicate a clockwise transport around each of the linear north-west-striking sand ridges with slight convergence of the sand waves on the ridge crests. This transport pattern implies erosion from the troughs and accumulation on the sand ridges. The asymmetry of the small sand waves along the south side of Georges Bank indicates that sand is also transported southward away from the linear sand ridges on top of the bank. Although the asymmetry of megaripples could not be determined, the occurrence of megaripples between the small sand-wave province and areas of featureless seafloor suggests a decreasing effectiveness of sand transport away from the bank crest. This sand dispersal pattern is further supported by the surface sediments which become progessively finer to the north and SW away from the crest of Georges Bank.     

Petrology and Trace Element Geochemistry of the Honolulu Volcanics, Oahu: Implications for the Oceanic Mantle below Hawaii

The Honolulu Volcanics comprises small volume, late-stage (post-erosional)vents along rifts cutting the older massive Koolau tholeüticshield on Oahu, Hawaii. Most of these lavas and tuff of theHonolulu Volcanics have geochemical features expected of near-primarymagmas derived from a peridotite source containing Fo_87–89olivine; e. g. 100 Mg/(Mg + Fe²⁺) >65, >250 p. p. m. Ni,and presence of ultramafic mantle xenoliths at 18 of the 37vents. Consequently, the geochemistry of the alkali olivinebasalt, basanite, nephelinite and nepheline melilitite lavasand tuff of the Honolulu Volcanics have been used to deducethe composition of their mantle source and the conditions underwhich they were generated by partial melting in the mantle. Compositional trends in 30 samples establish that the magmaswere derived by partial melting of a garnet (<10 per cent)Iherzolite source, which we infer to have been carbon-bearing,from analogy with experimental results. This source was isotopicallyhomogeneous (Sr, Lanphere & Dalrymple, 1980; Pb, Sun, 1980;Nd, Roden et al., 1981), and we infer that the source was compositionallyuniform in all major-element oxides except TiO₂, in compatibletrace elements (Sc, V, Cr, Mn, Co and Ni), and in highly incompatibletrace elements (P, Th, La, Ce). However, the source appearsto have been heterogeneous in TiO₂, Zr, Hf, Nb, and Ta, elementsthat were not strongly incompatible during partial melting.Some nepheline melilitite samples may be derived from a sourcewith distinct Sc and heavy-rare-earth-elements (REE) abundances,or which had a phase or phases controlling the distributionof these elements. The relatively limited abundance range for several elements,such as Ti, Zr, Nb, is partly a consequence of the low degreesof melting inferred for the series (2 per cent for nephelinemelilitite, 11 per cent for alkali olivine basalt), which failedto exhaust the source in minor residual phases. We infer thatthese residual phases probably included phlogopite, amphibole,and another Ti-rich phase (an oxide?), but not apatite. In comparison with estimates of a primordial mantle compositionand the mantle source of mid-oceanic-ridge basalt the garnetperidotite source of the Honolulu Volcanics was increasinglyenriched in the sequence heavy REEs, Y, Tb, Ti, Sm, Zr, andHf all <P <Nd <Sr Ce <La <Nb Ta. A multi-stagehistory for the source of the Honolulu Volcanics is requiredbecause this enrichment was superimposed on a mantle that hadbeen previously depleted in incompatible elements, as indicatedby the relatively low ⁸⁷Sr/⁸⁶Sr ratio, high ¹⁴³Nd/¹⁴⁴Nd ratioand low contents of K, Rb, Ba, and Th. The composition of thesource of the Honolulu Volcanics differs from the source ofthe previously erupted tholeiitic shield. The modal mineralogyof the source of the Honolulu Volcanics is not represented inthe upper-mantle xenoliths, e. g. the garnet pyroxenite andolivine-poor garnet Iherzolite included within the lavas andtuff of the unit.