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101.
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ZHU Guangyou ZHANG Shuichang LIANG Yingbo DAI Jinxing & LI Jian Research Institute of Petroleum Exploration Development PetroChina Beijing China 《中国科学D辑(英文版)》2005,48(11)
Isotopic evidence of TSR origin for natural gas bearing high H2S contents 1961 As the hazardous component of natural gas, the ex-istence of H2S, due to its extremely strong toxicity and corrosivity, not only decreases the percentage of hy-drocarbon gas within natural gas and reduces its in-dustrial value, it also threatens each aspect of drilling and exploitation. It frequently causes serious safety accidents[1] and leads to the E&P cost and risk of natural gas with higher H2S contents be… 相似文献
103.
对黄沙坪矿床硫化物期矿物进行矿物包裹体温度和成分测定,并进行热力学计算,获得毒砂-闪锌矿阶段成矿温度为300°,logfCO2为0.4~1.4;logfCH4为-2.05~2.07logfH2O为1.67~1.93;logfO2为-32.87~-38.39。对矽卡岩期和硫化物期硫化物进行硫同位素测定,获得矽卡岩期黄铁矿的δ34S为4.1‰~4.6‰; 硫化物期硫化物的δ34S为6.2‰~17.5‰,并具有δ34SSp大于δ34SGn和两组δ34SΣs值。对长石、方铅矿和闪锌矿进行了铅同位素测定,获得长石的206Pb/204Pb比值为18.429~19.305,207Pb/204Pb比值为15.598~15.905;208Pb/204Pb比值为38.647~39.235。方铅矿和闪锌矿的206Pb/204Pb比值为18.00~18.772,207Pb/204Pb比值为15.580~16.045,208Pb/204Pb比值为38.490~41.560,并呈线性排列,显示矿床硫铅是两种以上的物质来源。 相似文献
104.
Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids 总被引:16,自引:2,他引:16
Shifeng Dai Chen-Lin Chou Mei Yue Kunli Luo Deyi Ren 《International Journal of Coal Geology》2005,61(3-4):241-258
This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, Rr=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids. 相似文献
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106.
Yue Ma Xiao‐Hui Chen Lee J. Hosking Hai‐Sui Yu Hywel R. Thomas Simon Norris 《国际地质力学数值与分析法杂志》2021,45(1):64-82
Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials. 相似文献
107.
高速的城市扩展给社会发展带来了无比的活力。但是,也带来了一系列影响社会经济可持续发展的问题。因此,建立城市扩展预测模型对城市空间扩展预测有着实际的意义。本文主要是根据射线预测法的相关理论,使用Map Basic编程和Map Info软件进行相关操作,对济南市进行城市空间扩展预测并对预测进行分析,验证射线预测法的准确性。 相似文献
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无内标-多外标校正激光剥蚀等离子体质谱法测定磁铁矿微量元素组成 总被引:4,自引:2,他引:2
激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)常用于磁铁矿原位微量元素分析,按照校正策略不同,主要分为内标法和无内标法。内标法需要用电子探针(EMPA)预先测定磁铁矿中内标元素Fe的含量,过程较繁琐,且待测元素含量会受到内标元素含量测定的影响。本文采用铁含量较高的玄武质玻璃BCR-2G、BIR-1G、BHVO-2G和GSE-1G作为外标,避免了内标元素含量的测定,建立了无内标-多外标校正LA-ICP-MS测定磁铁矿微量元素组成的分析方法。利用该方法测定了科马提岩玻璃GOR-128g和自然岩浆磁铁矿BC 28的微量元素组成以评估方法的可靠性。结果表明,科马提岩玻璃的测定结果与推荐值及前人内标法的测定值一致,多数元素的相对标准偏差RSD5%;自然岩浆磁铁矿的测定结果与推荐值相比,多数元素的RSD7%,低于前人内标法的RSD(15%)。由此说明无内标-多外标法可以实现富铁硅酸岩或磁铁矿微量元素含量的准确校正,克服了基体效应的影响。因此,无内标-多外标法是一种原位测定磁铁矿微量元素含量的快速、准确方法,具有一定的应用潜力。 相似文献