Evolution of polycyclic alkanes in the Espirito Santo Basin

The distributions of polycyclic alkanes were monitored in a Neocomian sequence (well 1-ESS-34) from the Espirito Santo Basin, southeast Brazil. The profiles included, apart from regular hopanes, significant concentrations of 18α(H), 28,30-bisnorhopane and subordinate amounts of gammacerane. Sterane concentrations, normally with hopane/sterane <5, were compatible with other geochemical data indicating a predominantly planktonic/microbial source of the deposited organic matter. Sample maturities ranged from very immature to the onset of oil generation, allowing biomarker distributions to be followed along a broad maturation range. The ability of certain molecular ratios (e.g. C₂₇ 17α(H)/17β(H)hopanes) to reflect a maturity sequence with depth in the closely-spaced strata of the immature upper levels (Jiquiá Stage) showed the value of molecular techniques over classical geochemical methods (e.g. vitrinite reflectance) for the study of immature sequences. The presence in the oils of southern Espirito Santo of 28,30-bisnorhopane, gammacerane and methyl steranes in similar concentrations as in extracts of the deepest levels of the 1-ESS-34 well qualify the Jiquia Stage as the probable source rock of oils accumulated in the basin.     

Wavelet Analysis of Solar Diameter Measurements Performed at Calern Observatory Astrolabe

Since 1975, a visual program of solar diameter measurement is pursuedat Calern Observatory (France). These observations allowed to put inevidence variations in solar data. Several studies were developed inorder to analyze the data using appropriate me thods (deconvolution ofthe observation window function and least square fits) (Moussaouiet al., 1999). We present in this work a time-frequency studyof the found harmonic terms. It is developed using the wavelettransform. The obtained results are presented and discussed.     

Splash-saltation trajectories of soil particles under wind-driven rain

It is usually recognized that relatively large amounts of soil particles cannot be transported by raindrop splashes under windless rain. However, the splash-saltation process can cause net transportation in the prevailing wind direction since variations in splash-saltation trajectory due to the wind are expected in wind-driven rain. Therefore, determining the combined effect of rain and wind on the process should enable improvement of the estimation of erosion for any given prediction technique. This paper presents experimental data on the effects of slope aspect, slope gradient, and horizontal wind velocity on the splash-saltation trajectories of soil particles under wind-driven rain. In a wind tunnel facility equipped with a rainfall simulator, the rains driven by horizontal wind velocities of 6, 10, and 14 m s⁻¹ were allowed to impact three agricultural soils packed into 20×55 cm soil pans placed at both windward and leeward slopes of 7%, 15%, and 20%. Splash-saltation trajectories were measured by trapping the splashed particles at distances downwind on a 7-m uniform slope segment in the upslope and downslope directions, respectively, for windward and leeward slopes. Exponential decay curves were fitted for the mass distribution of splash-saltation sediment as a function of travel distance, and the average splash-saltation trajectory was derived from the average value of the fitted functions. The results demonstrated that the average trajectory of a raindrop-induced and wind-driven soil particle was substantially affected by the wind shear velocity, and it had the greatest correlation (r=0.96 for all data) with the shear velocity; however, neither slope aspect nor slope gradient significantly predicted the splash-saltation trajectory. More significantly, a statistical analysis conducted with nonlinear regression model of C₁(u_*²/g) showed that average trajectory of splash saltation was approximately three times greater than that of typical saltating sand grain.     

Microseismicity within a karstified rock mass due to cracks and collapses as a tool for risk management

Seismometer arrays have been widely applied to record collapse by controlled explosion in mines and caves. However, most underground failures are natural events, and because they can occur abruptly, underground failures represent a serious geological hazard. An accelerometric array installed on 4 September 2008 has been used to manage the geological risk of the Peschiera Springs drainage plant of Rome??s aqueduct, which is located in the Central Apennines approximately 80?km from Rome, Italy. The plant occupies a karstified carbonatic slope that is extensively involved in gravitational deformations, which are responsible for underground failures such as cracks and collapses. To distinguish among different types of recorded events, an automated procedure was implemented based on the duration, peak of ground acceleration (PGA) and PGA variation in the recordings of the plant??s accelerometric stations. The frequencies of earthquakes and micro-earthquakes due to underground failures are, in general, well correlated. Nevertheless, many underground failure sequences can be directly associated with the continuous deformations that affect the slope. The cumulative Arias intensity trend derived for the underground failures combined with the failure and earthquake frequencies enabled the definition of a control index (CI) that identifies alarming or emergency conditions. The CI can be used as a tool for managing the geological risk associated with the deformational processes that affect the drainage plant.     

Late Quaternary paleoclimate of western Alaska inferred from fossil chironomids and its relation to vegetation histories

Fossil Chironomidae assemblages (with a few Chaoboridae and Ceratopogonidae) from Zagoskin and Burial Lakes in western Alaska provide quantitative reconstructions of mean July air temperatures for periods of the late-middle Wisconsin (～39,000–34,000 cal yr B.P.) to the present. Inferred temperatures are compared with previously analyzed pollen data from each site summarized here by indirect ordination. Paleotemperature trends reveal substantial differences in the timing of climatic warming following the late Wisconsin at each site, although chronological uncertainty exists. Zagoskin Lake shows early warming beginning at about 21,000 cal yr B.P., whereas warming at Burial Lake begins ～4000 years later. Summer climates during the last glacial maximum (LGM) were on average ～3.5 °C below the modern temperatures at each site. Major shifts in vegetation occurred from ～19,000 to 10,000 cal yr B.P. at Zagoskin Lake and from ～17,000 to 10,000 cal yr B.P. at Burial Lake. Vegetation shifts followed climatic warming, when temperatures neared modern values. Both sites provide evidence of an early postglacial thermal maximum at ～12,300 cal yr B.P. These chironomid records, combined with other insect-based climatic reconstructions from Beringia, indicate that during the LGM: (1) greater continentality likely influenced regions adjacent to the Bering Land Bridge and (2) summer climates were, at times, not dominated by severe cold.     

Circannual Cycle and Oxygen Consumption in Eudendrium glomeratum (Cnidaria, Anthomedusae): Studies on a Shallow Water Population

Abstract. The oxygen consumption of Eudendrium glomeratum was measured monthly, throughout the period of active presence of the species in the field, to obtain indications on its physiological condition in the different phases of the cycle. Sets of one hundred polyps were assayed in the laboratory under normothermic (according to field temperature: 14–19°C) and hyperthermic conditions (22–25°C). The different response to identical temperatures at the extremes of the cycle, together with a differential ability to face stressful conditions in the same periods, suggests that other factors, besides temperature, regulate the seasonal cycle of Eudendrium glomeratum.     

Phytoplankton of the Barents Sea at the Polar Front in Spring

Oceanology - This paper describes the comprehensive studies of phytoplankton carried out in April 2018 in the northwestern Barents Sea, in the Polar Front region (74.8°–76.2° N), at...     

European Phanerozoic metallogenesis

Phanerozoic metallogenesis in Europe displays divergent characteristics which may be related to the variable nature of the three great European Phanerozoic orogens: Caledonian, Variscan and Alpine. These reflect different geodynamic processes. The Caledonian orogen resulted from the interaction of essentially oceanic with continental lithosphere, whilst the Variscan and Alpine orogens evolved mainly from continent-continent collisions with the involvement of a series of smaller oceanic basins. Each major stage of the orogenic processes is characterised by a typical metallogeny. The occurrence of subduction-related processes in the Caledonian orogeny gave rise to extensive VHMS deposition with characteristic Zn:Cu ratio signatures. The relative lack of abundance of metal-rich, Andean-type porphyry-type mineralisation remains unexplained, unless present erosional levels have prevented the preservation of such deposits. Continent-continent collisions do not appear to result in extensive mineralisation unless elevated heat flows result, possibly as a result of lithospheric delamination at the peak collisional stage. The development of late stage and peri-orogenic sedimentary basins are characterised by extensive Pb-Zn-Ba-F mineralisation as expressions of basinal fluid flow of regional dimensions.     

Fractional Crystallization and Liquid Immiscibility Processes in the Alkaline-Carbonatite Complex of Juqui (So Paulo, Brazil)

The Juqui circular intrusion, which is Cretaceous in age (130–135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 33–5%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 5–5 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO₂-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1–4–2–9) for light rare earth elements(LREE) than for REE from Eu to Yb (4–6–7–8),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K₀ REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial ⁸⁷Sr/⁸⁶Sr ratios (mostly between0–7052 and 0–7057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0–7060–0–7078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement.     

Structure Function Analysis of Two-Scale Scalar Ramps. Part II: Ramp Characteristics and Surface Renewal Flux Estimation

Ramp features in the turbulent scalar field are associated with turbulent coherent structures, which dominate energy and mass fluxes in the atmospheric surface layer. Although finer scale ramp-like shapes embedded within larger scale ramp-like shapes can readily be perceived in turbulent scalar traces, their presence has largely been overlooked in the literature. We demonstrate the signature of more than one ramp scale in structure functions of the turbulent scalar field measured from above bare ground and two types of short plant canopies, using structure-function time lags ranging in scale from isotropic to larger than the characteristic coherent structures. Spectral analysis of structure functions was used to characterize different scales of turbulent structures. By expanding structure function analysis to include two ramp scales, we characterized the intermittency, duration, and surface renewal flux contribution of the smallest (i.e., Scale One) and the dominant (i.e., Scale Two) coherent structure scales. The frequencies of the coherent structure scales increase with mean wind shear, implying that both Scale One and Scale Two are shear-driven. The embedded Scale One turbulent structure scale is ineffectual in the surface-layer energy and mass transport process. The new method reported here for obtaining surface renewal-based scalar exchange works well over bare ground and short canopies under unstable conditions, effectively eliminating the α calibration for these conditions and forming the foundation for analysis over taller and more complex surfaces.