天然气水合物生成数值模拟的DAVIE模型和意义

天然气水合物生成数值模拟是以水合物热力学理论为基础,结合计算机方法来模拟水合物在海底环境下生成和分解、分布和富集的热力学、动力学过程。Davie模型是首个能够预测海洋沉积物中天然气水合物体积和分布的定量模型,它系统地模拟了海底天然气水合物的海洋环境和质量平衡,并将其应用到已知水合物分布地区进行对比,取得了很好的效果。     

阿留申岛弧的非火山颤动

在阿留申岛弧观测到了一些非火山颤动。在数座火山上的大跨区的地震台网也监测到颤动状的事件,因此不可能与任何一座火山体有关。虽然目前还不能给这些颤动定位,但我们根据多个台网的反射时差和振幅给出了大概的位置。多数非火山颤动是在所推断的太平洋消减板块闭锁区或从蠕动到闭锁转换区记录到的。有一次非火山颤动事件是在拉特群岛和安德烈亚诺夫群岛附近地区地震活动和火山活动增强时期记录到的。类似的同步增加以往在阿留申群岛记录到过,并被假设是由慢滑动事件引起的大范围应力变化造成的。2008年7月12日奥克莫克火山喷发约1小时后在科罗文和大锡特金地震台网记录到显著的非火山颤动。非火山颤动并不是分散地出现在整个阿留申岛弧,而似乎是集中在几个地区。用2500km的消减带,我们有机会检查这些地区并将其与不产生非火山颤动地区加以比较,以便确定产生该颤动的作用因素。     

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

井底测井技术探测气体水合物

用井底测井技术来确定海洋沉积中气体水合物和地震信号与气体水合物下面游离气的联系已衩证明为非常有效。最近在布来克脊的钻探中,大洋钻探计划（ODP）记录到的现场测得速度和电阻率测井提示在温压稳定带内水合物含量深度的加大而增大。对应的剪切刚度（Vp/Vs比率减小）变小,含水合物层声波幅度减小是由于沉积物中的颗粒被水合物胶结,这解释了布来克脊地区采集的地震剖面普遍存在的振幅空白带现象。 将来的钻探活动中,采用安置在钻头正上方的随钻测井（LWD）传感器将改进孔隙度、气体水合物的横向变化和储层潜力现象精度估计。     

海洋天然气水合物氢氧同位素分馏初探

天然气水合物的形成会造成氢、氧同位素的分馏.在实验室合成研究中,利用天然海水 [(含 0.03%十二烷基硫酸钠 (SDS)]与甲烷气体反应,通过对水合物生成前后溶液中的 Cl-的质量浓度和氢、氧同位素组成的测定,研究了天然气水合物生成过程中氢、氧同位素的分馏情况.实验证明氢、氧的重同位素易于富集在水合物中,其在天然海水-甲烷体系中的分馏系数分别为 1.018～ 1.036和 1.003 4～ 1.006 3,这一分馏系数稍大于前人在纯水和 NaCl溶液中所测得的分馏系数.     

塔里木盆地沉积剥蚀过程与油气关系

塔里木盆地典型井的周期分析表明,塔里木盆地在其地质历史时期100Ma左右的周期是很明显的,自寒武纪以来共经历了4个完整的周期,每一完整周期都由正相位和负相位两个半周期所组成。而第三纪为第5个周期的正相位阶段。该周期控制了盆地内的沉积与剥蚀的过程及成藏旋回。对沉积与剥蚀过程的控制作用表现在周期波正相位和负相位分别对应于沉积期和剥蚀期,这在地质年代序列中表现为沉积与间断的互为消长的演化进程。对食油气系统的控制作用表现在:第1个周期波构成以早古生代地层为主体的含油气系统,第2个周期波至第4个周期波构成以晚古生代至中生代地层为主体的含油气系统,第5个周期的正相位阶段构成以第三纪地层为主体的含油气系统。     

副高边缘暴雨的多普勒雷达回波特征

利用常规观测资料和多普勒雷达探测资料，对2003-2004年湖南省4次副高边缘暴雨的天气形势和雷达回波特征进行了分析研究。结果表明：4次暴雨过程的副高位置适当，高空有低槽，中低层有低空急流和低涡切变线，地面上有冷锋。在基本反射率图上，低槽暴雨有S-N向的窄带回波特征、冷式切变线暴雨有准W—E向的积层回波特征、暖式切变线有NE—SW向的积层回波特征，但每一次暴雨过程不尽相同。在多普勒速度图上常出现低空急流、冷暖平流、冷锋、逆风区以及高层大风核等特征，并常是几种特征同时出现，有利于强降水产生。     

长江宜昌段水系沉积物镉高值带成因

应用贡献因子和富集因子等方法对长江宜昌段水系沉积物Cd的来源进行研究,结果表明：研究区内地层对宜昌段水系沉积物Cd的贡献由大到小依次为：震旦系>二叠系>泥盆系>志留系;前震旦系、寒武系、奥陶系、三叠系、侏罗系和白垩系地层则对长江宜昌段Cd高值带的形成有一定的削弱作用。利用贡献因子、富集因子和MapGIS空间分析综合研究表明,震旦系和二叠系含矿富Cd地层的风化产物是长江宜昌段Cd高值带的主要自然来源。区内锌矿、煤矿和磷矿开采过程中的尾砂、废水的堆积和排放是长江宜昌段Cd高值带的重要人为污染源。     

Polybrominated diphenyl ethers and their methoxylated analogs in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) from Bizerte Lagoon, Tunisia

Concentrations of ten polybrominated diphenyl ethers (PBDEs) and eight methoxylated polybrominated diphenyl ethers (MeO-PBDEs) in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) collected from the Bizerte Lagoon and the Mediterranean Sea were investigated. To the best of our knowledge, this is the first report of these compounds in marine fishes from Tunisia. The PBDE mean concentrations in fish from Bizerte Lagoon were 45.3 and 96.2 ng g(-1) lw respectively in mullet and sea bass, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea were 7.80 and 27.9 ng g(-1) lw respectively. MeO-PBDE concentrations in mullet and sea bass from Bizerte Lagoon ranged from 6.46 to 286 ng g(-1) lw and from 49.4 to 798 ng g(-1) lw respectively, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea ranged from 190 to 401 ng g(-1) lw and from 353 to 578 ng g(-1) lw respectively. The total PBDEs and total MeO-PBDEs concentration in fish from Bizerte Lagoon were similar or slightly lower than those reported for other species from other locations around the world.