Comparisons of 210Pb and pollen methods for determining rates of estuarine sediment accumulation

Comparisons of sedimentation rates obtained by ²¹⁰Pb and pollen analyses of 1-m cores collected throughout the Potomac Estuary show good agreement in the majority of cores that can be analyzed by both methods. Most of the discrepancy between the methods can be explained by the analytical precision of the ²¹⁰Pb method and by the exactness with which time horizons can be identified and dated for the pollen method. X-radiographs of the cores and the distinctness of the pollen horizons preclude significant displacement by reworking and/or mixing of sediments. Differences between the methods are greatest where uncertainties exist in assigning a rate by one or both methods (i.e., ²¹⁰Pb trends and/or “possible” horizon assignments). Both methods show the same relative rates, with greater sediment accumulation more common in the upper and middle estuary and less toward the mouth. The results indicate that geochronologic studies of estuarine sediments should be preceded by careful observation of sedimentary structures, preferably by X-radiography, to evaluate the extent of mixing of the sediments. Time horizons, whether paleontologic or isotopic, are generally blurred where mixing has occurred, precluding precise identification. Whenever possible, two methods should be used for dating sediments because a rate, albeit erroneous, can be obtained isotopically in sediments that are mixed; accurate sedimentation rates are also difficult to determine where the time boundary is a zone rather than a horizon, where the historical record does not provide a precise date for the pollen horizon, or where scouring has removed some of the sediment above a dated pollen horizon.     

Holocene geomagnetic secular variation recorded by volcanic deposits at Mount St. Helens,Washington

A compilation of paleomagnetic data from volcanic deposits of Mount St. Helens is presented in this report. The database is used to determine signature paleomagnetic directions of products from its Holocene eruptive events, to assign sampled units to their proper eruptive period, and to begin the assembly of a much larger database of paleomagnetic directions from Holocene volcanic rocks in western North America. The paleomagnetic results from Mount St. Helens are mostly of high quality, and generally agree with the division of its volcanic deposits into eruptive episodes based on previous geologic mapping and radiocarbon dates. The Muddy River andesite's paleomagnetic direction, however, indicates that it is more likely part of the Pine Creek eruptive period rather than the Castle Creek period. In addition, the Two-Fingers andesite flow is more likely part of the Middle Kalama eruptive period and not part of the Goat Rocks period. The paleomagnetic data from Mount St. Helens and Mount Hood document variation in the geomagnetic field's pole position over the last ~2,500 years. A distinct feature of the new paleosecular variation (PSV) record, similar to the Fish Lake record (Oregon), indicates a sudden change from rapid clockwise movement of the pole about the Earth's spin axis to relatively slow counterclockwise movement at ~800 to 900 years B.P.     

Evaluation of a Model for Predicting Simultaneous Contrast on Color Maps

Perceptions of colors of individual map symbols are affected by simultaneous contrast, or induction, from surrounding colors. In an experiment with human subjects, reaction times were significantly slower, with significantly more errors, for test maps on which an induction model predicted that colors would be misinterpreted. Reaction times and error rates improved significantly with map color adjustments that the model predicted would remove induced confusions. These results represent progress toward establishing objective guidance for the design of effective color schemes in computer-assisted mapping environments common in cartography, geographic information systems, and scientific visualization.     

Low-Flow Purging and Sampling of Ground Water Monitoring Wells with Dedicated Systems

A field study was conducted to assess purging requirements for dedicated sampling systems in conventional monitoring wells and for pumps encased in short screens and buried within a shallow sandy aquifer. Low-flow purging methods were used, and wells were purged until water quality indicator parameters (dissolved oxygen, specific conductance, turbidity) and contaminant concentrations (chromate, trichloroethylene, dichloroethylene) reached equilibrium. Eight wells, varying in depth from 4.6 to 15.2 m below ground surface, were studied. The data show that purge volumes were independent of well depth or casing volumes. Contaminant concentrations equilibrated with less than 7.5 I. of purge volume in all wells. Initial contaminant concentration values were generally within 20 percent of final values. Water quality parameters equilibrated in less than 10 L in all wells and were conservative measures for indicating the presence of adjacent formation water. Water quality parameters equilibrated faster in dedicated sampling systems than in portable systems and initial turbidity levels were lower.     

The Use of Industrial Hygiene Samplers for Soil-Gas Surveying

Soil-gas surveying by the use of a passive sampler which allows quantitative determination of concentrations of volatile organic compounds and remote analysis of samples is described. The results of a survey using the sampler above a chloroform ground water plume are compared to ground water analysis results and to results from a previous soil-gas study above the same plume. Chloroform concentrations measured with passive samplers correlate well (r = 0.79, n = 6; r = 0.93, n = 7) with the other two techniques. The short-range variability of the technique is characterized by a coefficiet of variation of 12 percent over a 27-foot distance for nine samplers, and compares favorably with grab-sample results at the same location.     

Implications of radiolarian assemblages for the late Quaternary Paleoceanography of the eastern equatorial Pacific

The distribution of radiolarian assemblages identified by Q-mode factor analysis of radiolarian microfossils in surface sediments from low latitudes in the Pacific Ocean reflects their associations with surface water masses. Downcore fluctuations of these radiolarian assemblages at two sites, RC10-65 and V19–29, indicate changes in circulation in the eastern equatorial Pacific during the past 500,000 yr. Surface-water radiolarian assemblages characteristic of zonal flow have dominated siliceous sedimentation in the eastern equatorial Pacific, except during times of intense upwelling which can occur along the coast of Peru and in the Equatorial Undercurrent. Fluctuations in the importance of this upwelling have not been consistent with glacial/interglacial changes in ice volume throughout the late Quaternary. Intensification of upwelling in the equatorial divergence, however, has consistently coincided with increases in ice volume in the past 500,000 yr. The times at which changes in the nature of the relationship between upwelling and ice volume occur (approximately 240,000 and 380,000 yr B.P.) roughly coincide with times of observed changes in other proxy indicators of oceanographic conditions in the Pacific and Indian oceans.     

Use of dissolved chloride concentrations in tributary streams to support geospatial estimates of Cl contamination potential near Skiatook Lake,northeastern Oklahoma

Releases of NaCl-rich (>100 000 mg/L) water that is co-produced from petroleum wells can adversely affect the quality of ground and surface waters. To evaluate produced water impacts on lakes, rivers and streams, an assessment of the contamination potential must be attainable using reliable and cost-effective methods. This study examines the feasibility of using geographic information system (GIS) analysis to assess the contamination potential of Cl to Skiatook Lake in the Hominy Creek drainage basin in northeastern Oklahoma. GIS-based predictions of affects of Cl within individual subdrainages are supported by measurements of Cl concentration and discharge in 19 tributaries to Skiatook Lake. Dissolved Cl concentrations measured in October, 2004 provide a snapshot of conditions assumed to be reasonably representative of typical inputs to the lake. Chloride concentrations ranged from 5.8 to 2300 mg/L and compare to a value of 34 mg/L in the lake. At the time of sampling, Hominy Creek provided 63% of the surface water entering the lake and 80% of the Cl load. The Cl load from the other tributaries is relatively small (<600 kg/day) compared to Hominy Creek (11 900 kg/day) because their discharges are relatively small (<0.44 m³/s) relative to Hominy Creek (3.1 m³/s). Examination of chemical components other than Cl in stream and lake waters indicates that many species, such as SO₄, cannot be used to assess contamination potential because they participate in a number of common biogeochemical processes that alter their concentrations.     

Oxygen and carbon stable isotopes in otoliths record spatial isolation of Patagonian toothfish (Dissostichus eleginoides)

Strong contrasts in ambient isotope ratios and in diet suggest stable isotopes in the otoliths of oceanic fish can resolve water masses and geographic areas, promising a powerful multivariate approach for examining population structure and provenance. To test this, whole otoliths were taken from Patagonian toothfish (Dissostichus eleginoides) sampled off the Patagonian Shelf and South Georgia, on either side of a population boundary, and otolith δ¹⁸O and δ¹³C values were measured to see if they could distinguish South American-caught fish from those taken in the Antarctic. Values of otolith δ¹⁸O and δ¹³C predicted capture area with 100% success, validating their use for distinguishing provenance and corroborating the prior evidence of population isolation. Values of δ¹⁸O in the otoliths reflected ambient values as well as seawater temperature: low values in Patagonian Shelf fish were consistent with exposure to Antarctic Intermediate Water (AAIW), and high values in South Georgia fish were consistent with exposure to Circumpolar Deep Water (CDW). In contrast, differences in otolith δ¹³C appeared to reflect diet: relative depletion of otolith δ¹³C at South Georgia compared to the Patagonian Shelf were most likely linked to differences in sources of metabolic carbon, as well as δ¹³C in dissolved inorganic carbon (DIC) of seawater. These contrasting properties strongly suggest that stable isotopes can resolve the provenance of toothfish from Antarctic sampling areas that hitherto have been difficult to separate. These results show that, by using the chemistry recorded in otoliths, researchers can exploit biogeochemical variation in fully marine environments to examine the spatial ecology of oceanic fish.     

A novel technique for detection of the toxic dinoflagellate, Karenia brevis, in the Gulf of Mexico from remotely sensed ocean color data

Karenia brevis, a toxic dinoflagellate that blooms regularly in the Gulf of Mexico, frequently causes widespread ecological and economic damage and can pose a serious threat to human health. A means for detecting blooms early and monitoring existing blooms that offers high spatial and temporal resolution is desired. Between 1999 and 2001, a large bio-optical data set consisting of spectral measurements of remote-sensing reflectance (R_rs(λ)), absorption (a(λ)), and backscattering (b_b(λ)) along with chlorophyll a concentrations and K. brevis cell counts was collected on the central west Florida shelf (WFS) as part of the Ecology and Oceanography of Harmful Algal Blooms (ECOHAB) and Hyperspectral Coastal Ocean Dynamics Experiment (HyCODE) programs. Reflectance model simulations indicate that absorption due to cellular pigmentation is not responsible for the factor of ∼3–4 decrease observed in R_rs(λ) for waters containing greater than 10⁴ cells l⁻¹ of K. brevis. Instead, particulate backscattering is responsible for this decreased reflectivity. Measured particulate backscattering coefficients were significantly lower when K. brevis concentrations exceeded 10⁴ cells l⁻¹ compared to values measured in high-chlorophyll (>1.5 mg m⁻³), diatom-dominated waters containing fewer than 10⁴ cells l⁻¹ of K. brevis. A classification technique for detecting high-chlorophyll, low-backscattering K. brevis blooms is developed. In addition, a method for quantifying chlorophyll concentrations in positively flagged pixels using fluorescence line height (FLH) data obtained from the Moderate Resolution Imaging Spectroradiometer (MODIS) is introduced. Both techniques are successfully applied to Sea-viewing Wide Field-of-view Sensor (SeaWiFS) and MODIS data acquired in late August 2001 and validated using in situ K. brevis cell concentrations.