Comparison of natural gases accumulated in Oligocene strata with hydrous pyrolysis gases from Menilite Shales of the Polish Outer Carpathians

This study examined the molecular and isotopic compositions of gases generated from different kerogen types (i.e., Types I/II, II, IIS and III) in Menilite Shales by sequential hydrous pyrolysis experiments. The experiments were designed to simulate gas generation from source rocks at pre-oil-cracking thermal maturities. Initially, rock samples were heated in the presence of liquid water at 330 °C for 72 h to simulate early gas generation dominated by the overall reaction of kerogen decomposition to bitumen. Generated gas and oil were quantitatively collected at the completion of the experiments and the reactor with its rock and water was resealed and heated at 355 °C for 72 h. This condition simulates late petroleum generation in which the dominant overall reaction is bitumen decomposition to oil. This final heating equates to a cumulative thermal maturity of 1.6% R_r, which represents pre-oil-cracking conditions. In addition to the generated gases from these two experiments being characterized individually, they are also summed to characterize a cumulative gas product. These results are compared with natural gases produced from sandstone reservoirs within or directly overlying the Menilite Shales. The experimentally generated gases show no molecular compositions that are distinct for the different kerogen types, but on a total organic carbon (TOC) basis, oil prone kerogens (i.e., Types I/II, II and IIS) generate more hydrocarbon gas than gas prone Type III kerogen. Although the proportionality of methane to ethane in the experimental gases is lower than that observed in the natural gases, the proportionality of ethane to propane and i-butane to n-butane are similar to those observed for the natural gases. δ¹³C values of the experimentally generated methane, ethane and propane show distinctions among the kerogen types. This distinction is related to the δ¹³C of the original kerogen, with ¹³C enriched kerogen generating more ¹³C enriched hydrocarbon gases than kerogen less enriched in ¹³C. The typically assumed linear trend for δ¹³C of methane, ethane and propane versus their reciprocal carbon number for a single sourced natural gas is not observed in the experimental gases. Instead, the so-called “dogleg” trend, exemplified by relatively ¹³C depleted methane and enriched propane as compared to ethane, is observed for all the kerogen types and at both experimental conditions. Three of the natural gases from the same thrust unit had similar “dogleg” trends indicative of Menilite source rocks with Type III kerogen. These natural gases also contained varying amounts of a microbial gas component that was approximated using the Δδ¹³C for methane and propane determined from the experiments. These approximations gave microbial methane components that ranged from 13–84%. The high input of microbial gas was reflected in the higher gas:oil ratios for Outer Carpathian production (115–1568 Nm³/t) compared with those determined from the experiments (65–302 Nm³/t). Two natural gas samples in the far western part of the study area had more linear trends that suggest a different organic facies of the Menilite Shales or a completely different source. This situation emphasizes the importance of conducting hydrous pyrolysis on samples representing the complete stratigraphic and lateral extent of potential source rocks in determining specific genetic gas correlations.     

ENA detection in the dayside of Mars: ASPERA-3 NPD statistical study

The Analyzer of Space Plasma and EneRgetic Atoms (ASPERA-3) on board Mars Express is designed to study the interaction between the solar wind and the atmosphere of Mars and to characterize the plasma and neutral gas environment in near-Mars space. Neutral Particle Detectors (NPD-1 and 2), which form part of the ASPERA-3 instrument suite, are Energetic Neutral Atom (ENA) detectors which use the time-of-flight (ToF) technique to resolve the energy of detected particles. In the present study, we perform a statistical analysis of NPD ToF data collected between 14 March 2004 and 17 June 2004 when Mars Express was located at the dayside of Mars looking toward the planet. After pre-processing and removal of UV contamination, the ToF spectra were fitted with simple analytical functions so as to derive a set of parameters. The behavior of these parameters, as a function of spacecraft position and attitude, is compared with a model, which describes ENA generation by charge exchange between shocked solar wind protons and extended Martian exosphere. The observations and the model agree well, indicating that the recorded signals are charge-exchanged shocked solar wind.     

Stable carbon isotopes (δ<Superscript>13</Superscript>C) of total organic carbon and long-chain <Emphasis Type="Italic">n</Emphasis>-alkanes as proxies for climate and environmental change in a sediment core from Lake Petén-Itzá, Guatemala

Sediment core PI-6 from Lake Petén Itzá, Guatemala, possesses an ~85-ka record of climate and environmental change from lowland Central America. Variations in sediment lithology suggest large and abrupt changes in precipitation during the last glacial and deglacial periods, and into the early Holocene. We measured stable carbon isotope ratios of total organic carbon and long-chain n-alkanes from the core, the latter representing a largely allochthonous (terrestrial) source of organic matter, to reveal past shifts in the relative proportion of C₃–C₄ terrestrial biomass. We sought to test whether stable carbon isotope results were consistent with other paleoclimate proxies measured in the PI-6 core, and if extraction and isotope analysis of n-alkanes is warranted. The largest δ¹³C variations are associated with Heinrich Events. Carbon isotope values in sediments deposited during the last glacial maximum indicate moderate precipitation with little fluctuation. The deglacial was a period of pronounced climate variability, e.g. a relatively warm and moist Bølling–Allerød, but a cool and dry Younger Dryas. Arid periods of the deglacial were inferred from samples with high δ¹³C values in total organic carbon, which reflect times of greater proportions of C₄ plants. These inferences are supported by stable isotope measurements on ostracod shells and relative abundance of grass pollen from the same depths in core PI-6. Similar trends in carbon stable isotopes measured on bulk organic carbon and n-alkanes suggest that carbon isotope measures on bulk organic carbon in sediments from this lake are sufficient to infer past climate-driven shifts in local vegetation.     

A comparison of TRMM to other basin-scale estimates of rainfall during the 1999 Hurricane Floyd flood

The volumetric rainfall attributed to Hurricane Floyd in 1999 was computed for the bulk of the Tar, Neuse, and Cape Fear River Basins in eastern North Carolina, USA from the Tropical Rainfall Measuring Mission (TRMM) Multi-Satellite Precipitation Analysis (TMPA) research product, and compared with volumes computed using kriged gauge data and one centrally located radar. TMPA showed similar features in the band of heaviest rainfall with kriged and radar data, but was higher in the basin-scale integrations. Furthermore, Floyd’s direct runoff volumes were computed and divided by the volumetric rainfall estimates to give runoff coefficients for the three basins. The TMPA, having the larger storm totals, would suggest greater infiltration during Floyd than the gauge and radar estimates would. Finally, we discuss a concept for adjusting the United States Department of Agriculture Natural Resources Conservation Service rainfall-runoff model when predicting discharge values from real-time TMPA in ungauged river basins.

A Multiscale Assessment of Shallow Groundwater Salinization in Michigan

Managing nonpoint-source (NPS) pollution of groundwater systems is a significant challenge because of the heterogeneous nature of the subsurface, high costs of data collection, and the multitude of scales involved. In this study, we assessed a particularly complex NPS groundwater pollution problem in Michigan, namely, the salinization of shallow aquifer systems due to natural upwelling of deep brines. We applied a system-based approach to characterize, across multiple scales, the integrated groundwater quantity–quality dynamics associated with the brine upwelling process, assimilating a variety of modeling tools and data—including statewide water well datasets scarcely used for larger scientific analysis. Specifically, we combined (1) data-driven modeling of massive amounts of groundwater/geologic information across multiple spatial scales with (2) detailed analysis of groundwater salinity dynamics and process-based flow modeling at local scales. Statewide “hotspots” were delineated and county-level severity rankings were developed based on dissolved chloride (Cl⁻) concentration percentiles. Within local hotspots, the relative impact of upwelling was determined to be controlled by: (1) streams—which act as “natural pumps” that bring deeper (more mineralized) groundwater to the surface; (2) the occurrence of nearly impervious geologic material at the surface—which restricts fresh water dilution of deeper, saline groundwater; and (3) the space–time evolution of water well withdrawals—which induces slow migration of saline groundwater from its natural course. This multiscale, data-intensive approach significantly improved our understanding of the brine upwelling processes in Michigan, and has applicability elsewhere given the growing availability of statewide water well databases.     

Long-term diagnostics of precipitation estimates and the development of radar hardware monitoring within a radar product data quality management system

Abstract

Quality is key to ensuring that the potential offered by weather radar networks is realized. To achieve optimum quality, a comprehensive radar data quality management system, designed to monitor the end-to-end radar data processing chain and evaluate product quality, is being developed at the UK Met Office. Three contrasting elements of this system are described: monitoring of key radar hardware performance indicators; generation of long-term integrations of radar products; and monitoring of radar reflectivity factor using synthesized observations from numerical weather prediction model fields. Examples of each component are presented and ways in which the different types of monitoring information have been used to both identify issues with the radar product data quality and help formulate solutions are given.

Editor Z.W. Kundzewicz; Guest editor R.J. Moore

Citation Harrison, D., Georgiou, S., Gaussiat, N., and Curtis, A., 2013. Long-term diagnostics of precipitation estimates and the development of radar hardware monitoring within a radar product data quality management system. Hydrological Sciences Journal, 59 (7), 1327–1342. http://dx.doi.org/10.1080/02626667.2013.841316     

Dynamics of a fringe mangrove forest detected by Landsat images in the Mekong River Delta,Vietnam

Mangrove forests dominate many tropical coastlines and are one of the most bio‐diverse and productive environments on Earth. However, little is known of the large‐scale dynamics of mangrove canopies and how they colonize intertidal areas. Here we focus on a fringe mangrove forest located in the Mekong River Delta, Vietnam; a fast prograding shoreline where mangroves are encroaching tidal flats. The spatial and temporal evolution of the mangrove canopy is studied using a time series of Landsat images spanning two decades as well as Shuttle Radar Topography Mission (SRTM) elevation data. Our results show that fast mangrove expansion is followed by an increase in Normalized Difference Vegetation Index (NDVI) in the newly established canopy. We observe three different dynamics of the mangrove fringe: in the southwest part of the fringe, near a deltaic distributary where the fringe boundary is linear, the canopy expands uniformly on the tidal flats with a high colonization rate and high NDVI values. In the northeast part of the fringe, near another distributary, the canopy expands at a much lower rate with low NDVI values. In the fringe center, far from the river mouths, the fringe boundary is highly irregular and mangroves expansion in characterized by sparse vegetated patches displaying low NDVI values. We ascribe these different dynamics to wave action and southwest longshore transport triggered by energetic northeasterly monsoons during winter. We further link the large‐scale dynamics of the fringe to small‐scale physical disturbances (waves, erosion and deposition) that might prevent the establishment of mangrove seedlings. Based on these results, we include mangrove encroachment in an already published conceptual model of progradation of the Mekong River Delta. We conclude that high NDVI values and a constantly linear vegetation–water interface are indicative of stable mangrove canopies undergoing fast expansion, probably triggered by sediment availability at the shore. Our results can be applied more generally to mangrove forests growing in minerogenic and high tidal range environments with high sediment inputs. Copyright © 2016 John Wiley & Sons, Ltd.