Otway Continental Margin Transect: Crustal architecture from wide‐angle seismic profiling across Australia's southern margin

The Otway Basin in southeastern Australia formed on a triangular‐shaped area of extended continental lithosphere during two extensional episodes in Cretaceous to Miocene times. The extent of the offshore continental margin is highlighted by Seasat/Geosat satellite altimeter data. The crustal architecture and structural features across this southeast Australian margin have been interpreted from offshore‐onshore wide‐angle seismic profiling data along the Otway Continental Margin Transect extending from the onshore Lake Condah High, through the town of Portland, to the deep Southern Ocean. Along the Otway Continental Margin Transect, the onshore half‐graben geometry of Early Cretaceous deposition gives way offshore to a 5 km‐thick slope basin (P‐wave velocity 2.2–4.6 km/s) to at least 60 km from the shoreline. At 120 km from the nearest shore in a water depth of 4220 m, sonobuoy data indicate a 4–5 km sedimentary sequence overlying a 7 km thick basement above the Moho at 15 km depth. Major fault zones affect the thickness of basin sequences in the onshore area (Tartwaup Fault Zone and its southeast continuation) and at the seaward edge of the Mussel Platform (Mussel Fault). Upper crustal basement is interpreted to be attenuated and thinned Palaeozoic rocks of the Delamerian and Lachlan Orogens (intruded with Jurassic volcanics) that thin from 16 km onshore to about 3.5 km at 120 km from the nearest shore. Basement rocks comprise a 3 km section with velocity 5.5–5.7 km/s overlying a deeper basement unit with velocity 6.15–6.35 km/s. The Moho shallows from a depth of 30 km onshore to 15 km depth at 120 km from the nearest shore, and then to about 12 km in the deep ocean at the limits of the transect (water depth 5200 m). The continent‐ocean boundary is interpreted to be at a prominent topographic inflection point 170 km from shore at the bottom of the continental slope in 4800 m of water. P‐wave velocities in the lower crust are 6.4–6.8 km/s, overlying a thin transition zone to an upper mantle velocity of 8.05 km/s beneath the Moho. Outstandingly clear Moho reflections seen in deep‐marine profiling data at about 10.3 s two‐way time under the slope basin and continent‐ocean boundary place further strong controls on crustal thickness. There is no evidence of massive high velocity (>7 km/s) intrusives/underplate material in the lower crust nor any synrift or early post‐rift subaerial volcanics, indicating that the Otway continental margin can be considered a non‐volcanic margin, similar in many respects to some parts of the Atlantic Ocean margins e.g. the Nova Scotia ‐ Newfoundland margin off Canada and the Galicia Bank off the Iberian Peninsula. Using this analogue, the prominent gravity feature trending northwest‐southeast at the continent‐ocean boundary may indicate the presence of highly serpentinised mantle material beneath a thin crust, but this has yet to be tested by detailed work.     

Gemstone Mineralization in the Palghat-Cauvery Shear Zone System (Karur-Kangayam Belt), Southern India

We summarize here the occurrence of a number of semiprecious stones within a major gemstone belt in the Palghat-Cauvery shear zone system close to the northern margin of the Madurai Granulite Block, southern India. The gem mineralization in this belt includes different varieties of corundum (star ruby, sapphire), cordierite (iolite), feldspar (moonstones and sunstone of various hues), beryl (emerald, aquamarine), chrysoberyl (alexandrite), kornerupine, topaz, spinel, crystal quartz and amethyst, among others. Gem mineralisation has not been directly dated, but is associated with pegmatites that crosscut rocks metamorphosed in late Neoproterozoic/Early Cambrian times. Similar aged gem mineralization occurs south of the Achankovil Shear Zone in southern India, as well as in Sri Lanka and Madagascar and strengthen the view of a broad late Neoproterozoic-early Cambrian gemstone province in central Gondwana. The ruby mineralization within this belt can be correlated with similar occurrences in eastern Madagascar, supporting a correlation between the Malagasy Betsimisaraka suture zone and the Palghat-Cauvery shear zone system in southern India.     

Estimation of hysteretic energy demand using concepts of modal pushover analysis

Hysteretic energy dissipation in a structure during an earthquake is the key factor, besides maximum displacement, related to the amount of damage in it. This energy demand can be accurately computed only through a nonlinear time‐history analysis of the structure subjected to a specific earthquake ground acceleration. However, for multi‐story structures, which are usually modeled as multi‐degree of freedom (MDOF) systems, this analysis becomes computation intensive and time consuming and is not suitable for adopting in seismic design guidelines. An alternative method of estimating hysteretic energy demand on MDOF systems is presented here. The proposed method uses multiple ‘generalized’ or ‘equivalent’ single degree of freedom (ESDOF) systems to estimate hysteretic energy demand on an MDOF system within the context of a ‘modal pushover analysis’. This is a modified version of a previous procedure using a single ESDOF system. Efficiency of the proposed procedure is tested by comparing energy demands based on this method with results from nonlinear dynamic analyses of MDOF systems, as well as estimates based on the previous method, for several ground motion scenarios. Three steel moment frame structures, of 3‐, 9‐, and 20‐story configurations, are selected for this comparison. Bias statistics that show the effectiveness of the proposed method are presented. In addition to being less demanding on the computation time and complexity, the proposed method is also suitable for adopting in design guidelines, as it can use response spectra for hysteretic energy demand estimation. Copyright © 2008 John Wiley & Sons, Ltd.     

Frequency distributions of transient regional climate change from perturbed physics ensembles of general circulation model simulations

Large ensembles of coupled atmosphere–ocean general circulation model (AOGCM) simulations are required to explore modelling uncertainty and make probabilistic predictions of future transient climate change at regional scales. These are not yet computationally feasible so we have developed a technique to emulate the response of such an ensemble by scaling equilibrium patterns of climate change derived from much cheaper “slab” model ensembles in which the atmospheric component of an AOGCM is coupled to a mixed-layer ocean. Climate feedback parameters are diagnosed for each member of a slab model ensemble and used to drive an energy balance model (EBM) to predict the time-dependent response of global surface temperature expected for different combinations of uncertain AOGCM parameters affecting atmospheric, land and sea-ice processes. The EBM projections are then used to scale normalised patterns of change derived for each slab member, and hence emulate the response of the relevant atmospheric model version when coupled to a dynamic ocean, in response to a 1% per annum increase in CO₂. The emulated responses are validated by comparison with predictions from a 17 member ensemble of AOGCM simulations, constructed from variants of HadCM3 using the same parameter combinations as 17 members of the slab model ensemble. Cross-validation permits estimation of the spatial and temporal dependence of emulation error, and also allows estimation of a correction field to correct discrepancies between the scaled equilibrium patterns and the transient response, reducing the emulation error. Emulated transient responses and their associated errors are obtained from the slab ensemble for 129 pseudo-HadCM3 versions containing multiple atmospheric parameter perturbations. These are combined to produce regional frequency distributions for the transient response of annual surface temperature change and boreal winter precipitation change. The technique can be extended to any surface climate variable demonstrating a scaleable, approximately linear response to forcing.     

Tracing suspended sediment and particulate phosphorus sources in catchments

Information on suspended sediment and particulate P (PP) sources is an important requirement in many catchment-based diffuse source pollution studies, in order to assist with model validation and to provide information to support the development of effective sediment and phosphorus control strategies. Such information is, however, frequently unavailable or difficult to assemble. In the study reported, source fingerprinting procedures were successfully used to assemble this information for seven sub-catchments in the Hampshire Avon catchment and five sub-catchments in the Middle Herefordshire Wye catchment. The results provide important new information on the relative importance of the contributions from surface and channel/subsurface sources to the suspended sediment and PP fluxes from the catchments. In the Wye sub-catchments channel/subsurface sources contributed 40–55% of the overall suspended sediment flux and 21–43% of the PP flux from the catchments. Equivalent values for the Avon were 1–41% and 1–54%, respectively. Combination of the information on the relative importance of surface and channel/subsurface sources with measured suspended sediment fluxes has provided the first estimates of the specific fluxes of sediment and PP attributable to channel/subsurface sources for UK catchments. The former are as high as 15–20 t km⁻² year⁻¹ in some of the Wye sub-catchments, whereas the latter exceeded 0.1 kgP ha⁻¹ year⁻¹ in the same sub-catchments. The results emphasize the need to take account of potential contributions from channel/subsurface sources when using measured suspended sediment and PP flux data to validate predictions derived from models incorporating only surface contributions.     

The Global Distribution of Secondary Particulate Matter in a 3-D Lagrangian Chemistry Transport Model

A global 3-D Lagrangian chemistry-transport model STOCHEM is used to describe the tropospheric distributions of four components of the secondary atmospheric aerosol: nitrate, sulphate, ammonium and organic compounds. The model describes the detailed chemistry of the formation of the acid precursors from the oxidation of SO₂, DMS, NO_x, NH₃ and terpenes and their uptake into the aerosol. Model results are compared in some detail with the available surface observations. Comparisons are made between the global budgets and burdens found in other modelling studies. The global distributions of the total mass of secondary aerosols have been estimated for the pre-industrial, present day and 2030 emissions and large changes have been estimated in the mass fractions of the different secondary aerosol components.     

Tropospheric Ozone in a Global-Scale Three-Dimensional Lagrangian Model and Its Response to NOX Emission Controls

A three-dimensional Lagrangian tropospheric chemistry modelis used toinvestigate the impact of human activities on the tropospheric distributionofozone and hydroxyl radicals. The model describes the behaviour of 50 speciesincluding methane, carbon monoxide, oxides of nitrogen, sulphur dioxide andnineorganic compounds emitted from human activities and a range of other sources.Thechemical mechanism involves about 100 chemical reactions of which 16 arephotochemical reactions whose diurnal dependence is treated in full. The modelutilises a five minute chemistry time step and a three hour advection timestepfor the 50,000 air parcels. Meteorological data for the winds, temperatures,clouds and so on are taken from the UK Meteorological Office global model for1994 onwards. The impacts of a 50% reduction in European NO_Xemissions onglobal ozone concentrations are assessed. Surface ozoneconcentrations decrease in summertime and rise in wintertime, but to differentextents.     

Mineralogy and petrology of the LaPaz Icefield lunar mare basaltic meteorites

Abstract— Five basaltic meteorites from the LaPaz ice field are paired on the basis of their mineralogy and texture, and represent a unique basalt type distinct from those in the Apollo or Luna sample collections. LaPaz Icefield (LAP) 02205, LAP 02224, LAP 02226, LAP 02436 and LAP 03632 all contain plagioclase, pyroxene, ilmenite, spinel, olivine, and minor troilite, metal, phosphate, baddeleyite and silica (cristobalite). Brown glassy melt veins are ubiquitous and cross the primary igneous texture. Plagioclase, the major mineral and occurring as laths in a subophitic texture, is of narrow compositional range, from An_85–89. Pyroxene, also a major mineral, is strongly zoned, from augite and pigeonite cores to very iron‐rich rims. Ilmenite laths comprise approximately 3–5% of the basalts. Spinels show a large compositional range, comparable to that documented in Apollo 15 basalts, indicating an early chromite‐rich stage followed by an intermediate to late stage with Cr‐rich ulvöspinel. Relatively large, subhedral to skeletal olivine crystals (Fo_46–62) are sparse, and are too Forich to be in equilibrium with the bulk rock, indicating that these are xenocrysts rather than phenocrysts. The presence of melt veins with a similar composition to the bulk rock, maskelynitized plagioclase feldspar, and metastable cristobalite indicate that these rocks underwent significant shock, between 30 and 50 GPa. Calculated oxygen fugacity, using spinel‐ilmenite‐iron metal equilibria, is within the range defined by previous studies of lunar materials. The bulk composition (low MgO) and low calculated temperatures, together with modelling calculations, indicate an origin by fractional crystallization of a more primitive low TiO₂ parent liquid similar to Apollo 12 olivine basalt.