The role of magma mixing in the petrogenesis of mafic alkaline lavas,Rockeskyllerkopf Volcanic Complex,West Eifel,Germany

The quaternary Rockeskyllerkopf Volcanic Complex (RVC) comprises three spatially and temporally distinct volcanic centers that can also be distinguished on the basis of their geochemical signatures. All the volcanic products in the complex are olivine basanites whose major and trace element compositions span almost the entire range defined for the West Eifel field as a whole. The RVC lavas have lower Al₂O₃, Na₂O and Y contents and higher TiO₂, CaO, K₂O, Sc, V, Co, Rb, and Ba than the Tertiary lavas in nearby Hocheifel volcanic field. Within the complex, the oldest South East Lammersdorf Center (SEL) comprises primitive lavas with an average MgO content of ～11 wt.% and La_N/Yb_N of 29?±?2. The second center, Mäuseberg, has similar MgO to SEL but is distinct in its much higher La_N/Yb_N of 42?±?2. The Rockeskyllerkopf Center, which was erupted after a break in activity, comprises lavas similar in composition to the SEL Center but with distinctly higher Al₂O₃ and lower MgO contents. Given the lack of evidence for significant fractionation or assimilation in the RVC lavas, we attribute the compositional variations within and between the centers of the RVC to be due to variations in the composition of the source region in combination with magma mixing. Our preferred model involves 1–5% partial melting of LREE-enriched mantle in the garnet stability field, likely within the thermal boundary layer at the base of the lithospheric mantle. These melts mixed to variable degrees with 2–4% partial melts of phlogopite-spinel peridotite formed at higher levels in the modally metasomatised lithospheric mantle.     

Crystal chemical controls on rare earth element partitioning between epidote-group minerals and melts: an experimental and theoretical study

We have experimentally determined the partitioning of REE (rare earth elements) between zoisite and hydrous silicate melt at 1,100 °C and 3 GPa. All REE behave moderately compatible in zoisite with respect to the melt and all show a smooth parabolic dependence on ionic radius. The partitioning parabola peaks at Nd , and the compatibility slightly decreases towards La and decreases by half an order of magnitude towards Yb . Application of the elastic strain model of Blundy and Wood (1994) to the available zoisite and allanite REE mineral/melt partitioning data and comparison with partitioning pattern calculated from a combination of structural and physical data (taken from the literature) with the elastic strain model suggest that in zoisite REE prefer the A1-site and that only La and Ce are incorporated into the A2-site in significant amounts. In contrast, in allanite, all REE are preferentially incorporated into the large and highly co-ordinated A2 site. As a result, zoisite fractionates the MREE effectively from the HREE and moderately from the LREE, while allanite fractionates the LREE very effectively from the MREE and HREE. Consequently, the presence of either zoisite or allanite during slab melting will lead to quite different REE pattern in the produced melt.Editorial responsibility: J. Hoefs     

Metamorphic evolution of the Sesia-Lanzo Zone,Western Alps: time constraints from multi-system geochronology

 The Sesia-Lanzo Zone is a polymetamorphic unit containing Hercynian granulite relics overprinted by eclogite and greenschist facies metamorphism and deformation during the Alpine orogeny. Different parts of the unit record different stages on the P-T-deformation evolution, allowing multi-system isotopic studies to unravel the precise timing of the metamorphic history. New Rb–Sr white mica and U–Pb sphene data constrain the age of eclogite facies metamorphism and deformation to 60–70 Ma. This substantially alters the common view of early- to mid-Cretaceous eclogite facies metamorphism in this unit. The new results are more consistent with the established geotectonic framework for the Alpine orogeny, since they do not require a prolonged period of depressed geothermal gradient at a time when the region was in extension. It is also more concordant with recent studies of other units that demonstrate post-Cretaceous high-pressure metamorphism. Step-heated ⁴⁰Ar–³⁹Ar analysis of phengites yields good plateaux giving ages older than the corresponding Rb–Sr age. Such anomalously high ages indicate the presence of radiogenic argon-rich fluids in the grain boundary network under the fluid/pressure conditions acting during this high-pressure metamorphic event. The U–Pb sphene ages are variable in polymetamorphic rocks, and show inheritance of older Pb or sphene crystals into the high-pressure event. Two monometamorphic assemblages yield concordant ages at 66±1 Ma, reflecting crystallisation of the eclogite facies assemblage. The Gneiss Minuti Complex (GMC) lies structurally below the Eclogitic Micaschists, and its pervasive greenschist facies fabric yields tightly clustered Rb–Sr white mica ages at 38–39 Ma. This greenschist event did not affect the majority of the EMC. The ⁴⁰Ar–³⁹Ar ages of micas formed at this time were very disturbed, whereas micas surviving from an earlier higher pressure assemblage had their ⁴⁰Ar–³⁹Ar system reset. The greenschist event did not strongly affect U–Pb systematics in Hercynian age sphenes, suggesting that the GMC did not uniformly suffer an eclogite facies metamorphism during the Alpine cycle, but was juxtaposed against the EMC later in the orogeny. This model still requires that the locus of deformation and metamorphism (and possibly fluid flux) moved outboard with time, leaving the Sesia-Lanzo basement as a shear-bounded unreactive block within the orogenic wedge. Received: 12 October 1995/Accepted:25 June 1996     

Strontium isotopic equilibration during metamorphism of tillites from the Ogcheon Belt,South Korea

The NE/SW trending Ogcheon Belt formed during the Mesozoic by deformation and metamorphism of a sedimentary sequence which includes tillite formations of late Precambrian or Lower Palaeozoic age. In this study Rb-Sr isotopic data are reported from cm-scale sampling of clasts and matrix in these tillites, which underwent metamorphism at grades ranging from the biotite zone to the kyanite zone. Sr-isotopic disequilibrium between clasts and matrix persists up to the highest grade but in four out of five rocks the matrix samples approximate to isochrons (MSWD's<12). The mechanism for this selective isotopic equilibration is considered to be related to the metamorphic reactions in the matrix, which were probably accompanied by a substantial fluid flow. The matrix isochrons for three of the rocks, together with separated white micas from associated schists, suggest that metamorphism took place in the Trias, approximately 200 Myr ago. Metamorphism was followed by slow cooling and biotite closure temperatures were not reached until 190-150 Myr. — These results suggest that where high fluid/rock ratios can be demonstrated on independent petrological grounds, the analysis of small-scale whole-rock samples may allow effective Rb/Sr dating of metamorphism.     

Large wood distribution,mobility, and recruitment in an inter‐dam river reach: A comparison with geomorphic process on the Garrison Reach of the Missouri River pre and post the historical 2011 flood

This study assessed the effect of the largest flood since dam regulation on geomorphic and large wood (LW) trends using LW distributions at three time periods on the 150 km long Garrison Reach of the Missouri River. In 2011, a flood exceeded 4390 m³/s for a two‐week period (705% above mean flow; 500 year flood). LW was measured using high resolution satellite imagery in summer 2010 and 2012. Ancillary data including forest character, vegetation cover, lateral bank retreat, and channel capacity. Lateral bank erosion removed approximately 7400 standing trees during the flood. Other mechanisms, that could account for the other two‐thirds of the measured in‐channel LW, include overland flow through floodplains and islands. LW transport was commonly near or over 100 km as indicated by longitudinal forest and bank loss and post‐flood LW distribution. LW concentrations shift at several locations along the river, both pre‐ and post‐flood, and correspond to geomorphic river regions created by the interaction of the Garrison Dam upstream and the Oahe Dam downstream. Areas near the upstream dam experienced proportionally higher rates of bank erosion and forest loss but in‐channel LW decreased, likely due to scouring. A large amount of LW moved during this flood, the chief anchoring mechanism was not bridges or narrow channel reaches but the channel complexity of the river delta created by the downstream reservoir. Areas near the downstream dam experienced bank accretion and large amounts of LW deposition. This study confirms the results of similar work in the Reach: despite a historic flood longitudinal LW and channel trends remain the same. Dam regulation has created a geomorphic and LW pattern that is largely uninterrupted by an unprecedented dam regulation era flood. River managers may require other tools than infrequent high intensity floods to restore geomorphic and LW patterns. Copyright © 2018 John Wiley & Sons, Ltd.     

Experimental peridotite–melt reaction at one atmosphere: a textural and chemical study

Sieve-textured clinopyroxene and spinel are common in mantle xenoliths and have been interpreted to be the result of partial melting, mantle metasomatism and host magma–xenolith reaction during transport. In this paper, we test the latter hypothesis with a series of reduced and oxidized experiments at 1,200 and 1,156°C at one atmosphere using a synthetic leucitite melt and discs of natural peridotite. Our results show that sieve texture development on clinopyroxene and spinel in mantle xenoliths is the result of a multistage reaction process. In the first step, orthopyroxene undergoes incongruent dissolution to produce a silica and alkali-rich melt together with olivine. As this melt migrates along grain boundaries it causes incongruent dissolution of clinopyroxene and spinel. The incongruent dissolution mechanism involves complete dissolution of the clinopyroxene or spinel followed by nucleation and growth of a secondary clinopyroxene or spinel once the reacting melt is saturated. The reaction of orthopyroxene, clinopyroxene and spinel with infiltrated host magma results in a range of melt compositions that are very similar to those interpreted to be due to very small degrees of partial melting. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Developing a new stream metric for comparing stream function using a bank–floodplain sediment budget: a case study of three Piedmont streams

A bank and floodplain sediment budget was created for three Piedmont streams tributary to the Chesapeake Bay. The watersheds of each stream varied in land use from urban (Difficult Run) to urbanizing (Little Conestoga Creek) to agricultural (Linganore Creek). The purpose of the study was to determine the relation between geomorphic parameters and sediment dynamics and to develop a floodplain trapping metric for comparing streams with variable characteristics. Net site sediment budgets were best explained by gradient at Difficult Run, floodplain width at Little Conestoga Creek, and the relation of channel cross‐sectional area to floodplain width at Linganore Creek. A correlation for all streams indicated that net site sediment budget was best explained by relative floodplain width (ratio of channel width to floodplain width). A new geomorphic metric, the floodplain trapping factor, was used to compare sediment budgets between streams with differing suspended sediment yields. Site sediment budgets were normalized by floodplain area and divided by the stream's sediment yield to provide a unitless measure of floodplain sediment trapping. A floodplain trapping factor represents the amount of upland sediment that a particular floodplain site can trap (e.g. a factor of 5 would indicate that a particular floodplain site traps the equivalent of 5 times that area in upland erosional source area). Using this factor we determined that Linganore Creek had the highest gross and net (floodplain deposition minus bank erosion) floodplain trapping factor (107 and 46, respectively) that Difficult Run the lowest gross floodplain trapping factor (29) and Little Conestoga Creek had the lowest net floodplain trapping factor (–14, indicating that study sites were net contributors to the suspended sediment load). The trapping factor is a robust metric for comparing three streams of varied watershed and geomorphic character, it promises to be a useful tool for future stream assessments. Published 2012. This article is a U.S. Government work and is in the public domain in the USA.     

The golden ark: arsenopyrite crystal plasticity and the retention of gold through high strain and metamorphism

Quantitative electron backscatter diffraction analysis and ion microprobe imaging of gold‐rich arsenopyrites provide the first insights into the crystal plasticity and element mobility behaviour of arsenopyrites through metamorphism (340°–460° and 2 kbar). Remarkably, the gold‐rich arsenopyrites remained structurally and chemically robust during high strain deformation. It was only during a superimposed lower strain deformation event, at a high angle to the preferred orientation of the arsenopyrites, that small amounts of crystal plasticity affected the arsenopyrites. During the low strain event, a dissolution–reprecipitation reaction resulted in loss of gold from the crystal lattice, facilitated by localised domains of recrystallisation, most likely due to fluid percolation along sub‐ and new grain boundaries. We suggest that the abundance and rheologically robust nature of gold‐rich arsenopyrite in giant gold deposits, affected by greenschist–amphibolite metamorphism, is actually critical in the preservation of those deposits.     

The SOLAS air-sea gas exchange experiment (SAGE) 2004

The SOLAS air-sea gas exchange experiment (SAGE) was a multiple-objective study investigating gas-transfer processes and the influence of iron fertilisation on biologically driven gas exchange in high-nitrate low-silicic acid low-chlorophyll (HNLSiLC) Sub-Antarctic waters characteristic of the expansive subpolar zone of the southern oceans. This paper provides a general introduction and summary of the main experimental findings. The release site was selected from a pre-voyage desktop study of environmental parameters to be in the south-west Bounty Trough (46.5°S 172.5°E) to the south-east of New Zealand and the experiment was conducted between mid-March and mid-April 2004. In common with other mesoscale iron addition experiments (FeAX’s), SAGE was designed as a Lagrangian study, quantifying key biological and physical drivers influencing the air-sea gas exchange processes of CO₂, DMS and other biogenic gases associated with an iron-induced phytoplankton bloom. A dual tracer SF₆/³He release enabled quantification of both the lateral evolution of a labelled volume (patch) of ocean and the air-sea tracer exchange at tenths of kilometer scale, in conjunction with the iron fertilisation. Estimates from the dual-tracer experiment found a quadratic dependency of the gas exchange coefficient on windspeed that is widely applicable and describe air-sea gas exchange in strong wind regimes. Within the patch, local and micrometeorological gas exchange process studies (100 m scale) and physical variables such as near-surface turbulence, temperature microstructure at the interface, wave properties and windspeed were quantified to further assist the development of gas exchange models for high-wind environments.There was a significant increase in the photosynthetic competence (F_v/F_m) of resident phytoplankton within the first day following iron addition, but in contrast to other FeAX’s, rates of net primary production and column-integrated chlorophyll a concentrations had only doubled relative to the unfertilised surrounding waters by the end of the experiment. After 15 days and four iron additions totalling 1.1 ton Fe²⁺, this was a very modest response compared to other mesoscale iron enrichment experiments. An investigation of the factors limiting bloom development considered co-limitation by light and other nutrients, the phytoplankton seed-stock and grazing regulation. Whilst incident light levels and the initial Si:N ratio were the lowest recorded in all FeAXs to date, there was only a small seed-stock of diatoms (less than 1% of biomass) and the main response to iron addition was by the picophytoplankton. A high rate of dilution of the fertilised patch relative to phytoplankton growth rate, the greater than expected depth of the surface mixed layer and microzooplankton grazing were all considered as factors that prevented significant biomass accumulation. In line with the limited response, the enhanced biological draw-down of pCO₂ was small and masked by a general increase in pCO₂ due to mixing with higher pCO₂ waters. The DMS precursor DMSP was kept in check through grazing activity and in contrast to most FeAX’s dissolved dimethylsulfide (DMS) concentration declined through the experiment. SAGE is an important low-end member in the range of responses to iron addition in FeAX’s. In the context of iron fertilisation as a geoengineering tool for atmospheric CO₂ removal, SAGE has clearly demonstrated that a significant proportion of the low iron ocean may not produce a phytoplankton bloom in response to iron addition.